High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization

Ning Zhang; Bin Zhang; Yong Pang; Hong-Sheng Yang; Lu Zong; Yong-Xin Duan; Jian-Ming Zhang

doi:10.1007/s10118-022-2664-x

Your Location：

Home >

Browse articles >

High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization

RESEARCH ARTICLE | Updated：2022-03-28

- High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization
- High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization
- Chinese Journal of Polymer Science 2022年40卷第4期页码：373-383
- Affiliations：
  
  a.Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-plastics, Qingdao University of Science & Technology, Qingdao 266042, China
  b.State Key Laboratory of Bio-fibers and Eco-textiles, Qingdao University, Qingdao 266071, China
- Author bio：
  
  dyx@qust.edu.cn (Y.X.D.)
  zjm@qust.edu.cn (J.M.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51773103 and 51603112), Taishan Mountain Scholar Foundation (Nos. TS20081120 and tshw20110510), and State Key Laboratory of Bio-Fibers and Eco-Textiles (Qingdao University) (No. K2019-09).
- DOI：10.1007/s10118-022-2664-x
  中图分类号：
- 收稿：2021-10-05，
  
  修回：2021-10-31，
  
  录用：2021-11-10，
  
  网络首发：2022-01-17，
  
  纸质出版：2022-04-01
- Accepted：
Scan QR Code
Zhang, N.; Zhang, B.; Pang, Y.; Yang, H. S.; Zong, L.; Duan, Y. X.; Zhang, J. M. High performance of PVA nanocomposite reinforced by Janus-like asymmetrically oxidized graphene: synergetic effect of H-bonding interaction and interfacial crystallization. Chinese J. Polym. Sci. 2022, 40, 373–383

Ning Zhang, Bin Zhang, Yong Pang, et al. High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization[J]. Chinese Journal of Polymer Science, 2022, 40(4): 373-383.
Zhang, N.; Zhang, B.; Pang, Y.; Yang, H. S.; Zong, L.; Duan, Y. X.; Zhang, J. M. High performance of PVA nanocomposite reinforced by Janus-like asymmetrically oxidized graphene: synergetic effect of H-bonding interaction and interfacial crystallization. Chinese J. Polym. Sci. 2022, 40, 373–383 DOI： 10.1007/s10118-022-2664-x.

Ning Zhang, Bin Zhang, Yong Pang, et al. High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization[J]. Chinese Journal of Polymer Science, 2022, 40(4): 373-383. DOI： 10.1007/s10118-022-2664-x.

摘要

Abstract

Macromolecule nanocrystal network and strong interfacial interaction are always beneficial to enhance the mechanical property of polymer-based nanocomposites. Poly(vinyl alcohol) (PVA)

a typical biocompatible semicrystalline polymer

is an ideal candidate for preparing high performance polymer-based nanocomposites. However

the rich hydrogen bonds between PVA matrix and graphene oxide (GO) can disrupt the formation of PVA nanocrystal network. Thus

it remains a great challenge to achieve both strong and tough PVA-GO nanocomposites. Herein

by introducing a novel Janus-like amphiphilic graphene oxide (JGO)

both hydrogen bonding and interfacial crystallization have been constructed between JGO sheets and PVA matrix. Benefiting from amphiphilic interfacial interaction and the enhanced crystal network

both PVA-JGO dried films and their swollen hydrogel films show superior mechanical properties than those of traditional PVA-GO nanocomposites. PVA-JGO dried films exhibit a 264% improvement of toughness at a JGO loading of 1 wt%. Meanwhile

the corresponding PVA-JGO swollen hydrogel films display simultaneous improvement of nearly 8 times increase of tensile strength and 20 times increase of toughness compared to traditional PVA-GO nanocomposite. This work indicates multiple interfacial interactions and macromolecule crystal networks can be concurrent in PVA nanocomposites by innovative modification of nanofillers

providing a new strategy to construct PVA nanocomposites with high strength and high toughness. The integration of outstanding mechanical and swelling resistance properties on PVA-JGO nanocomposite films render their promising applications

such as packaging and toughening hydrogel materials.

关键词

Keywords

references

Ye, Y.; Zhang, Y.; Chen, Y.; Han, X.; Jiang, F . Cellulose nanofibrils enhanced, strong, stretchable, freezing-tolerant ionic conductive organohydrogel for multi-functional sensors . Adv. Funct. Mater. , 2020 . 30 2003430 DOI: 10.1002/adfm.202003430 http://doi.org/10.1002/adfm.202003430 .

Chen, W.; Li, N.; Ma, Y.; Minus, M . L.; Benson, K.; Lu, X.; Wang, X.; Ling, X.; Zhu, H. Superstrong and tough hydrogel through physical cross-linking and molecular alignment . Biomacromolecules , 2019 . 20 4476 - 4484 . DOI: 10.1021/acs.biomac.9b01223 http://doi.org/10.1021/acs.biomac.9b01223 .

Lin, S.; Liu, X.; Liu, J.; Yuk, H.; Loh, H. C.; Parada, G. A.; Settens, C.; Song, J.; Masic, A.; McKinley, G. H.; Zhao, X . Anti-fatigue-fracture hydrogels . Sci. Adv. , 2019 . 5 eaau8528 DOI: 10.1126/sciadv.aau8528 http://doi.org/10.1126/sciadv.aau8528 .

Gong, Z.; Zhang, G.; Zeng, X.; Li, J.; Li, G.; Huang, W.; Sun, R.; Wong, C . High-strength, tough, fatigue resistant, and self-healing hydrogel based on dual physically cross-linked network . ACS Appl. Mater. Interfaces , 2016 . 8 24030 - 24037 . DOI: 10.1021/acsami.6b05627 http://doi.org/10.1021/acsami.6b05627 .

Zhang, C.; Liang, K.; Zhou, D.; Yang, H.; Liu, X.; Yin, X.; Xu, W.; Zhou, Y.; Xiao, P . High-performance photopolymerized poly(vinyl alcohol)/silica nanocomposite hydrogels with enhanced cell adhesion . ACS Appl. Mater. Interfaces , 2018 . 10 27692 - 27700 . DOI: 10.1021/acsami.8b09026 http://doi.org/10.1021/acsami.8b09026 .

Marcano, D. C.; Kosynkin, D. V.; Berlin, J. M.; Sinitskii, A.; Sun, Z. Z.; Slesarev, A. S.; Alemany, L. B.; Lu, W.; Tour, J. M . Improved synthesis of graphene oxide (vol 4, pg 4806, 2010) . ACS Nano , 2018 . 12 2078 - 2078 . DOI: 10.1021/acsnano.8b00128 http://doi.org/10.1021/acsnano.8b00128 .

Hu, K.; Kulkarni, D. D.; Choi, I.; Tsukruk, V. V . Graphene-polymer nanocomposites for structural and functional applications . Prog. Polym. Sci. , 2014 . 39 1934 - 1972 . DOI: 10.1016/j.progpolymsci.2014.03.001 http://doi.org/10.1016/j.progpolymsci.2014.03.001 .

Yang, X.; Wang, B.; Sha, D.; Liu, Y.; Liu, Z.; Shi, K.; Liu, W.; Yu, C.; Ji, X . PVA/poly(hexamethylene guanidine)/gallic acid composite hydrogel films and their antibacterial performance . ACS Appl. Polym. Mater. , 2021 . 3 3867 - 3877 . .

Meyer, J. C.; Geim, A. K.; Katsnelson, M. I.; Novoselov, K. S.; Booth, T. J.; Roth, S . The structure of suspended graphene sheets . Nature , 2007 . 446 60 - 63 . DOI: 10.1038/nature05545 http://doi.org/10.1038/nature05545 .

Liang, J.; Huang, Y.; Zhang, L.; Wang, Y.; Ma, Y.; Guo, T.; Chen, Y . Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites . Adv. Funct. Mater. , 2009 . 19 2297 - 2302 . DOI: 10.1002/adfm.200801776 http://doi.org/10.1002/adfm.200801776 .

Zhao, X.; Zhang, Q.; Chen, D.; Lu, P . Enhanced mechanical properties of graphene-based poly(vinyl alcohol) composites . Macromolecules , 2010 . 43 2357 - 2363 . DOI: 10.1021/ma902862u http://doi.org/10.1021/ma902862u .

Putz, K. W.; Compton, O. C.; Palmeri, M. J.; Nguyen, S. T.; Brinson, L. C . High-nanofiller-content graphene oxide-polymer nanocomposites via vacuum-assisted self-assembly . Adv. Funct. Mater. , 2010 . 20 3322 - 3329 . DOI: 10.1002/adfm.201000723 http://doi.org/10.1002/adfm.201000723 .

Bian, Q.; Tian, H.; Wang, Y.; Liu, Q.; Ge, X.; Rajulu, A. V.; Xiang, A . Effect of graphene oxide on the structure and properties of poly(vinyl alcohol) composite films . Polym. Sci. Series A , 2015 . 57 836 - 844 . DOI: 10.1134/S0965545X15060048 http://doi.org/10.1134/S0965545X15060048 .

Panova, T. V.; Efimova, A. A.; Efimov, A. V.; Berkovich, A. K . Physico-mechanical properties of graphene oxide/poly(vinyl alcohol) composites . Colloid. Polym. Sci. , 2019 . 297 485 - 491 . DOI: 10.1007/s00396-018-04465-3 http://doi.org/10.1007/s00396-018-04465-3 .

Kashyap, S.; Pratihar, S. K.; Behera, S. K . Strong and ductile graphene oxide reinforced PVA nanocomposites . J. Alloy. Compd. , 2016 . 684 254 - 260 . DOI: 10.1016/j.jallcom.2016.05.162 http://doi.org/10.1016/j.jallcom.2016.05.162 .

Wang, X.; Liu, X.; Yuan, H.; Liu, H.; Liu, C.; Li, T.; Yan, C.; Yan, X.; Shen, C.; Guo, Z . Non-covalently functionalized graphene strengthened poly(vinyl alcohol) . Mater. Des. , 2018 . 139 372 - 379 . DOI: 10.1016/j.matdes.2017.11.023 http://doi.org/10.1016/j.matdes.2017.11.023 .

Panova, T. V.; Efimova, A. A.; Berkovich, A. K.; Efimov, A. V . Plasticity control of poly(vinyl alcohol)-graphene oxide nanocomposites . RSC Adv. , 2020 . 10 24027 - 24036 . DOI: 10.1039/D0RA04150E http://doi.org/10.1039/D0RA04150E .

Hwang, S. H.; Kang, D.; Ruoff, R. S.; Shin, H. S.; Park, Y. B . Poly(vinyl alcohol) reinforced and toughened with poly(dopamine)-treated graphene oxide, and its use for humidity sensing . ACS Nano , 2014 . 8 6739 - 6747 . DOI: 10.1021/nn500504s http://doi.org/10.1021/nn500504s .

Bao, C.; Guo, Y.; Song, L.; Hu, Y . Poly(vinyl alcohol) nanocomposites based on graphene and graphite oxide: a comparative investigation of property and mechanism . J. Mater. Chem. , 2011 . 21 13942 - 13950 . DOI: 10.1039/c1jm11662b http://doi.org/10.1039/c1jm11662b .

Zhang, Z.; Qin, J.; Diao, H.; Huang, S.; Yin, J.; Zhang, H.; Duan, Y.; Zhang, J . Janus-like asymmetrically oxidized graphene: facile synthesis and distinct liquid crystal alignment at the oil/water interface . Carbon , 2020 . 161 316 - 322 . DOI: 10.1016/j.carbon.2020.01.078 http://doi.org/10.1016/j.carbon.2020.01.078 .

Luo, W.; Zhang, S.; Li, P.; Xu, R.; Zhang, Y.; Liang, L.; Wood, C . D.; Lu, Q.; Tan, B. Surfactant-free CO 2 -in-water emulsion-templated poly(vinyl alcohol) (PVA) hydrogels . Polymer , 2015 . 61 183 - 191 . DOI: 10.1016/j.polymer.2015.02.002 http://doi.org/10.1016/j.polymer.2015.02.002 .

Hou, J. R.; Huang, S. S.; Zhang, N.; Liu, D. Y.; Zhang, Z. J.; Yang, H. S.; Zong, L.; Duan, Y. X.; Zhang, J. M . Reinforcing natural rubber by amphiphilic graphene oxide for high-performance catheters . Polymer , 2021 . 232 124142 DOI: 10.1016/j.polymer.2021.124142 http://doi.org/10.1016/j.polymer.2021.124142 .

Yin, J.; Hou, J. R.; Huang, S. S.; Li, N.; Zhong, M.; Zhang, Z. J.; Geng, Y.; Ding, B. B.; Chen, Y. W.; Duan, Y. X.; Zhang, J. M . Effect of surface chemistry on the dispersion and pH-responsiveness of chitin nanofibers/natural rubber latex nanocomposites . Carbohydr. Polym. , 2019 . 207 555 - 562 . DOI: 10.1016/j.carbpol.2018.12.025 http://doi.org/10.1016/j.carbpol.2018.12.025 .

Huang, S. S.; Hou, J. R.; Yin, J.; Zhang, Z. J.; Ding, B. B.; Duan, Y. X.; Zhang, J. M . Anti-blooming effect of graphene oxide on natural rubber latex composite films . Compos. Sci. Technol. , 2019 . 174 142 - 148 . DOI: 10.1016/j.compscitech.2019.02.027 http://doi.org/10.1016/j.compscitech.2019.02.027 .

Peng, L.; Xu, Z.; Liu, Z.; Wei, Y.; Sun, H.; Li, Z.; Zhao, X.; Gao, C . An iron-based green approach to 1-h production of single-layer graphene oxide . Nat. Commun. , 2015 . 6 5716 DOI: 10.1038/ncomms6716 http://doi.org/10.1038/ncomms6716 .

Stankovich, S.; Dikin, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y.; Wu, Y.; Nguyen, S. T.; Ruoff, R. S . Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide . Carbon , 2007 . 45 1558 - 1565 . DOI: 10.1016/j.carbon.2007.02.034 http://doi.org/10.1016/j.carbon.2007.02.034 .

Grande, R.; Carvalho, A. J . Compatible ternary blends of chitosan/poly(vinyl alcohol)/poly(lactic acid) produced by oil-in-water emulsion processing . Biomacromolecules , 2011 . 12 907 - 914 . DOI: 10.1021/bm101227q http://doi.org/10.1021/bm101227q .

Du, J.; Wang, Y.; Lang, X.; Fan, S . Effects of polyvinyl alcohol on the adhesion force of tetrahydrofuran hydrate particles . Energy Fuel. , 2011 . 25 3204 - 3211 . .

Yu, Y . T.; Zhu, H.; Wang, S. Amphiphilic polyvinyl alcohol adsorbent for the removal of low-density lipoprotein . Artif Cells Nanomed. Biotechnol. , 2015 . 43 117 - 123 . DOI: 10.3109/21691401.2014.909823 http://doi.org/10.3109/21691401.2014.909823 .

Li, H.; Yang, L.; Weng, G.; Xing, W.; Wu, J.; Huang, G . Toughening rubbers with a hybrid filler network of graphene and carbon nanotubes . J. Mater. Chem. A , 2015 . 3 22385 - 22392 . DOI: 10.1039/C5TA05836H http://doi.org/10.1039/C5TA05836H .

Karki, A.; Nguyen, L.; Sharma, B.; Yan, Y.; Chen, W . Unusual morphologies of poly(vinyl alcohol) thin films adsorbed on poly(dimethylsiloxane) substrates . Langmuir , 2016 . 32 3191 - 3198 . DOI: 10.1021/acs.langmuir.6b00470 http://doi.org/10.1021/acs.langmuir.6b00470 .

Barrett, D. A.; Hartshorne, M. S.; Hussain, M. A.; Shaw, P. N.; Davies, M. C . Resistance to nonspecific protein adsorption by poly(vinyl alcohol) thin films adsorbed to a poly(styrene) support matrix studied using surface plasmon resonance . Anal. Chem. , 2001 . 73 5232 - 5239 . DOI: 10.1021/ac010368u http://doi.org/10.1021/ac010368u .

Serizawa, T.; Hashiguchi, S.; Akashi, M . Stepwise assembly of ultrathin poly(vinyl alcohol) films on a gold substrate by repetitive adsorption/drying processes . Langmuir , 1999 . 15 5363 - 5368 . DOI: 10.1021/la9816050 http://doi.org/10.1021/la9816050 .

Minus, M. L.; Chae, H. G.; Kumar, S . Interfacial crystallization in gel-spun poly(vinyl alcohol)/single-wall carbon nanotube composite fibers . Macromo. Chem. Phys. , 2009 . 210 1799 - 1808 . DOI: 10.1002/macp.200900223 http://doi.org/10.1002/macp.200900223 .

Ben Shalom, T.; Nevo, Y.; Leibler, D.; Shtein, Z.; Azerraf, C.; Lapidot, S.; Shoseyov, O . Cellulose nanocrystals (CNCS) induced crystallization of polyvinyl alcohol (PVA) super performing nanocomposite films . Macromol. Biosci. , 2019 . e1800347 .

Ning, N.; Fu, S.; Zhang, W.; Chen, F.; Wang, K.; Deng, H.; Zhang, Q.; Fu, Q . Realizing the enhancement of interfacial interaction in semicrystalline polymer/filler composites via interfacial crystallization . Prog. Polym. Sci. , 2012 . 37 1425 - 1455 . DOI: 10.1016/j.progpolymsci.2011.12.005 http://doi.org/10.1016/j.progpolymsci.2011.12.005 .

Miltner, H. E.; Grossiord, N.; Lu, K.; Loos, J.; Koning, C. E.; Van Mele, B . Isotactic polypropylene/carbon nanotube composites prepared by latex technology. thermal analysis of carbon nanotube-induced nucleation . Macromolecules , 2008 . 41 ( 15 ): 5753 - 5762 . DOI: 10.1021/ma800643j http://doi.org/10.1021/ma800643j .

Tanabe, Y.; Strobl, G. R.; Fischer, E. W . Surface melting in melt-crystallized linear polyethylene . Polymer , 1986 . 27 1147 - 1153 . DOI: 10.1016/0032-3861(86)90001-7 http://doi.org/10.1016/0032-3861(86)90001-7 .

Chen, L.; Zheng, K.; Tian, X.; Hu, K.; Wang, R.; Liu, C.; Li, Y.; Cui, P . Double glass transitions and interfacial immobilized layer in in-situ -synthesized poly(vinyl alcohol)/silica nanocomposites . Macromolecules , 2009 . 43 1076 - 1082 . .

Gowd, E . B.; Shibayama, N.; Tashiro, K. Structural correlation between crystal lattice and lamellar morphology in the phase transitions of uniaxially oriented syndiotactic polystyrene ( δ and δ (e) forms) as revealed by simultaneous measurements of wide-angle and small-angle X-ray scatterings . Macromolecules , 2008 . 41 2541 - 2547 . DOI: 10.1021/ma071759z http://doi.org/10.1021/ma071759z .

Bunn, C. W . Crystal structure of polyvinyl alcohol . Nature , 1948 . 161 929 - 930 . DOI: 10.1038/161929a0 http://doi.org/10.1038/161929a0 .

Chi, E.; An, M.; Yao, G.; Tian, F.; Wang, Z . The influence of epitaxial crystallization on the mechanical properties of polyamide 66/reduced graphene oxide nanocomposite injection bar . Crystals , 2017 . 7 384 DOI: 10.3390/cryst7120384 http://doi.org/10.3390/cryst7120384 .

Miao, W.; Wu, F.; Zhou, S.; Yao, G.; Li, Y.; Wang, Z . Epitaxial crystallization of poly( ε -caprolactone) on reduced graphene oxide at a low shear rate by in situ SAXS/WAXD methods . ACS Omega , 2020 . 5 31535 - 31542 . DOI: 10.1021/acsomega.0c03410 http://doi.org/10.1021/acsomega.0c03410 .

Kozlov, M.; Quarmyne, M.; Chen, W.; McCarthy, T. J . Adsorption of poly(vinyl alcohol) onto hydrophobic substrates. A general approach for hydrophilizing and chemically activating surfaces . Macromolecules , 2003 . 36 6054 - 6059 . DOI: 10.1021/ma021681g http://doi.org/10.1021/ma021681g .

Miyazaki, T.; Miyata, N.; Asada, M.; Tsumura, Y.; Torikai, N.; Aoki, H.; Yamamoto, K.; Kanaya, T.; Kawaguchi, D.; Tanaka, K . Elucidation of a heterogeneous layered structure in the thickness direction of poly(vinyl alcohol) films with solvent vapor-induced swelling . Langmuir , 2019 . 35 11099 - 11107 . DOI: 10.1021/acs.langmuir.9b01665 http://doi.org/10.1021/acs.langmuir.9b01665 .

Miyazaki, T.; Miyata, N.; Yoshida, T.; Arima, H.; Tsumura, Y.; Torikai, N.; Aoki, H.; Yamamoto, K.; Kanaya, T.; Kawaguchi, D.; Tanaka, K . Detailed structural study on the poly(vinyl alcohol) adsorption layers on a si substrate with solvent vapor-induced swelling . Langmuir , 2020 . 36 3415 - 3424 . DOI: 10.1021/acs.langmuir.9b03964 http://doi.org/10.1021/acs.langmuir.9b03964 .

浏览量

215

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Biodegradable Alginate-based Fibers with High Mechanical Performance and Aqueous Stability via Stretch-mediated Network Engineering

Stable Integration of Hydrophobic Silica Aerogels into Rubber Latex via Poly(vinyl alcohol)-assisted Aqueous Processing for Thermal Insulating Composites

Sustainable Flame-retardant and Tough Poly(vinyl alcohol) Films with Phytic Acid and Biochar: A Simple and Effective Approach

One-handed Helical Poly(m-terphenyl acetylene)s with Broad Optical Activity Range from Ultraviolet-Visible to Near-infrared Regions

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst