Construction of Safety and Non-flammable Polyimide Separator Containing Carboxyl Groups for Advanced Fast Charing Lithium-ion Batteries

Ji-Ping Gu; Kai-Yuan Zhang; Xiu-Ting Li; Jie Dong; Qing-Hua Zhang; Xin Zhao

doi:10.1007/s10118-022-2678-4

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Construction of Safety and Non-flammable Polyimide Separator Containing Carboxyl Groups for Advanced Fast Charing Lithium-ion Batteries

RESEARCH ARTICLE | Updated：2022-03-28

- Construction of Safety and Non-flammable Polyimide Separator Containing Carboxyl Groups for Advanced Fast Charing Lithium-ion Batteries
- Construction of Safety and Non-flammable Polyimide Separator Containing Carboxyl Groups for Advanced Fast Charing Lithium-ion Batteries
- Chinese Journal of Polymer Science 2022年40卷第4期页码：345-354
- Affiliations：
  
  State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  xzhao@dhu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. U21A2087, 51903038 and 21975040).
- DOI：10.1007/s10118-022-2678-4
  中图分类号：
- 收稿：2021-10-25，
  
  修回：2021-11-23，
  
  录用：2021-12-9，
  
  网络首发：2022-02-15，
  
  纸质出版：2022-04-01
- Accepted：
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Gu, J. P.; Zhang, K. Y.; Li, X. T.; Dong, J.; Zhang, Q. H.; Zhao, X. Construction of safety and non-flammable polyimide separator containing carboxyl groups for advanced fast charing lithium-ion batteries. Chinese J. Polym. Sci. 2022, 40, 345–354

Ji-Ping Gu, Kai-Yuan Zhang, Xiu-Ting Li, et al. Construction of Safety and Non-flammable Polyimide Separator Containing Carboxyl Groups for Advanced Fast Charing Lithium-ion Batteries[J]. Chinese Journal of Polymer Science, 2022, 40(4): 345-354.
Gu, J. P.; Zhang, K. Y.; Li, X. T.; Dong, J.; Zhang, Q. H.; Zhao, X. Construction of safety and non-flammable polyimide separator containing carboxyl groups for advanced fast charing lithium-ion batteries. Chinese J. Polym. Sci. 2022, 40, 345–354 DOI： 10.1007/s10118-022-2678-4.

Ji-Ping Gu, Kai-Yuan Zhang, Xiu-Ting Li, et al. Construction of Safety and Non-flammable Polyimide Separator Containing Carboxyl Groups for Advanced Fast Charing Lithium-ion Batteries[J]. Chinese Journal of Polymer Science, 2022, 40(4): 345-354. DOI： 10.1007/s10118-022-2678-4.

摘要

Polyimide separators with spongy-like pore structure were prepared by non-solvent induced phase separation (NIPS)

containing carboxyl groups which promote the desolvation of Li

ions and exhibiting excellent resistance to thermal shrinkage and flame retardant properties.

Abstract

With the wide applications of lithium-ion batteries (LIBs) in electronic devices and electric vehicles

it is of great importance to improve their safety and electrochemical performance. Herein

soluble polyimides (PI) containing carboxyl groups (―COOH) were synthesized by a simple one-step method and PI separators with sponge-like

interpenetrating porous structures were prepared

via

non-solvent induced phase separation (NIPS). The obtained PI separators exhibited excellent thermal stability and fire-resistance properties

with the electrolyte uptake of 344% and good dimensional integrity in air at 200 °C. The results showed that the lithium-ion transference number of the obtained PI separator could reach 0.48

which was much higher than that of the Celgard-2400 separator (0.38). The Li/LiFePO

half-cell with the PI separator showed excellent cycle capability and high-rate performance with a high capacity of 121.80 mA·h·g

–1

at 5 C

which was better than that of the cell with the Celgard-2400 separator (54.3 mA·h·g

–1

)

demonstrating the promising applications of this PI separators in LIBs.

关键词

Keywords

references

Shan, X. Y.; Li, F.; Wang, D. W.; Cheng, H. M . The smart era of electrochemical energy storage devices . Energy Storage Mater. , 2016 . 3 66 - 68 . DOI: 10.1016/j.ensm.2016.01.005 http://doi.org/10.1016/j.ensm.2016.01.005 .

Lee, H.; Yanilmaz, M.; Toprakci, O.; Fu, K.; Zhang, X . A review of recent developments in membrane separators for rechargeable lithium-ion batteries . Energy Environ. Sci. , 2014 . 7 3857 - 3886 . DOI: 10.1039/C4EE01432D http://doi.org/10.1039/C4EE01432D .

Li, Y.; Yu, L.; Hu, W.; Hu, X . Thermotolerant separators for safe lithium-ion batteries under extreme conditions . J. Mater. Chem. A , 2020 . 8 20294 - 20317 . DOI: 10.1039/D0TA07511F http://doi.org/10.1039/D0TA07511F .

Feng, X.; Ouyang, M.; Liu, X.; Lu, L.; Xia, Y.; He, X . Thermal runaway mechanism of lithium ion battery for electric vehicles: a review . Energy Storage Mater. , 2018 . 10 246 - 267 . DOI: 10.1016/j.ensm.2017.05.013 http://doi.org/10.1016/j.ensm.2017.05.013 .

Shin, D. W.; Guiver, M. D.; Lee, Y. M . Hydrocarbon-based polymer electrolyte membranes: importance of morphology on ion transport and membrane stability . Chem. Rev. , 2017 . 117 4759 - 4805 . DOI: 10.1021/acs.chemrev.6b00586 http://doi.org/10.1021/acs.chemrev.6b00586 .

Li, D.; Zhang, H.; Li, X . Porous polyetherimide membranes with tunable morphology for lithium-ion battery . J. Membr. Sci. , 2018 . 565 42 - 49 . DOI: 10.1016/j.memsci.2018.08.011 http://doi.org/10.1016/j.memsci.2018.08.011 .

Yin, M.; Huang, J.; Yu, J.; Chen, G.; Qu, S.; Wang, X.; Li, C . The polypropylene membrane modified by an atmospheric pressure plasma jet as a separator for lithium-ion button battery . Electrochim. Acta , 2018 . 260 489 - 497 . DOI: 10.1016/j.electacta.2017.12.119 http://doi.org/10.1016/j.electacta.2017.12.119 .

Costa, C. M.; Lee, Y. H.; Kim, J. H.; Lee, S. Y.; Lanceros- Méndz, S . Recent advances on separator membranes for lithium-ion battery applications: from porous membranes to solid electrolytes . Energy Storage Mater. , 2019 . 22 346 - 375 . DOI: 10.1016/j.ensm.2019.07.024 http://doi.org/10.1016/j.ensm.2019.07.024 .

Heidari, A. A.; Mahdavi, H . Recent development of polyolefin-based microporous separators for Li-ion batteries: a review . Chem. Rec. , 2020 . 20 570 - 595 . DOI: 10.1002/tcr.201900054 http://doi.org/10.1002/tcr.201900054 .

Gu, Q. Q.; Xue, H. J.; Li, Z. W.; Song, J. C.; Sun, Z. Y . High-performance polyethylene separators for lithium-ion batteries modified by phenolic resin . J. Power Sources , 2021 . 483 229155 DOI: 10.1016/j.jpowsour.2020.229155 http://doi.org/10.1016/j.jpowsour.2020.229155 .

Sheng, L.; Song, L.; Gong, H.; Pan, J.; Bai, Y.; Song, S.; Liu, G.; Wang, T.; Huang, X.; He, J . Polyethylene separator grafting with polar monomer for enhancing the lithium-ion transport property . J. Power Sources , 2020 . 479 228812 DOI: 10.1016/j.jpowsour.2020.228812 http://doi.org/10.1016/j.jpowsour.2020.228812 .

Luo, W.; Cheng, S.; Wu, M.; Zhang, X.; Yang, D.; Rui, X . A review of advanced separators for rechargeable batteries . J. Power Sources , 2021 . 509 230372 DOI: 10.1016/j.jpowsour.2021.230372 http://doi.org/10.1016/j.jpowsour.2021.230372 .

Ding, L.; Zhang, C.; Wu, T.; Yang, F.; Lan, F.; Cao, Y.; Xiang, M . Effect of temperature on compression behavior of polypropylene separator used for Lithium-ion battery . J. Power Sources , 2020 . 466 228300 DOI: 10.1016/j.jpowsour.2020.228300 http://doi.org/10.1016/j.jpowsour.2020.228300 .

Feng, X.; Zheng, S.; Ren, D.; He, X.; Wang, L.; Cui, H.; Liu, X.; Jin, C.; Zhang, F.; Xu, C.; Hsu, H.; Gao, S.; Chen, T.; Li, Y.; Wang, T.; Wang, H.; Li, M.; Ouyang, M . Investigating the thermal runaway mechanisms of lithium-ion batteries based on thermal analysis database . Appl. Energy , 2019 . 246 53 - 64 . DOI: 10.1016/j.apenergy.2019.04.009 http://doi.org/10.1016/j.apenergy.2019.04.009 .

Lu, L.; Han, X.; Li, J.; Hua, J.; Ouyang, M . A review on the key issues for lithium-ion battery management in electric vehicles . J. Power Sources , 2013 . 226 272 - 288 . DOI: 10.1016/j.jpowsour.2012.10.060 http://doi.org/10.1016/j.jpowsour.2012.10.060 .

Orendorff, C. J.; Lambert, T. N.; Chavez, C. A.; Bencomo, M.; Fenton, K. R . Polyester separators for lithium-ion cells: improving thermal stability and abuse tolerance . Adv. Energy Mater. , 2013 . 3 314 - 320 . DOI: 10.1002/aenm.201200292 http://doi.org/10.1002/aenm.201200292 .

Song, J.; Ryou, M. H.; Son, B.; Lee, J. N.; Lee, D. J.; Lee, Y. M.; Choi, J. W.; Park, J. K . Co-polyimide-coated polyethylene separators for enhanced thermal stability of lithium ion batteries . Electrochim. Acta , 2012 . 85 524 - 530 . DOI: 10.1016/j.electacta.2012.06.078 http://doi.org/10.1016/j.electacta.2012.06.078 .

Liang, N.; Fang, J.; Guo, X . A simple approach for preparation of porous polybenzimidazole membranes as a promising separator for lithium ion batteries . J. Mater. Chem. A , 2017 . 5 15087 - 15095 . DOI: 10.1039/C7TA03554C http://doi.org/10.1039/C7TA03554C .

Liu, X.; Wu, Y.; Yang, F.; Wang, S.; Zhang, B.; Wang, L . An effective dual-channel strategy for preparation of polybenzimidazole separator for advanced-safety and high-performance lithium-ion batteries . J. Membr. Sci. , 2021 . 626 119190 DOI: 10.1016/j.memsci.2021.119190 http://doi.org/10.1016/j.memsci.2021.119190 .

Liu, X.; Zhang, B.; Wu, Y.; Chen, J.; Fang, M.; Wang, L.; Wang, L . The effects of polybenzimidazole nanofiber separator on the safety and performance of lithium-ion batteries: characterization and analysis from the perspective of mechanism . J. Power Sources , 2020 . 475 228624 DOI: 10.1016/j.jpowsour.2020.228624 http://doi.org/10.1016/j.jpowsour.2020.228624 .

Patel, A.; Wilcox, K.; Li, Z.; George, I.; Juneja, R.; Lollar, C.; Lazar, S.; Grunlan, J.; Tenhaeff, W. E.; Lutkenhaus, J. L . High modulus, thermally stable, and self-extinguishing aramid nanofiber separators . ACS Appl. Mater. Interfaces , 2020 . 12 25756 - 25766 . DOI: 10.1021/acsami.0c03671 http://doi.org/10.1021/acsami.0c03671 .

Yang, B.; Wang, L.; Zhang, M.; Li, W.; Zhou, Q.; Zhong, L . Advanced separators based on aramid nanofiber (ANF) membranes for lithium-ion batteries: a review of recent progress . J. Mater. Chem. A , 2021 . 9 12923 - 12946 . DOI: 10.1039/D1TA03125B http://doi.org/10.1039/D1TA03125B .

Liu, J.; Wang, J.; Zhu, L.; Chen, X.; Ma, Q.; Wang, L.; Wang, X.; Yan, W . A high-safety and multifunctional MOFs modified aramid nanofiber separator for lithium-sulfur batteries . Chem. Eng. J. , 2021 . 411 128540 DOI: 10.1016/j.cej.2021.128540 http://doi.org/10.1016/j.cej.2021.128540 .

l'Abee, R.; DaRosa, F.; Armstrong, M. J.; Hantel, M. M.; Mourzagh, D . High temperature stable Li-ion battery separators based on polyetherimides with improved electrolyte compatibility . J. Power Sources Sources , 2017 . 345 202 - 211 . DOI: 10.1016/j.jpowsour.2017.02.005 http://doi.org/10.1016/j.jpowsour.2017.02.005 .

Shi, J.; Xia, Y.; Yuan, Z.; Hu, H.; Li, X.; Zhang, H.; Liu, Z . Porous membrane with high curvature, three-dimensional heat-resistance skeleton: a new and practical separator candidate for high safety lithium ion battery . Sci. Rep. , 2015 . 5 8255 DOI: 10.1038/srep08255 http://doi.org/10.1038/srep08255 .

Kong, L.; Liu, B.; Ding, J.; Yan, X.; Tian, G.; Qi, S.; Wu, D . Robust polyetherimide fibrous membrane with crosslinked topographies fabricated via in-situ micro-melting and its application as superior Lithium-ion battery separator with shutdown function . J. Membr. Sci. , 2018 . 549 244 - 250 . DOI: 10.1016/j.memsci.2017.12.015 http://doi.org/10.1016/j.memsci.2017.12.015 .

Qi, W.; Lu, C.; Chen, P.; Han, L.; Yu, Q.; Xu, R . Electrochemical performances and thermal properties of electrospun poly(phthalazinone ether sulfone ketone) membrane for lithium-ion battery . Mater. Lett. , 2012 . 66 239 - 241 . DOI: 10.1016/j.matlet.2011.08.042 http://doi.org/10.1016/j.matlet.2011.08.042 .

Wang, T.; Sun, F.; Wang, H.; Yang, S.; Fan, L . Preparation and properties of pore-filling membranes based on sulfonated copolyimides and porous polyimide matrix . Polymer , 2012 . 53 3154 - 3162 . DOI: 10.1016/j.polymer.2012.05.049 http://doi.org/10.1016/j.polymer.2012.05.049 .

Pai, J. Y.; Hsieh, C. T.; Lee, C. H.; Wang, J. A.; Ku, H. Y.; Huang, C. L.; Hardwick, L. J.; Hu, C. C . Engineering of electrospun polyimide separators for electrical double-layer capacitors and lithium-ion cells . J. Power Sources , 2021 . 482 229054 DOI: 10.1016/j.jpowsour.2020.229054 http://doi.org/10.1016/j.jpowsour.2020.229054 .

Lin, D.; Zhuo, D.; Liu, Y.; Cui, Y . All-integrated bifunctional separator for Li dendrite detection via novel solution synthesis of a thermostable polyimide separator . J. Am. Chem. Soc. , 2016 . 138 11044 - 11050 . DOI: 10.1021/jacs.6b06324 http://doi.org/10.1021/jacs.6b06324 .

Liao, C.; Wang, W.; Wang, J.; Han, L.; Qiu, S.; Song, L.; Gui, Z.; Kan, Y.; Hu, Y . Magnetron sputtering deposition of silicon nitride on polyimide separator for high-temperature lithium-ion batteries . J. Energy Chem. , 2021 . 56 1 - 10 . DOI: 10.1016/j.jechem.2020.07.046 http://doi.org/10.1016/j.jechem.2020.07.046 .

Lu, Z.; Sui, F.; Miao, Y . E.; Liu, G.; Li, C.; Dong, W.; Cui, J.; Liu, T.; Wu, J.; Yang, C. Polyimide separators for rechargeable batteries . J. Energy Chem. , 2021 . 58 170 - 197 . DOI: 10.1016/j.jechem.2020.09.043 http://doi.org/10.1016/j.jechem.2020.09.043 .

Dong, G.; Liu, B.; Kong, L.; Wang, Y.; Tian, G.; Qi, S.; Wu, D . Neoteric polyimide nanofiber encapsulated by the TiO 2 armor as the tough, highly wettable, and flame-retardant separator for advanced lithium-ion batteries . ACS Sustain. Chem. Eng. , 2019 . 7 17643 - 17652 . DOI: 10.1021/acssuschemeng.9b03525 http://doi.org/10.1021/acssuschemeng.9b03525 .

Huang, X.; Hitt, J. Lithium ion battery separators: development and performance characterization of a composite membrane. J. Membr. Sci. 2013 , 425-426 , 163-168.

Shi, C.; Zhang, P.; Huang, S.; He, X.; Yang, P.; Wu, D.; Sun, D.; Zhao, J . Functional separator consisted of polyimide nonwoven fabrics and polyethylene coating layer for lithium-ion batteries . J. Power Sources , 2015 . 298 158 - 165 . DOI: 10.1016/j.jpowsour.2015.08.008 http://doi.org/10.1016/j.jpowsour.2015.08.008 .

Yu, B. C.; Park, K.; Jang, J. H.; Goodenough, J. B . Cellulose-based porous membrane for suppressing Li dendrite formation in lithium-sulfur battery . ACS Energy Lett. , 2016 . 1 633 - 637 . DOI: 10.1021/acsenergylett.6b00209 http://doi.org/10.1021/acsenergylett.6b00209 .

Shi, J.; Hu, H.; Xia, Y.; Liu, Y.; Liu, Z . Polyimide matrix-enhanced cross-linked gel separator with three-dimensional heat-resistance skeleton for high-safety and high-power lithium ion batteries . J. Mater. Chem. A , 2014 . 2 9134 - 9141 . DOI: 10.1039/C4TA00808A http://doi.org/10.1039/C4TA00808A .

Tan, J.; Kong, L.; Qiu, Z.; Yan, Y . Flexible, high-wettability and thermostable separator based on fluorinated polyimide for lithium-ion battery . J. Solid State Electrochem. , 2018 . 22 3363 - 3373 . DOI: 10.1007/s10008-018-4049-1 http://doi.org/10.1007/s10008-018-4049-1 .

Zhang, H.; Lin, C. E.; Zhou, M. Y.; John, A. E.; Zhu, B. K . High thermal resistance polyimide separators prepared via soluble precusor and non-solvent induced phase separation process for lithium ion batteries . Electrochim. Acta , 2016 . 187 125 - 133 . DOI: 10.1016/j.electacta.2015.11.028 http://doi.org/10.1016/j.electacta.2015.11.028 .

Li, D.; Wang, H.; Luo, L.; Zhu, J.; Li, J.; Liu, P.; Yu, Y.; Jiang, M . Electrospun separator based on sulfonated polyoxadiazole with outstanding thermal stability and electrochemical properties for lithium-ion Batteries . ACS Appl. Energy Mater. , 2021 . 4 879 - 887 . DOI: 10.1021/acsaem.0c02767 http://doi.org/10.1021/acsaem.0c02767 .

Lin, C. E.; Zhang, H.; Song, Y. Z.; Zhang, Y.; Yuan, J. J.; Zhu, B. K . Carboxylated polyimide separator with excellent lithium ion transport properties for a high-power density lithium-ion battery . J. Mater. Chem. A , 2018 . 6 991 - 998 . DOI: 10.1039/C7TA08702K http://doi.org/10.1039/C7TA08702K .

Dhara, M. G.; Banerjee, S . Fluorinated high-performance polymers: poly(arylene ether)s and aromatic polyimides containing trifluoromethyl groups . Prog. Polym. Sci. , 2010 . 35 1022 - 1077 . DOI: 10.1016/j.progpolymsci.2010.04.003 http://doi.org/10.1016/j.progpolymsci.2010.04.003 .

Zhai, L.; Yang, S.; Fan, L . Preparation and characterization of highly transparent and colorless semi-aromatic polyimide films derived from alicyclic dianhydride and aromatic diamines . Polymer , 2012 . 53 3529 - 3539 . DOI: 10.1016/j.polymer.2012.05.047 http://doi.org/10.1016/j.polymer.2012.05.047 .

Qiu, W.; Chen, C. C.; Xu, L.; Cui, L.; Paul, D. R.; Koros, W. J . Sub- T g cross-linking of a polyimide membrane for enhanced CO 2 plasticization resistance for natural gas separation . Macromolecules , 2011 . 44 6046 - 6056 . DOI: 10.1021/ma201033j http://doi.org/10.1021/ma201033j .

Shi, J. L.; Fang, L. F.; Li, H.; Zhang, H.; Zhu, B. K.; Zhu, L. P . Improved thermal and electrochemical performances of PMMA modified PE separator skeleton prepared via dopamine-initiated ATRP for lithium ion batteries . J. Membr. Sci. , 2013 . 437 160 - 168 . DOI: 10.1016/j.memsci.2013.03.006 http://doi.org/10.1016/j.memsci.2013.03.006 .

Miao, Y. E.; Zhu, G. N.; Hou, H.; Xia, Y. Y.; Liu, T . Electrospun polyimide nanofiber-based nonwoven separators for lithium-ion batteries . J. Power Sources , 2013 . 226 82 - 86 . DOI: 10.1016/j.jpowsour.2012.10.027 http://doi.org/10.1016/j.jpowsour.2012.10.027 .

Kong, L.; Yan, Y.; Qiu, Z.; Zhou, Z.; Hu, J . Robust fluorinated polyimide nanofibers membrane for high-performance lithium-ion batteries . J. Membr. Sci. , 2018 . 549 321 - 331 . DOI: 10.1016/j.memsci.2017.12.028 http://doi.org/10.1016/j.memsci.2017.12.028 .

Luo, X.; Lu, X.; Chen, X.; Chen, Y.; Song, C.; Yu, C.; Wang, N.; Su, D.; Wang, C.; Gao, X.; Wang, G.; Cui, L . A robust flame retardant fluorinated polyimide nanofiber separator for high-temperature lithium-sulfur batteries . J. Mater. Chem. A , 2020 . 8 14788 - 14798 . DOI: 10.1039/D0TA00439A http://doi.org/10.1039/D0TA00439A .

Hussain, A.; Li, D.; Luo, Y.; Zhang, H.; Zhang, H.; Li, X . Porous membrane with improved dendrite resistance for high-performance lithium metal-based battery . J. Membr. Sci. , 2020 . 605 118108 DOI: 10.1016/j.memsci.2020.118108 http://doi.org/10.1016/j.memsci.2020.118108 .

Wang, Q.; Yang, J.; Wang, Z.; Shi, L.; Zhao, Y.; Yuan, S . Dual-scale Al 2 O 3 particles coating for high-performance separator and lithium metal anode . Energy Technol. , 2020 . 8 1901429 DOI: 10.1002/ente.201901429 http://doi.org/10.1002/ente.201901429 .

Wang, Y.; Shi, L.; Zhou, H.; Wang, Z.; Li, R.; Zhu, J.; Qiu, Z.; Zhao, Y.; Zhang, M.; Yuan, S . Polyethylene separators modified by ultrathin hybrid films enhancing lithium ion transport performance and Li-metal anode stability . Electrochim. Acta , 2018 . 259 386 - 394 . DOI: 10.1016/j.electacta.2017.10.120 http://doi.org/10.1016/j.electacta.2017.10.120 .

Xu, W.; Wang, Z.; Shi, L.; Ma, Y.; Yuan, S.; Sun, L.; Zhao, Y.; Zhang, M.; Zhu, J . Layer-by-layer deposition of organic-inorganic hybrid multilayer on microporous polyethylene separator to enhance the electrochemical performance of lithium-ion battery . ACS Appl. Mater. Interfaces , 2015 . 7 20678 - 20686 . DOI: 10.1021/acsami.5b05457 http://doi.org/10.1021/acsami.5b05457 .

Mao, X.; Shi, L.; Zhang, H.; Wang, Z.; Zhu, J.; Qiu, Z.; Zhao, Y.; Zhang, M.; Yuan, S . Polyethylene separator activated by hybrid coating improving Li + ion transference number and ionic conductivity for Li-metal battery . J. Power Sources , 2017 . 342 816 - 824 . DOI: 10.1016/j.jpowsour.2017.01.006 http://doi.org/10.1016/j.jpowsour.2017.01.006 .

Song, Y. Z.; Yuan, J. J.; Yin, X.; Zhang, Y.; Lin, C. E.; Sun, C. C.; Fang, L. F.; Zhu, B.; Zhu, L. P . Effect of polyphenol-polyamine treated polyethylene separator on the ionic conduction and interface properties for lithium-metal anode batteries . J. Electroanal. Chem. , 2018 . 816 68 - 74 . DOI: 10.1016/j.jelechem.2018.03.044 http://doi.org/10.1016/j.jelechem.2018.03.044 .

Li, D.; Shi, D.; Xia, Y.; Qiao, L.; Li, X.; Zhang, H . Superior thermally stable and nonflammable porous polybenzimidazole membrane with high wettability for high-power lithium-ion batteries . ACS Appl. Mater. Interfaces , 2017 . 9 8742 - 8750 . DOI: 10.1021/acsami.6b16316 http://doi.org/10.1021/acsami.6b16316 .

Zhang, Y.; Wang, Z.; Xiang, H.; Shi, P.; Wang, H . A thin inorganic composite separator for lithium-ion batteries . J. Membr. Sci. , 2016 . 509 19 - 26 . DOI: 10.1016/j.memsci.2016.02.047 http://doi.org/10.1016/j.memsci.2016.02.047 .

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