CO<sub>2</sub>-based Biodegradable Supramolecular Polymers with Well-tunable Adhesive Properties

Xiao-Jing Li; Ying-Feng Wen; Yong Wang; Hai-Yan Peng; Xing-Ping Zhou; Xiao-Lin Xie

doi:10.1007/s10118-021-2641-9

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CO₂-based Biodegradable Supramolecular Polymers with Well-tunable Adhesive Properties

Papers | Updated：2021-11-09

- CO₂-based Biodegradable Supramolecular Polymers with Well-tunable Adhesive Properties
- CO₂-based Biodegradable Supramolecular Polymers with Well-tunable Adhesive Properties
- Chinese Journal of Polymer Science 2022年40卷第1期页码：47-55
- Affiliations：
  
  Key Laboratory for Material Chemistry of Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
- Author bio：
  
  tcwy@mail.hust.edu.cn (Y.W.)
  xpzhou@mail.hust.edu.cn (X.P.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 21604027), National Key R&D Plan of China (No.2016YFB0302400) as well as the analytical and testing assistance from the Analysis and Testing Centre of HUST.
- DOI：10.1007/s10118-021-2641-9
  中图分类号：
- 收稿：2021-06-25，
  
  修回：2021-8-4，
  
  录用：2021-8-19，
  
  网络首发：2021-11-09，
  
  纸质出版：2022-01-01
- Accepted：
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Li, X. J.; Wen, Y. F.; Wang, Y.; Peng, H. Y.; Zhou, X. P.; Xie, X. L. CO₂-based biodegradable supramolecular polymers with well-tunable adhesive properties. Chinese J. Polym. Sci. 2022, 40, 47–55 DOI: 10.1007/s10118-021-2641-9.

Xiao-Jing Li, Ying-Feng Wen, Yong Wang, et al. CO₂-based Biodegradable Supramolecular Polymers with Well-tunable Adhesive Properties[J]. Chinese Journal of Polymer Science, 2022, 40(1): 47-55. DOI: 10.1007/s10118-021-2641-9.
Li, X. J.; Wen, Y. F.; Wang, Y.; Peng, H. Y.; Zhou, X. P.; Xie, X. L. CO₂-based biodegradable supramolecular polymers with well-tunable adhesive properties. Chinese J. Polym. Sci. 2022, 40, 47–55 DOI: 10.1007/s10118-021-2641-9. DOI：

Xiao-Jing Li, Ying-Feng Wen, Yong Wang, et al. CO₂-based Biodegradable Supramolecular Polymers with Well-tunable Adhesive Properties[J]. Chinese Journal of Polymer Science, 2022, 40(1): 47-55. DOI: 10.1007/s10118-021-2641-9. DOI：

摘要

Abstract

Supramolecular adhesives that enable debonding on-demand are of significant research interest for the development of adaptive and smart materials

yet

biodegrable supramolecular adhesives have been rarely exploited. Herein

telechelic

three-armed and four-armed CO

-based polyols with close molecular weights and various CO

content (or carbonate unite content) have been synthesized

via

a zinc-cobalt double metal cyanide complex catalyzed ring-opening copolymerization of CO

and propylene oxide

and further exploited as sustainable and biodegradable building blocks for supramolecular polymers (SMPs) with 2-ureido-4[1

]-pyrimidinone (UPy) motifs. Notably

the orthogonal modulation of the CO

content and the topology of CO

-based polyols provide a unique opportunity to fine-tune the surface energy as well as the cohesive strength of the resulting CO

-based SMPs. Notably

a three-armed SMP with 44% CO

(3UPy-CO

-44%) can well balance the trade-off between surface energy and cohesive strength

therefore bestowing a high adhesive strength of 7.5 and 9.7 MPa towards stainless steel and wood substrates respectively by testing the corresponding single lap joints. Moreover

the light-responsive adhesion property of 3UPy-CO

-44% has been demonstrated exemplarily by blending with a UV sensitizer.

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Keywords

references

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DOI：10.1007/s10118-021-2641-9

摘要

Abstract

关键词

Keywords

references

CO₂-based Biodegradable Supramolecular Polymers with Well-tunable Adhesive Properties

CO₂-based Biodegradable Supramolecular Polymers with Well-tunable Adhesive Properties