Annealing of Oriented PP/PE Double-layer Film within the Melting Range of PE: the Role of Partial Melting and Self-nucleation

Jia-Yi Xie; Yong-Shi Wu; Ze-Feng Yin; Liang-Dong Yin; Rui-Jie Xu; Cai-Hong Lei

doi:10.1007/s10118-022-2681-9

Your Location：

Home >

Browse articles >

Annealing of Oriented PP/PE Double-layer Film within the Melting Range of PE: the Role of Partial Melting and Self-nucleation

RESEARCH ARTICLE | Updated：2022-03-28

- Annealing of Oriented PP/PE Double-layer Film within the Melting Range of PE: the Role of Partial Melting and Self-nucleation
- Annealing of Oriented PP/PE Double-layer Film within the Melting Range of PE: the Role of Partial Melting and Self-nucleation
- Chinese Journal of Polymer Science 2022年40卷第4期页码：403-412
- Affiliations：
  
  School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
- Author bio：
  
  xu565786@163.com (R.J.X.)
  lch528@gdut.edu.cn (C.H.L.)
- Funds：
  
  We are grateful to Dr. Xuke Li and Prof. Zhongbao Wang from Ningbo University for their assistance with SAXS testing and analysis. The authors also would like to thank the financial support from the National Natural Science Foundation of China (Nos. 52173033, 51773044 and 51603047), Guangzhou Science and Technology Plan Project (No. 202102020952), Research and Development Plan for Key Areas in Guangdong Province (No. 2019B090914002), the Project of Science Foundation of Guangdong Province (No. 2021A1515011914), Foshan Science and technology innovation project (No. FS0AA-KJ919-4402-0145).
- DOI：10.1007/s10118-022-2681-9
  中图分类号：
- 收稿：2021-11-04，
  
  修回：2021-12-9，
  
  录用：2021-12-13，
  
  网络首发：2022-02-10，
  
  纸质出版：2022-04-01
- Accepted：
Scan QR Code
Xie, J. Y.; Wu, Y. S.; Yin, Z. F.; Yin, L. D.; Xu, R. J.; Lei, C. H. Annealing of oriented PP/PE double-layer film within the melting range of PE: the role of partial melting and self-nucleation. Chinese J. Polym. Sci. 2022, 40, 403–412

Jia-Yi Xie, Yong-Shi Wu, Ze-Feng Yin, et al. Annealing of Oriented PP/PE Double-layer Film within the Melting Range of PE: the Role of Partial Melting and Self-nucleation[J]. Chinese Journal of Polymer Science, 2022, 40(4): 403-412.
Xie, J. Y.; Wu, Y. S.; Yin, Z. F.; Yin, L. D.; Xu, R. J.; Lei, C. H. Annealing of oriented PP/PE double-layer film within the melting range of PE: the role of partial melting and self-nucleation. Chinese J. Polym. Sci. 2022, 40, 403–412 DOI： 10.1007/s10118-022-2681-9.

Jia-Yi Xie, Yong-Shi Wu, Ze-Feng Yin, et al. Annealing of Oriented PP/PE Double-layer Film within the Melting Range of PE: the Role of Partial Melting and Self-nucleation[J]. Chinese Journal of Polymer Science, 2022, 40(4): 403-412. DOI： 10.1007/s10118-022-2681-9.

摘要

Abstract

Due to the mechanical stability of the PP layer

the oriented PP/PE double-layer film with a row-nucleated crystalline structure can be annealed at a higher temperature than the PE monolayer film. In this work

the effects of annealing temperature within the melting range of PE on the crystalline structure and properties of PP/PE double-layer films were studied. When the annealing temperature is between 100 and 130 °C

below the melting point of PE

the crystallinity

the long period

lateral dimension and orientation of the lamellae in the PE layer increase with the annealing temperature due to the melting of thin lamellae and the self-nucleated effect of partially-melted melts during annealing. With the annealing temperature further increasing to 138 °C

near the melting ending point of PE

since the lamellae melt completely and the melt memory becomes weak during annealing

some spherulite structures are formed in the annealed sample

resulting in a decrease of orientation. In contrast

the annealing only causes the appearance of a low-temperature endothermic plateau in the PP layer. The improved size and orientation of lamellar structure in the PE layer increase the pore arrangement and porosity of the stretched PP/PE microporous membrane. This study successfully applies the self-nucleation effect of partially-melted polymer melt into the practical annealing process

which is helpful to guide the production of high-performance PP/PE/PP lithium batteries separator and the annealing process of other multilayer products.

关键词

Keywords

references

McHugh, A . The role of polymer membrane formation in sustained release drug delivery systems . J. Control. Release , 2005 . 109 211 - 221 . DOI: 10.1016/j.jconrel.2005.09.038 http://doi.org/10.1016/j.jconrel.2005.09.038 .

Venugopal, G.; Moore, J.; Howard, J.; Pendalwar, S . Characterization of microporous separators for lithium-ion batteries . J. Power Sources , 1999 . 77 34 - 41 . DOI: 10.1016/S0378-7753(98)00168-2 http://doi.org/10.1016/S0378-7753(98)00168-2 .

Dahn, J.; Fuller, E.; Obrovac, M.; Von Sacken, U . Thermal stability of Li x CoO 2 , Li x NiO 2 and λ -MnO 2 and consequences for the safety of Li-ion cells . Solid State Ionics , 1994 . 69 265 - 270 . DOI: 10.1016/0167-2738(94)90415-4 http://doi.org/10.1016/0167-2738(94)90415-4 .

Chen, W.; Wu, G.; Chu, J.; Zhang, Y.; Yang, M . Novel method for fabrication of PP/HDPE/PP trilayer microporous membrane with a highly orientated structure . J. Appl. Polym. Sci. , 2019 . 136 47249 DOI: 10.1002/app.47249 http://doi.org/10.1002/app.47249 .

Tabatabaei, S. H.; Carreau, P. J.; Ajji, A . Microporous membranes obtained from PP/HDPE multilayer films by stretching . J. Membr. Sci. , 2009 . 345 148 - 159 . DOI: 10.1016/j.memsci.2009.08.038 http://doi.org/10.1016/j.memsci.2009.08.038 .

Cai, Q.; Xu, R. J.; Wu, S. Q.; Chen, C. B.; Mo, H. B.; Lei, C. H.; Li, L. B.; Li, Z. H . Influence of annealing temperature on the lamellar and connecting bridge structure of stretched polypropylene microporous membrane . Polym. Int. , 2015 . 64 446 - 452 . DOI: 10.1002/pi.4828 http://doi.org/10.1002/pi.4828 .

Chen, C. B.; Lei, C. H.; Cai, Q.; Mo, H. B.; Xu, R. J . Influence of annealing time on the structure and properties of high-density polyethylene microporous membrane . J. Plast. Film Sheet. , 2015 . 31 78 - 95 . DOI: 10.1177/8756087914533563 http://doi.org/10.1177/8756087914533563 .

Saffar, A.; Ajji, A.; Carreau, P. J.; Kamal, M. R . The impact of new crystalline lamellae formation during annealing on the properties of polypropylene based films and membranes . Polymer , 2014 . 55 3156 - 3167 . DOI: 10.1016/j.polymer.2014.05.017 http://doi.org/10.1016/j.polymer.2014.05.017 .

Hedesiu, C.; Demco, D.; Kleppinger, R.; Poel, G . V.; Gijsbers, W.; Blümich, B.; Remerie, K.; Litvinov, V. Effect of temperature and annealing on the phase composition, molecular mobility, and the thickness of domains in isotactic polypropylene studied by proton solid-state NMR, SAXS, and DSC . Macromolecules , 2007 . 40 3977 - 3989 . DOI: 10.1021/ma070014q http://doi.org/10.1021/ma070014q .

Bai, H.; Deng, H.; Zhang, Q.; Wang, K.; Fu, Q.; Zhang, Z.; Men, Y . Effect of annealing on the microstructure and mechanical properties of polypropylene with oriented shish-kebab structure . Polym. Int. , 2012 . 61 252 - 258 . DOI: 10.1002/pi.3180 http://doi.org/10.1002/pi.3180 .

Han, L.; Li, X.; Li, Y.; Huang, T.; Wang, Y.; Wu, J.; Xiang, F . Influence of annealing on microstructure and physical properties of isotactic polypropylene/calcium carbonate composites with β -phase nucleating agent . Mat. Sci. Eng. A , 2010 . 527 3176 - 3185 . DOI: 10.1016/j.msea.2010.01.069 http://doi.org/10.1016/j.msea.2010.01.069 .

Gu, X.; Zhou, M.; Wang, Y.; Zhang, J . Influence of annealing on the morphology and mechanical properties of i PP/HDPE blend with tailored oriented crystalline structures . J. Polym. Res. , 2019 . 26 1 - 11 . DOI: 10.1007/s10965-018-1657-5 http://doi.org/10.1007/s10965-018-1657-5 .

Ding, Z.; Bao, R.; Zhao, B.; Yan, J.; Liu, Z.; Yang, M . Effects of annealing on structure and deformation mechanism of isotactic polypropylene film with row-nucleated lamellar structure . J. Appl. Polym. Sci. , 2013 . 130 1659 - 1666 . DOI: 10.1002/app.39351 http://doi.org/10.1002/app.39351 .

Lee, S. Y.; Park, S. Y.; Song, H. S . Effects of melt-extension and annealing on row-nucleated lamellar crystalline structure of HDPE films . J. Appl. Polym. Sci. , 2007 . 103 3326 - 3333 . DOI: 10.1002/app.25495 http://doi.org/10.1002/app.25495 .

Lee, S. Y.; Park, S. Y.; Song, H. S . Lamellar crystalline structure of hard elastic HDPE films and its influence on microporous membrane formation . Polymer , 2006 . 47 3540 - 3547 . DOI: 10.1016/j.polymer.2006.03.070 http://doi.org/10.1016/j.polymer.2006.03.070 .

Gray, A. P . Polymer crystallinity determinations by DSC . Thermochim. Acta , 1970 . 1 563 - 579 . DOI: 10.1016/0040-6031(70)80008-9 http://doi.org/10.1016/0040-6031(70)80008-9 .

Crist, B . Microfibril dimensions from small-angle X-ray scattering . J. Appl. Crystallogr. , 1979 . 12 27 - 33 . DOI: 10.1107/S0021889879011717 http://doi.org/10.1107/S0021889879011717 .

Tang, Y.; Jiang, Z.; Men, Y.; An, L.; Enderle, H. F.; Lilge, D.; Roth, S . V.; Gehrke, R.; Rieger, J., Uniaxial deformation of overstretched polyethylene: in-situ synchrotron small angle X-ray scattering study . Polymer , 2007 . 48 5125 - 5132 . DOI: 10.1016/j.polymer.2007.06.056 http://doi.org/10.1016/j.polymer.2007.06.056 .

Hashimoto, T.; Nagatoshi, K.; Todo, A.; Kawai, H . Deformation mechanism of ‘hard elastic polyethylene films’ . Polymer , 1976 . 17 1063 - 1074 . DOI: 10.1016/0032-3861(76)90008-2 http://doi.org/10.1016/0032-3861(76)90008-2 .

Lei, C.; Xu, R.; Tian, Z.; Huang, H.; Xie, J.; Zhu, X . Stretching-induced uniform micropores formation: an in situ SAXS/WAXS study . Macromolecules , 2018 . 51 3433 - 3442 . DOI: 10.1021/acs.macromol.7b02335 http://doi.org/10.1021/acs.macromol.7b02335 .

Lin, Y.; Li, X.; Meng, L.; Chen, X.; Lv, F.; Zhang, Q.; Li, L . Stress-induced microphase separation of interlamellar amorphous phase in hard-elastic isotactic polypropylene film . Polymer , 2018 . 148 79 - 92 . DOI: 10.1016/j.polymer.2018.06.009 http://doi.org/10.1016/j.polymer.2018.06.009 .

Xu, R.; Chen, X.; Cai, Q.; Chen, C.; Lin, Y.; Lei, C.; Li, L . In situ study of the annealing process of a polyethylene cast film with a row-nucleated crystalline structure by SAXS . RSC Adv. , 2015 . 5 27722 - 27734 . DOI: 10.1039/C5RA00659G http://doi.org/10.1039/C5RA00659G .

Li, X.; Lin, Y.; Ji, Y.; Meng, L.; Zhang, Q.; Zhang, R.; Zhang, W.; Li, L . Strain and temperature dependence of deformation mechanism of lamellar stacks in HDPE and its guidance on microporous membrane preparation . Polymer , 2016 . 105 264 - 275 . DOI: 10.1016/j.polymer.2016.10.043 http://doi.org/10.1016/j.polymer.2016.10.043 .

Xu, R.; Chen, X.; Xie, J.; Cai, Q.; Lei, C . Influence of melt-draw ratio on the crystalline structure and properties of polypropylene cast film and stretched microporous membrane . Ind. Eng. Chem. Res. , 2015 . 54 2991 - 2999 . DOI: 10.1021/acs.iecr.5b00215 http://doi.org/10.1021/acs.iecr.5b00215 .

Yadegari, A.; Morshedian, J.; Khonakdar, H. A.; Wagenknecht, U.; Heinrich, G . Influence of precursor film microstructure on properties of HDPE microporous membranes prepared by stretching . J. Appl. Polym. Sci. , 2017 . 134 .

Sangroniz, L.; Cavallo, D.; Müller, A. J . Self-nucleation effects on polymer crystallization . Macromolecules , 2020 . 53 4581 - 4604 . DOI: 10.1021/acs.macromol.0c00223 http://doi.org/10.1021/acs.macromol.0c00223 .

Lorenzo, A. T.; Arnal, M. L.; Sanchez, J. J.; Müller, A. J . Effect of annealing time on the self-nucleation behavior of semicrystalline polymers . J. Polym. Sci., Part B: Polym. Phys. , 2006 . 44 1738 - 1750 . DOI: 10.1002/polb.20832 http://doi.org/10.1002/polb.20832 .

Fillon, B.; Wittmann, J.; Lotz, B.; Thierry, A . Self-nucleation and recrystallization of isotactic polypropylene ( α phase) investigated by differential scanning calorimetry . J. Polym. Sci., Part B: Polym. Phys. , 1993 . 31 1383 - 1393 . .

浏览量

185

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

MICROSTRUCTURE EVOLUTION OF ISOTACTIC POLYPROPYLENE DURING ANNEALING: EFFECT OF POLY(ETHYLENE OXIDE)

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Silk Sericin-inspired Poly-β-homoserine for Protein Protection