Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties

Yu-Ting Fang; Feng Gan; Jie Dong; Xin Zhao; Xiu-Ting Li; Qing-Hua Zhang

doi:10.1007/s10118-022-2666-8

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Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties

RESEARCH ARTICLE | Updated：2022-03-23

- Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties
- Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties
- Chinese Journal of Polymer Science 2022年40卷第3期页码：280-289
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.School of Textile Materials and Engineering, Wuyi University, Jiangmen 529020, China
- Author bio：
  
  Lixiuting@dhu.edu.cn (X.T.L.)
  qhzhang@dhu.edu.cn (Q.H.Z.)
- Funds：
  
  This work was ﬁnancially supported by the National Natural Science Foundation of China (Nos. 51903038 and 21975040) and Guangdong Basic and Applied Basic Research Foundation (No. 2020A1515110897).
- DOI：10.1007/s10118-022-2666-8
  中图分类号：
- 收稿：2021-09-30，
  
  修回：2021-10-26，
  
  录用：2021-11-11，
  
  网络首发：2022-01-12，
  
  纸质出版：2022-03-01
- Accepted：
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Fang, Y. T.; Gan, F.; Dong, J.; Zhao, X.; Li, X. T.; Zhang, Q. H. Preparation of high-performance polyimide fibers with wholly rigid structures containing benzobisoxazole moieties. Chinese J. Polym. Sci. 2022, 40, 280–289

Yu-Ting Fang, Feng Gan, Jie Dong, et al. Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties[J]. Chinese Journal of Polymer Science, 2022, 40(3): 280-289.
Fang, Y. T.; Gan, F.; Dong, J.; Zhao, X.; Li, X. T.; Zhang, Q. H. Preparation of high-performance polyimide fibers with wholly rigid structures containing benzobisoxazole moieties. Chinese J. Polym. Sci. 2022, 40, 280–289 DOI： 10.1007/s10118-022-2666-8.

Yu-Ting Fang, Feng Gan, Jie Dong, et al. Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties[J]. Chinese Journal of Polymer Science, 2022, 40(3): 280-289. DOI： 10.1007/s10118-022-2666-8.

摘要

Abstract

In this work

a fully rigid coplanar symmetric heterocyclic unit was introduced into the rigid polyimide macromolecular backbone structure to prepare high-performance polyimide fibers. The novel co-polyimide (co-PI) fibers based on 3

3’

4’-biphenyltetracarboxylic anhydride (BPDA)

-phenylenediamine (PDA) and 2

6-(4

4’-diaminodiphenyl) benzo[1

'] bisoxazole (PBOA) were fabricated

via

a two-step wet-spinning method. The effects of benzobisoxazole moiety on spinnability

aggregation structure

and mechanical properties of fibers were systematically discussed. The detailed structural analysis revealed that the well-defined aggregation structures of co-PI fibers were obtained from initial amorphous structure when post hot-drawing temperature was higher than 460 °C under proper drawing ratio

and the incorporation PBOA into BPDA-PDA structures produced more compact structural co-PI fiber than homo BPDA-PDA fiber. The BPDA-PDA/PBOA co-PI fibers exhibited optimum tensile strength and modulus of 2.65 and 103 GPa

which increased by 182% and 84% compared to the homo BPDA-PDA fiber

respectively.

关键词

Keywords

references

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