Tailoring the Crystallization Behavior and Mechanical Property of Poly(glycolic acid) by Self-nucleation

Jia-Xuan Li; De-Yu Niu; Peng-Wu Xu; Zhao-Yang Sun; Wei-Jun Yang; Yang Ji; Pi-Ming Ma

doi:10.1007/s10118-022-2671-y

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Tailoring the Crystallization Behavior and Mechanical Property of Poly(glycolic acid) by Self-nucleation

RESEARCH ARTICLE | Updated：2022-03-28

- Tailoring the Crystallization Behavior and Mechanical Property of Poly(glycolic acid) by Self-nucleation
- Tailoring the Crystallization Behavior and Mechanical Property of Poly(glycolic acid) by Self-nucleation
- Chinese Journal of Polymer Science 2022年40卷第4期页码：365-372
- Affiliations：
  
  a.The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, Jiangnan University, Wuxi 214122, China
  b.Inner Mongolia Pujing Polymer Material Technology Corporation Ltd., Baotou 014060, China
- Author bio：
  
  pengwuxu@jiangnan.edu.cn (P.W.X.)
  p.ma@jiangnan.edu.cn (P.M.M.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51873082, 52073123 and 52103032), the Distinguished Young Natural Science Foundation of Jiangsu Province (No. BK20200027), and the Natural Science Foundation of Jiangsu Province (No. BK20200606).
- DOI：10.1007/s10118-022-2671-y
  中图分类号：
- 收稿：2021-10-07，
  
  修回：2021-11-5，
  
  录用：2021-11-23，
  
  网络首发：2022-01-20，
  
  纸质出版：2022-04-01
- Accepted：
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Li, J. X.; Niu, D. Y.; Xu, P. W.; Sun, Z. Y.; Yang, W. J.; Ji, Y.; Ma, P. M. Tailoring the crystallization behavior and mechanical property of poly(glycolic acid) by self-nucleation. Chinese J. Polym. Sci. 2022, 40, 365–372

Jia-Xuan Li, De-Yu Niu, Peng-Wu Xu, et al. Tailoring the Crystallization Behavior and Mechanical Property of Poly(glycolic acid) by Self-nucleation[J]. Chinese Journal of Polymer Science, 2022, 40(4): 365-372.
Li, J. X.; Niu, D. Y.; Xu, P. W.; Sun, Z. Y.; Yang, W. J.; Ji, Y.; Ma, P. M. Tailoring the crystallization behavior and mechanical property of poly(glycolic acid) by self-nucleation. Chinese J. Polym. Sci. 2022, 40, 365–372 DOI： 10.1007/s10118-022-2671-y.

Jia-Xuan Li, De-Yu Niu, Peng-Wu Xu, et al. Tailoring the Crystallization Behavior and Mechanical Property of Poly(glycolic acid) by Self-nucleation[J]. Chinese Journal of Polymer Science, 2022, 40(4): 365-372. DOI： 10.1007/s10118-022-2671-y.

摘要

Abstract

Biocompostable poly(glycolic acid) (PGA) crystallizes slowly under fast cooling condition

leading to poor mechanical performance of the final products. In this work

a self-nucleation (SN) route was carried out to promote the crystallization of PGA by regulating only the thermal procedure without any extra nucleating agents. When self-nucleation temperature (

) decreased from 250 °C to 227 °C

the nuclei density was increased

and the non-isothermal crystallization temperature (

) of PGA was increased from 156 °C to 197 °C and the half-life time (

0.5

) of isothermal crystallization at 207 °C was decreased by 89%. Consequently

the tensile strength and the elongation at break of the PGA were increased by 12% and 189%

respectively. According to the change of

as a function of

a three-stage temperature domain map (Domain I

II and III) was protracted and the viscoelastic behavior of the self-nucleation melt and the homogeneous melt was studied. The results indicated that interaction among PGA chains was remained in Domain IIb

which can act as pre-ordered structure to accelerate the overall crystallization rate. This work utilizes a simple and effective SN method to regulate the crystallization behavior and the mechanical properties of PGA

which may broaden the application range of resulting materials.

关键词

Keywords

references

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