High Performance Electrospun Polynaphthalimide Nanofibrous Membranes with Excellent Resistance to Chemically Harsh Conditions

Meng-Jie Yuan; Zhao-Yu Hu; Hong Fang; Shu-Jing Li; Hong-Tao Guo; Ru-Bei Hu; Shao-Hua Jiang; Kun-Ming Liu; Hao-Qing Hou

doi:10.1007/s10118-021-2634-8

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High Performance Electrospun Polynaphthalimide Nanofibrous Membranes with Excellent Resistance to Chemically Harsh Conditions

ARTICLE | Updated：2021-09-06

- High Performance Electrospun Polynaphthalimide Nanofibrous Membranes with Excellent Resistance to Chemically Harsh Conditions
- High Performance Electrospun Polynaphthalimide Nanofibrous Membranes with Excellent Resistance to Chemically Harsh Conditions
- Chinese Journal of Polymer Science 2021年39卷第12期页码：1634-1644
- Affiliations：
  
  a.Department of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
  b.Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
  c.Shandong Key Laboratory of Biochemical Analysis; College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
  d.Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China
- Author bio：
  
  shaohua.jiang@njfu.edu.cn (S.H.J.)
  haoqing@jxnu.edu.cn (H.Q.H.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21975111, 21774053, and 51803093), Natural Science Foundation of Jiangsu Province (No. BK20180770) and Open Project of Chemistry Department of Qingdao University of Science and Technology (No. QUSTHX201921).
- DOI：10.1007/s10118-021-2634-8
  中图分类号：
- 收稿：2021-06-04，
  
  修回：2021-1-1，
  
  录用：2021-7-30，
  
  网络首发：2021-09-06，
  
  纸质出版：2021-10-18
- Accepted：
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Yuan, M. J.; Hu, Z. Y.; Fang, H.; Li, S. J.; Guo, H. T.; Hu, R. B.; Jiang, S. H.; Liu, K. M.; Hou, H. Q. High performance electrospun polynaphthalimide nanofibrous membranes with excellent resistance to chemically harsh conditions. Chinese J. Polym. Sci. 2021, 39, 1634–1644

Meng-Jie Yuan, Zhao-Yu Hu, Hong Fang, et al. High Performance Electrospun Polynaphthalimide Nanofibrous Membranes with Excellent Resistance to Chemically Harsh Conditions[J]. Chinese Journal of Polymer Science, 2021, 39(12): 1634-1644.
Yuan, M. J.; Hu, Z. Y.; Fang, H.; Li, S. J.; Guo, H. T.; Hu, R. B.; Jiang, S. H.; Liu, K. M.; Hou, H. Q. High performance electrospun polynaphthalimide nanofibrous membranes with excellent resistance to chemically harsh conditions. Chinese J. Polym. Sci. 2021, 39, 1634–1644 DOI： 10.1007/s10118-021-2634-8.

Meng-Jie Yuan, Zhao-Yu Hu, Hong Fang, et al. High Performance Electrospun Polynaphthalimide Nanofibrous Membranes with Excellent Resistance to Chemically Harsh Conditions[J]. Chinese Journal of Polymer Science, 2021, 39(12): 1634-1644. DOI： 10.1007/s10118-021-2634-8.

摘要

Abstract

Polynaphthalimide (PNI) with six-membered imide ring (

-PI) has better chemical resistance than five-membered imide ring (

-PI)

but is difficult to be processed into nanofibers due to the poor processability. In this work

we proposed a template strategy to fabricate nanofiber

-PI membranes and their composite membranes. Neat

-PI and

-PI composite fibrous membranes were prepared using high-molecular-weight polymers

-PAA and PVP as templates by electrospinning. FTIR

DMA

TGA and tensile tests were used to characterize their chemical structures

thermal stability and mechanical properties. Further eye-observation

micro-morphology investigation and tensile tests were applied to evaluate the chemical resistance of nanofibrous membranes in strong acid

strong alkaline

and concentrated salt. The results demonstrated that

-PI nanofibrous membranes possessed the best thermal stability

best acid

alkaline

and salt resistance with the highest mechanical retention. This study will provide basic information for high-performance electrospun

-PI nanofiber membranes and provide opportunities for applications of PIs in different chemically harsh environments.

关键词

Keywords

references

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