Hypercrosslinking Polymers Fabricated from Divinyl Benzene <italic style="font-style: italic">via</italic> Friedel-Crafts Addition Polymerization

Zheng-Yu Duan; Yan-Yan Wang; Qi-Wei Pan; Yun-Feng Xie; Zhi-Yong Chen

doi:10.1007/s10118-022-2667-7

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Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization

RESEARCH ARTICLE | Updated：2022-03-23

- Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization
- Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization
- Chinese Journal of Polymer Science 2022年40卷第3期页码：310-320
- Affiliations：
  
  a.Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering; University of Jinan, Jinan 250022, China
  b.Nutrition & Health Research Institute, COFCO Corporation, Beijing Key Laboratory of Nutrition & Health and Food Safety, Beijing 102209, China
- Author bio：
  
  chm_panqw@ujn.edu.cn (Q.W.P.)
  xieyunfeng@cofco.com (Y.F.X.)
  chm_chenzy@ujn.edu.cn (Z.Y.C.)
- Funds：
  
  The authors gratefully thank National Key R&D Program of China (No. 2017YFC1600404) and Natural Science Foundation of Shandong Province (No. ZR2013BM011) for financial support. The work was also supported by Open Projects Fund of Shandong Key Laboratory of Carbohydrate Chemistry and Glycobiology, Shandong University (No. 2019CCG02), Shandong Key Laboratory of Fluorine Chemistry and Chemical Engineering Materials, and Science and Technology Bureau of Jinan (No. 2021GXRC105). The authors thank Dr. Yang Xu for valuable discussion with preparation and characterization of HCPs.
- DOI：10.1007/s10118-022-2667-7
  中图分类号：
- 收稿：2021-07-31，
  
  修回：2021-11-17，
  
  录用：2021-11-18，
  
  网络首发：2022-01-14，
  
  纸质出版：2022-03-01
- Accepted：
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Duan, Z. Y.; Wang, Y. Y.; Pan, Q. W.; Xie, Y. F.; Chen, Z. Y. Hypercrosslinking polymers fabricated from divinyl benzene via Friedel-Crafts addition polymerization. Chinese J. Polym. Sci. 2022, 40, 310–320

Zheng-Yu Duan, Yan-Yan Wang, Qi-Wei Pan, et al. Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization[J]. Chinese Journal of Polymer Science, 2022, 40(3): 310-320. DOI: 10.1007/s10118-022-2667-7.
Duan, Z. Y.; Wang, Y. Y.; Pan, Q. W.; Xie, Y. F.; Chen, Z. Y. Hypercrosslinking polymers fabricated from divinyl benzene via Friedel-Crafts addition polymerization. Chinese J. Polym. Sci. 2022, 40, 310–320 DOI： 10.1007/s10118-022-2667-7.

Zheng-Yu Duan, Yan-Yan Wang, Qi-Wei Pan, et al. Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization[J]. Chinese Journal of Polymer Science, 2022, 40(3): 310-320. DOI: 10.1007/s10118-022-2667-7. DOI：

摘要

Abstract

Microporous organic polymers with high surface area are widely used in many applications. Among them

hypercrosslinked polymers have been extensively concerned because of their simple processes and low-cost reagents. However

due to most state-of-the-art strategies for HCPs based on condensation reactions

the release of small molecules such as hydrochloric acid and methanol involved in such strategies brings about new hazards to environment. Herein

we propose a method of fabrication of hypercrosslinked polymers

via

self-addition polymerization of divinyl benzene and its crosslinking with polar aromatic molecules. The hypercrosslinked polyDVB-based products are demonstrated by Friedel-Crafts addition reaction of double bonds on DVB that can connect adjacent phenyl rings of aromatic molecules to form the crosslinked networks. The HCPDVB-CB obtained in 1-chlorobutane as solvent has a high micropore content and displays high surface area up to 931 m

/g. Following this finding

DVB is used as a novel external crosslinker for knitting polar aromatic molecules. When L-phenylalanine and bisphenol A are used as the aromatic units

the obtained HCP(Phe-DVB) and HCP(BPA-DVB) could reach surface area of 612 and 471 m

and have hydrogen uptake of 0.62 wt% and 0.58 wt% at 77 K and 1.13 bar by comparison with HCPDVB-CB having hydrogen uptake of 0.30 wt%

respectively.

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Keywords

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DOI：10.1007/s10118-022-2667-7

摘要

Abstract

关键词

Keywords

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