Self-healing Polymeric Hydrogels: Toward Multifunctional Soft Smart Materials

Xiao-Ling Zuo; Shao-Fan Wang; Xiao-Xia Le; Wei Lu; Tao Chen

doi:10.1007/s10118-021-2612-1

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Self-healing Polymeric Hydrogels: Toward Multifunctional Soft Smart Materials

REVIEW | Updated：2021-07-25

- Self-healing Polymeric Hydrogels: Toward Multifunctional Soft Smart Materials
- Self-healing Polymeric Hydrogels: Toward Multifunctional Soft Smart Materials
- Chinese Journal of Polymer Science 2021年39卷第10期页码：1262-1280
- Affiliations：
  
  a.College of Materials Science and Engineering, Guizhou Minzu University, Guiyang 550025, China
  b.Key Laboratory of Bio-Based Polymeric Materials Technology and Application of Zhejiang Province, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  c.School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  luwei@nimte.ac.cn (W.L.)
  tao.chen@nimte.ac.cn (T.C.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51773215, 21774138), the Sino-German Mobility Programme (No. M-0424), Key Research Program of Frontier Sciences, Chinese Academy of Sciences (No. QYZDB-SSW-SLH036), and Youth Innovation Promotion Association of Chinese Academy of Sciences (No. 2019297). Xiaoling Zuo is grateful for the financial supported by Science and Technology Fund of Guizhou Province, China (No. [2020]1Y209), the Overseas Talents Selection Fund of Guizhou Province, China (No. [2020]11) and Fund Project of Guizhou Minzu University, China (No. GZMU[2019]YB23).
- DOI：10.1007/s10118-021-2612-1
  中图分类号：
- 收稿：2021-04-13，
  
  修回：2021-1-1，
  
  录用：2021-5-25，
  
  网络首发：2021-07-25，
  
  纸质出版：2021-08-20
- Accepted：
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Zuo, X. L.; Wang, S. F.; Le, X. X.; Lu, W.; Chen, T. Self-healing polymeric hydrogels: toward multifunctional soft smart materials. Chinese J. Polym. Sci. 2021, 39, 1262–1280

Xiao-Ling Zuo, Shao-Fan Wang, Xiao-Xia Le, et al. Self-healing Polymeric Hydrogels: Toward Multifunctional Soft Smart Materials[J]. Chinese Journal of Polymer Science, 2021, 39(10): 1262-1280.
Zuo, X. L.; Wang, S. F.; Le, X. X.; Lu, W.; Chen, T. Self-healing polymeric hydrogels: toward multifunctional soft smart materials. Chinese J. Polym. Sci. 2021, 39, 1262–1280 DOI： 10.1007/s10118-021-2612-1.

Xiao-Ling Zuo, Shao-Fan Wang, Xiao-Xia Le, et al. Self-healing Polymeric Hydrogels: Toward Multifunctional Soft Smart Materials[J]. Chinese Journal of Polymer Science, 2021, 39(10): 1262-1280. DOI： 10.1007/s10118-021-2612-1.

摘要

Abstract

The concept of self-healing that involves a built-in ability to heal in response to damage wherever and whenever it occurs in a material

analogous to the healing process in living organisms

has emerged a couple of decades ago. Driven primarily by the demands for life-like materials and soft smart materials

therefore

the development of self-healing polymeric hydrogels has continually attracted the attention of the scientific community. Here

this review is intended to give an in-depth overview of the state-of-the-art advances in the field of self-healing polymeric hydrogels. Specifically

recently emerging trends in self-healing polymeric hydrogels are summarized

and notably

recommendations to endow these hydrogels with fascinating multi-functionalities including luminescence

conductivity/magnetism and shape memory

etc.

are presented. To close

the current challenges and future opportunities in this field are also discussed.

关键词

Keywords

references

Shang, J. J.; Le, X. X.; Zhang, J. W.; Chen, T.; Theato, P . Trends in polymeric shape memory hydrogels and hydrogel actuators . Polym. Chem. , 2019 . 10 1036 - 1055 . DOI: 10.1039/C8PY01286E http://doi.org/10.1039/C8PY01286E .

Wichterle, O.; Lim, D . Hydrophilic gels for biological use . Nature , 1960 . 185 117 - 118 . DOI: 10.1038/185117a0 http://doi.org/10.1038/185117a0 .

Wheeler, J. C.; Woods, J. A.; Cox, M. J.; Cantrell, R. W.; Watkins, F. H.; Edlich, R. F . Evolution of hydrogel polymers as contact lenses, surface coatings, dressings, and drug delivery systems . J. Long Term Eff. Med. Implants. , 1996 . 6 207 - 217 . .

Jeon, I.; Cui, J. X.; Illeperuma, W. R. K.; Aizenberg, J.; Vlassak, J. J . Extremely stretchable and fast self-healing hydrogels . Adv. Mater. , 2016 . 28 4678 - 4683 . DOI: 10.1002/adma.201600480 http://doi.org/10.1002/adma.201600480 .

Phadke, A.; Zhang, C.; Arman, B.; Hsu, C. C.; Mashelkar, R. A.; Lele, A. K.; Tauber, M. J.; Arya, G.; Varghese, S . Rapid self-healing hydrogels . Proc. Natl. Acad. Sci. USA , 2012 . 109 4383 - 4388 . DOI: 10.1073/pnas.1201122109 http://doi.org/10.1073/pnas.1201122109 .

Cai, L. L.; Liu, S.; Guo, J. W.; Jia, Y. G . Polypeptide-based self-healing hydrogels: design and biomedical applications . Acta Biomat. , 2020 . 113 84 - 100 . DOI: 10.1016/j.actbio.2020.07.001 http://doi.org/10.1016/j.actbio.2020.07.001 .

Wei, Z.; Yang, J. H.; Zhou, J. X.; Xu, F.; Zrinyi, M.; Dussault, P. H.; Osada, Y.; Chen, Y. M . Self-healing gels based on constitutional dynamic chemistry and their potential applications . Chem. Soc. Rev. , 2014 . 43 8114 - 8131 . DOI: 10.1039/C4CS00219A http://doi.org/10.1039/C4CS00219A .

Yang, Y.; Ding, X. C.; Urban, M. W . Chemical and physical aspects of self-healing materials . Prog. Polym. Sci. , 2015 . 49−50 34 - 59 . DOI: 10.1016/j.progpolymsci.2015.06.001 http://doi.org/10.1016/j.progpolymsci.2015.06.001 .

Ahn, B. K.; Lee, D. W.; Israelachvili, J. N.; Waite, J. H . Surface-initiated self-healing of polymers in aqueous media . Nat. Mater. , 2014 . 13 867 - 872 . DOI: 10.1038/nmat4037 http://doi.org/10.1038/nmat4037 .

Eyring, H . Plasticity, and diffusion as examples of absolute reaction rates . J. Chem. Phys , 1936 . 4 283 - 291 . DOI: 10.1063/1.1749836 http://doi.org/10.1063/1.1749836 .

Taylor, D. L.; Panhuis, M. I. H . Self-healing hydrogels . Adv. Mater. , 2016 . 28 9060 - 9093 . DOI: 10.1002/adma.201601613 http://doi.org/10.1002/adma.201601613 .

Mondal, S.; Das, S.; Nandi, A. K . A review on recent advances in polymer and peptide hydrogels . Soft Matter , 2020 . 16 1404 - 1454 . DOI: 10.1039/C9SM02127B http://doi.org/10.1039/C9SM02127B .

Chen, J.; Huang, Y. K.; Ma, X. Y.; Lei, Y . Functional self-healing materials and their potential applications in biomedical engineering . Adv. Compos. Hybrid Mater. , 2018 . 1 94 - 113 . DOI: 10.1007/s42114-017-0009-y http://doi.org/10.1007/s42114-017-0009-y .

Yin, Q. Y.; Dai, C. H.; Chen, H.; Gou, K.; Guan, H. Z.; Wang, P. H.; Jiang, J. T.; Weng, G. S . Tough double metal-ion cross-linked elastomers with temperature-adaptable self-healing and luminescence properties . Chinese J. Polym. Sci. , 2021 . 39 554 - 565 . DOI: 10.1007/s10118-021-2517-z http://doi.org/10.1007/s10118-021-2517-z .

Li, C. H.; Zuo, J. L . Self-healing polymers based on coordination bonds . Adv. Mater. , 2020 . 32 1903762 .

Xun, X. C.; Zhang, Z.; Zhao, X.; Zhao, B.; Gao, F. F.; Kang, Z.; Liao, Q. L.; Zhang, Y . Highly robust and self-powered electronic skin based on tough conductive self-healing elastomer . ACS Nano , 2020 . 14 9066 - 9072 . DOI: 10.1021/acsnano.0c04158 http://doi.org/10.1021/acsnano.0c04158 .

Sima, W. X.; Shao, Q. Q.; Sun, P. T.; Liang, C.; Yang, M.; Yin, Z.; Deng, Q . Magnetically gradient-distributed microcapsule/epoxy composites: Low capsule load and highly targeted self-healing performance . Chem. Eng. J. , 2021 . 405 126908 DOI: 10.1016/j.cej.2020.126908 http://doi.org/10.1016/j.cej.2020.126908 .

Hornat, C. C.; Urban, M. W . Shape memory effects in self-healing polymers . Prog. Polym. Sci. , 2020 . 102 101208 DOI: 10.1016/j.progpolymsci.2020.101208 http://doi.org/10.1016/j.progpolymsci.2020.101208 .

Zhu, D. Y.; Rong, M. Z.; Zhang, M. Q . Self-healing polymers and composites . Prog. Polym. Sci. , 2015 . 49-50 175 - 220 . DOI: 10.1016/j.progpolymsci.2015.07.002 http://doi.org/10.1016/j.progpolymsci.2015.07.002 .

Blaiszik, B. J.; Kramer, S. L. B.; Olugebefola, S. C.; Moore, J. S. Sottos, N. R.; White, S. R . Self-healing polymers and composites . Annu. Rev. Mater. Res. , 2010 . 40 179 - 211 . DOI: 10.1146/annurev-matsci-070909-104532 http://doi.org/10.1146/annurev-matsci-070909-104532 .

Liu, J.; Zhang, X. C.; Chen, X.; Qu, L. L . Stimuli-responsive dendronized polymeric hydrogels through Schiff-base chemistry showing remarkable topological effects . Polym. Chem. , 2018 . 9 378 - 387 . DOI: 10.1039/C7PY01865G http://doi.org/10.1039/C7PY01865G .

Neal, J. A.; Mozhdehi, D.; Guan, Z. B . Enhancing mechanical performance of a covalent self-healing material by sacrificial noncovalent bonds . J. Am. Chem. Soc. , 2015 . 137 4846 - 4850 . DOI: 10.1021/jacs.5b01601 http://doi.org/10.1021/jacs.5b01601 .

Gao, Z. Y.; Gotland, B.; Tronci, G.; Thornton, P. D. . A redox-responsive hyaluronic acid-based hydrogel for chronic wound management . J. Mater. Chem. B , 2019 . 7 7494 - 7501 . DOI: 10.1039/C9TB01683J http://doi.org/10.1039/C9TB01683J .

Zhang, Y. C.; Le, X. X.; Jian, Y. K.; Lu, W.; Zhang, J. W.; Chen, T . 3D fluorescent hydrogel origami for multistage data security protection . Adv. Funct. Mater. , 2019 . 29 1905514 DOI: 10.1002/adfm.201905514 http://doi.org/10.1002/adfm.201905514 .

Meng, H.; Xiao, P.; Gu, J. C.; Wen, X. F.; Xu, J.; Zhao, C. Z.; Zhang, J. W.; Chen, T . Self-healable macro-/microscopic shape memory hydrogels based on supramolecular interactions . Chem. Commun. , 2014 . 50 12277 DOI: 10.1039/C4CC04760E http://doi.org/10.1039/C4CC04760E .

Shao, C. Y.; Wang, M.; Chang, H. L.; Xu, F.; Yang, J . A self-Healing cellulose nanocrystal-poly(ethylene glycol) nanocomposite hydrogel via Diels-Alder click reaction . ACS Sustain. Chem. Eng. , 2017 . 5 6167 - 6174 . DOI: 10.1021/acssuschemeng.7b01060 http://doi.org/10.1021/acssuschemeng.7b01060 .

Xia, N. N.; Xiong, X. M.; Rong, M. Z.; Zhang, M. Q.; Kong, F . Self-healing of polymer in acidic water toward strength restoration through the synergistic effect of hydrophilic and hydrophobic interactions . ACS Appl. Mater. Interfaces , 2017 . 9 37300 - 37309 . DOI: 10.1021/acsami.7b11230 http://doi.org/10.1021/acsami.7b11230 .

Wang, Y. M.; Huang, F. R.; Chen, X. B.; Wang, X. W.; Zhang, W. B.; Peng, J.; Li, J. Q.; Zhai, M. L . Stretchable, conductive, and self-healing hydrogel with super metal adhesion . Chem. Mater. , 2018 . 30 4289 - 4297 . DOI: 10.1021/acs.chemmater.8b01260 http://doi.org/10.1021/acs.chemmater.8b01260 .

Tamate, R.; Hashimoto, K.; Horii, T.; Hirasawa, M.; Li, X.; Shibayama, M.; Watanabe, M . Synthesis of particulate hierarchical tandem heterojunctions toward optimized photocatalytic hydrogen production . Adv. Mater. , 2018 . 30 1802792 DOI: 10.1002/adma.201802792 http://doi.org/10.1002/adma.201802792 .

Li, L.; Yan, B.; Yang, J.; Chen, L.; Zeng, H . Novel mussel-inspired injectable self-healing hydrogel with anti-biofouling property . Adv. Mater , 2015 . 27 1294 - 1299 . DOI: 10.1002/adma.201405166 http://doi.org/10.1002/adma.201405166 .

Nishimura, T.; Sum, N.; Mukai, S. A.; Sasaki, Y.; Akiyoshi, K . Supramacromolecular injectable hydrogels by crystallization-driven self-assembly of carbohydrate-conjugated poly(2-isopropyloxazoline)s for biomedical applications . J. Mater. Chem. B , 2019 . 7 6362 - 6369 . DOI: 10.1039/C9TB00918C http://doi.org/10.1039/C9TB00918C .

Nakahata, M.; Takashima, Y. Harada, A . Highly flexible, tough, and self-healing supramolecular polymeric materials using host-guest interaction . Macromol. Rapid Commun. , 2016 . 37 86 - 92 . DOI: 10.1002/marc.201500473 http://doi.org/10.1002/marc.201500473 .

Wei, Z. J.; He, J.; Liang, T.; Oh, H.; Athas, J.; Tong, Z.; Wang, C. Y.; Nie, Z. H . Autonomous self-healing of poly(acrylic acid) hydrogels induced by the migration of ferric ions . Polym. Chem. , 2013 . 4 4601 - 4605 . DOI: 10.1039/c3py00692a http://doi.org/10.1039/c3py00692a .

Wei, S. X.; Li, Z.; Lu, W.; Liu, H.; Zhang, J. W.; Chen, T.; Tang, B. Z . Multicolor fluorescent polymeric hydrogels: colorfulness is more shining than homochromy . Angew. Chem. Int. Ed. , 2021 . 60 8608 - 8624 . DOI: 10.1002/anie.202007506 http://doi.org/10.1002/anie.202007506 .

Peivandi, A.; Tian, L.; Mahabir, R.; Hosseinidoust, Z . Hierarchically structured, self-healing, fluorescent, bioactive hydrogels with self-organizing bundles of phage nanofilaments . Chem. Mater , 2019 . 31 5442 - 5449 . DOI: 10.1021/acs.chemmater.9b00720 http://doi.org/10.1021/acs.chemmater.9b00720 .

Zhang, Y. D. Y.; Ding, Z. Y.; Liu, Y.; Zhang, Y. P.; Jiang, S. M. . White-light-emitting hydrogels with self-healing properties and adjustable emission colors . J. Colloid Interf. Sci , 2021 . 582 825 - 833 . DOI: 10.1016/j.jcis.2020.08.080 http://doi.org/10.1016/j.jcis.2020.08.080 .

Zhu, C. N.; Bai, T. W.; Wang, H.; Bai, W.; Ling, J.; Sun, J. Z. Huang, F. H.; Wu, Z. L.; Zheng, Q . Single chromophore-based white-light-emitting hydrogel with tunable fluorescence and patternability . ACS Appl. Nano Mater. , 2018 . 10 39343 - 39352 . DOI: 10.1021/acsami.8b12619 http://doi.org/10.1021/acsami.8b12619 .

Zhao, Q.; Chen, Y.; Li, S. H.; Liu, Y . Tunable white-light emission by supramolecular self-sorting in highly swollen hydrogels . Chem. Commun. , 2018 . 54 200 - 203 . DOI: 10.1039/C7CC08822A http://doi.org/10.1039/C7CC08822A .

Yang, D. Q.; Wang, Y. G.; Li, Z. Q.; Xu, Y.; Cheng, F.; Li, P.; Li, H. R . Color-tunable luminescent hydrogels with tough mechanical strength and self-healing ability . J. Mater. Chem. C , 2018 . 6 1153 - 1159 . DOI: 10.1039/C7TC05593E http://doi.org/10.1039/C7TC05593E .

Chen, H.; Ma, X.; Wu, S. F.; Tian, H . A rapidly self-healing supramolecular polymer hydrogel with photostimulated room-temperature phosphorescence responsiveness . Angew. Chem. Int. Ed. , 2014 . 126 14373 - 14376 . DOI: 10.1002/ange.201407402 http://doi.org/10.1002/ange.201407402 .

Li, B.; Lin, C. L.; Lu, C. J.; Zhang, J. J.; He, T.; Qiu, H. Y.; Yin, S. C . Rapid and reversible thermochromic supramolecular polymer hydrogel and its application in protected quick response code . Mater. Chem. Front. , 2020 . 4 869 - 874 . DOI: 10.1039/C9QM00699K http://doi.org/10.1039/C9QM00699K .

Xie, S. W.; Ren, B. P.; Gong, G.; Zhang, D.; Chen, Y.; Xu, L. J.; Zhang, C. F.; Xu, J. X.; Zheng, J . Lanthanide-doped upconversion nanoparticle-cross-linked double-network hydrogels with strong bulk/interfacial toughness and tunable full-color fluorescence for bioimaging and biosensing . ACS Appl. Nano Mater. , 2020 . 3 2774 - 2786 . DOI: 10.1021/acsanm.0c00105 http://doi.org/10.1021/acsanm.0c00105 .

Luo, J. D.; Xie, Z. L.; Lam, J. W. Y.; Cheng, L.; Chen, H. Y.; Qiu, C. F.; Kwok, H. S.; Zhan, X. W.; Liu, Y. Q.; Zhu, D. B.; Tang, B. Z . Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole . Chem. Commun. , 2001 . 1740 - 1741 . DOI: 10.1039/B105159H http://doi.org/10.1039/B105159H .

Li, J.; Wang, J. X.; Li, H. X.; Song, N.; Wang, D.; Tang, B. Z . Supramolecular materials based on AIE luminogens (AIEgens): construction and applications . Chem. Soc. Rev. , 2020 . 49 1144 - 1172 . DOI: 10.1039/C9CS00495E http://doi.org/10.1039/C9CS00495E .

Ji, X. F.; Li, Z.; Hu, Y. B.; Xie, H. L.; Wu, W. J.; Song, F. Y.; Liu, H. X.; Wang, J. G.; Jiang, M. J.; Lam, J. W. Y.; Tang, B. Z . Bioinspired hydrogels with muscle-like structure for AIEgen-guided selective self-healing . CCS Chem. , 2020 . 3 1146 - 1156 . DOI: 10.31635/ccschem.020.202000302 http://doi.org/10.31635/ccschem.020.202000302 .

Guaresti, O.; Crocker, L.; Palomares, T.; Alonso-Varona, A.; Eceiza, A.; Fruk, L.; Gabilondo, N . Light-driven assembly of biocompatible fluorescent chitosan hydrogels with self-healing ability . J. Mater. Chem. B , 2020 . 8 9804 - 9811 . DOI: 10.1039/D0TB01746A http://doi.org/10.1039/D0TB01746A .

Ma, C. X.; Lu, W.; Yang, X. X.; He, J.; Le, X. X.; Wang, L.; Zhang, J. W.; Serpe, M. J.; Huang, Y. J.; Chen, T . Bioinspired anisotropic hydrogel actuators with on-off switchable and color-tunable fluorescence behaviors . Adv. Funct. Mater. , 2018 . 28 1704568 DOI: 10.1002/adfm.201704568 http://doi.org/10.1002/adfm.201704568 .

Wu, B. Y.; Le, X. X.; Jian, Y. K.; Lu, W.; Yang, Z. Y.; Zheng, Z. K.; Theato, P.; Zhang, J. W.; Zhang, A.; Chen, T . pH and thermo dual-responsive fluorescent hydrogel actuator . Macromol. Rapid Commun. , 2019 . 40 1800648 DOI: 10.1002/marc.201800648 http://doi.org/10.1002/marc.201800648 .

Deng, Z. X.; Wang, H.; Ma, P. X.; Guo, B. L . Self-healing conductive hydrogels: preparation, properties and applications . Nanoscale , 2020 . 12 1224 - 1246 . DOI: 10.1039/C9NR09283H http://doi.org/10.1039/C9NR09283H .

Bao, R.; Tan, B. Y.; Liang, S.; Zhang, N.;. Wang, W; Liu, W. G . A π - π conjugation-containing soft and conductive injectable polymer hydrogel highly efficiently rebuilds cardiac function after myocardial infarction . Biomaterials , 2017 . 122 63 - 71 . DOI: 10.1016/j.biomaterials.2017.01.012 http://doi.org/10.1016/j.biomaterials.2017.01.012 .

Gao, G. R.; Yang, F. G.; Zhou, F. H.; He, J.; Lu, W.; Xiao, P.; Yan, H. Z.; Pan, C. F.; Chen, T.; Wang, Z. L . Bioinspired self-healing human-machine interactive touch pad with pressure-sensitive adhesiveness on targeted substrates . Adv. Mater. , 2020 . 32 2004290 DOI: 10.1002/adma.202004290 http://doi.org/10.1002/adma.202004290 .

Darabi, M. A.; Khosrozadeh, A.; Mbeleck, R.; Liu, Y. Q.; Chang, Q.; Jiang, J. Z.; Cai, J.; Wang, Q.; Luo, G. X.; Xing, M . Skin-inspired multifunctional autonomic-intrinsic conductive self-healing hydrogels with pressure sensitivity, stretchability, and 3D printability . Adv. Mater. , 2018 . 30 1705922 DOI: 10.1002/adma.201705922 http://doi.org/10.1002/adma.201705922 .

Shuai, L. Y. Z.; Guo, Z. H.; Zhang, P. P.; Wan, J. M.; Pu, X.; Wang, Z. L . Stretchable, self-healing, conductive hydrogel fibers for strain sensing and triboelectric energy-harvesting smart textiles . Nano Energy , 2020 . 78 105389 DOI: 10.1016/j.nanoen.2020.105389 http://doi.org/10.1016/j.nanoen.2020.105389 .

Lei, Z. Y.; Wang, Q. K.; Sun, S. T.; Zhu, W. C.; Wu, P. Y . A bioinspired mineral hydrogel as a self-Healable, mechanically adaptable ionic skin for highly sensitive pressure sensing . Adv. Mater. , 2017 . 29 1700321 DOI: 10.1002/adma.201700321 http://doi.org/10.1002/adma.201700321 .

Gao, F.; Xie, W. S.; Miao, Y. Q.; Wang, D.; Guo, Z. H.; Ghosal, A.; Li, Y. S.; Wei, Y.; Feng, S. S.; Zhao, L. Y.; Fan, H. M . Magnetic hydrogel with optimally adaptive functions for breast cancer recurrence prevention . Adv. Healthc. Mater. , 2019 . 8 1900203 DOI: 10.1002/adhm.201900203 http://doi.org/10.1002/adhm.201900203 .

Zhang, Y. L.; Yang, B.; Zhang, X. Y.; Xu, L. X.; Tao, L.; Lia, S. X.; Wei, Y . A magnetic self-healing hydrogel . Chem. Commun. , 2012 . 48 9305 - 9307 . DOI: 10.1039/c2cc34745h http://doi.org/10.1039/c2cc34745h .

Gang, F. L.; Yan, H.; Ma, B C. Y.; Jiang, L.; Gu, Y. Y.; Liu, Z. Y.; Zhao, L. Y.; Wang, X. M.; Zhang, J. W.; Sun, X. D . Robust magnetic double-network hydrogels with self-healing, MR imaging, cytocompatibility and 3D printability . Chem. Commun. , 2019 . 55 12412 - 12412 . DOI: 10.1039/C9CC90441G http://doi.org/10.1039/C9CC90441G .

Zhang, D. C.; Zhang, J. W.; Jian, Y. K.; Wu, B. Y.; Yan, H. Z.; Lu, H. H.; Wei, S. X.; Wu, S.; Xue, Q. J.; Chen, T . Multi-field synergy manipulating soft polymeric hydrogel transformers . Adv. Intell. Syst. , 2021 . 3 2000208 DOI: 10.1002/aisy.202000208 http://doi.org/10.1002/aisy.202000208 .

Zhang, Y. L.; Wang, Y.; Wen, Y. Y.; Zhong, Q. F.; Zhao, Y. J . Self-healable magnetic structural color hydrogels . ACS Appl. Mater. Interfaces , 2020 . 12 7486 - 7493 . DOI: 10.1021/acsami.9b22579 http://doi.org/10.1021/acsami.9b22579 .

Wang, L.; Yang, X. F.; Chen, H. M.; Yang, G.; Gong, T.; Li, W. B.; Zhou, S. B . Multi-stimuli sensitive shape memory poly(vinyl alcohol)-graft-polyurethane . Polym. Chem. , 2013 . 4 4461 - 4468 . DOI: 10.1039/c3py00519d http://doi.org/10.1039/c3py00519d .

Zhang, Y. Y.; Gao H. J.; Wang, H.; Xu, Z. Y.; Chen, X. W.; Liu, B.; Shi, Y.; Lu, Y.; Wen, L. F.; Li, Y.; Li, Z. S.; Men, Y. F.; Feng, X. Q.; Liu, W. G . Radiopaque highly stiff and tough shape memory hydrogel microcoils for permanent embolization of arteries . Adv. Funct. Mater. , 2018 . 28 1705962 DOI: 10.1002/adfm.201705962 http://doi.org/10.1002/adfm.201705962 .

Zhang, Y. C.; Le, X. X.; Lu, W.; Jian, Y. K.; Zhang, J. W.; Chen, T . An “off-the-Shelf” shape memory hydrogel based on the dynamic borax-diol ester bonds . Macromol. Mater. Eng. , 2018 . 303 1800144 DOI: 10.1002/mame.201800144 http://doi.org/10.1002/mame.201800144 .

Le, X. X.; Lu, W.; Zheng, J.; Tong, D. Y.; Zhao, N.; Ma, C. X.; Xiao, H.; Zhang, J. W.; Huang, Y. J.; Chen, T . Stretchable supramolecular hydrogels with triple shape memory effect . Chem. Sci. , 2016 . 7 6715 - 6720 . DOI: 10.1039/C6SC02354A http://doi.org/10.1039/C6SC02354A .

Meng, H.; Zheng, J.; Wen, X. F.; Cai, Z. Q.; Zhang, J. W.; Chen, T. . pH- and sugar-induced shape memory hydrogel based on reversible penylboronic acid-diol ester bonds . Macromol. Rapid Commun. , 2015 . 36 533 - 537 . DOI: 10.1002/marc.201400648 http://doi.org/10.1002/marc.201400648 .

Li, Z. W.; Lu, W.; Ngai, T.; Le, X. X.; Zheng, J.; Zhao, N.; Huang, Y. J.; Wen, X. F.; Zhang, J. W.; Chen, T . Mussel-inspired multifunctional supramolecular hydrogels with self-healing, shape memory and adhesive properties . Polym. Chem. , 2016 . 7 5343 - 5346 . DOI: 10.1039/C6PY01112H http://doi.org/10.1039/C6PY01112H .

Qiu, H. Y.; Wei, S. X.; Liu, H.; Zhan, B. B.; Yan, H. Z.; Lu, W.; Zhang, J. W.; Wu, S.; Chen, T . Programming multistate aggregation-induced emissive polymeric hydrogel into 3D structures for on-demand information decryption and transmission . Adv. Intell. Syst. , 2021 . 3 2000239 DOI: 10.1002/aisy.202000239 http://doi.org/10.1002/aisy.202000239 .

Jiang, L. B.; Lu, Y.; Liu, X. Y.; Tu, H.; Zhang, J. W.; Shi, X. W.; Deng H. B.; Du, Y. M . Layer-by-layer immobilization of quaternized carboxymethyl chitosan/organic rectorite and alginate onto nanofibrous mats and their antibacterial application . Carbohydr. Polym. , 2015 . 121 428 - 435 . DOI: 10.1016/j.carbpol.2014.12.069 http://doi.org/10.1016/j.carbpol.2014.12.069 .

Yan, K.; Xu, F. Y.; Wang, C. Y.; Li, Y. Y.; Chen, Y. L.; Li, X. F.; Lu, Z. T. Wang, D . A multifunctional metal-biopolymer coordinated double network hydrogel combined with multistimulus responsiveness, self-healing, shape memory and antibacterial properties . Biomater. Sci. , 2020 . 8 3193 - 3201 . DOI: 10.1039/D0BM00425A http://doi.org/10.1039/D0BM00425A .

Lu, X. K.; Chan, C. Y.; Lee, K. I.; Ng, P. F.; Fei, B.; Xin, J. H.; Fu, J . Super-tough and thermo-healable hydrogel-promising for shape-memory absorbent fiber . J. Mater. Chem. B , 2014 . 2 7631 - 7638 . DOI: 10.1039/C4TB01289E http://doi.org/10.1039/C4TB01289E .

Zhang, H. J.; Han, D. H.; Yan, Q.; Fortin, D.; Xia, H. S.; Zhao, Y . Light-healable hard hydrogels through photothermally induced melting-crystallization phase transition . J. Mater. Chem. A , 2014 . 2 13373 - 13379 . DOI: 10.1039/C4TA02463J http://doi.org/10.1039/C4TA02463J .

Yang, L.; Wang, Z. H.; Fei, G. X.; Xia, H. S . Polydopamine particles reinforced poly(vinyl alcohol) hydrogel with NIR light triggered shape memory and self-healing capability . Macromol. Rapid Commun. , 2017 . 38 1700421 DOI: 10.1002/marc.201700421 http://doi.org/10.1002/marc.201700421 .

Ye, F. M.; Li, M.; Ke, D. N.; Wang, L. P.; Lu, Y . Ultrafast self-healing and injectable conductive hydrogel for strain and pressure sensors . Adv. Mater. Technol. , 2019 . 4 1900346 DOI: 10.1002/admt.201900346 http://doi.org/10.1002/admt.201900346 .

Wang, Z. F.; Ren, Y. P.; Zhu, Y.; Hao, L. J.; Chen, Y. H.; An, G.; Wu, H. K.; Shi, X. T.; Mao, C. B . A novel rapidly self-healing host-guest supramolecular hydrogel with high mechanical strength and excellent biocompatibility . Angew. Chem. Int. Ed. , 2018 . 57 9008 - 9012 . DOI: 10.1002/anie.201804400 http://doi.org/10.1002/anie.201804400 .

Zheng, J.; Xiao, P.; Liu, W.; Zhang, J. W.; Huang, Y. J.; Chen, T . Mechanical robust and self-healable supramolecular hydrogel . Macromol. Rapid Commun. , 2016 . 37 265 - 270 . DOI: 10.1002/marc.201500571 http://doi.org/10.1002/marc.201500571 .

Sun, T. L.; Kurokawa, T.; Kuroda, S.; Ihsan, A. B.; Akasaki, T.; Sato, K.; Haque, M. A.; Nakajima, T.; Gong, J. P . Physical hydrogels composed of polyampholytes demonstrate high toughness and viscoelasticity . Nat. Mater. , 2013 . 12 932 - 937 . DOI: 10.1038/nmat3713 http://doi.org/10.1038/nmat3713 .

Long, T. J.; Li, Y. X.; Fang, X.; Sun, J. Q . Salt-Mediated polyampholyte hydrogels with high mechanical strength, excellent self-healing property, and satisfactory electrical conductivity . Adv. Funct. Mater. , 2018 . 28 1804416 DOI: 10.1002/adfm.201804416 http://doi.org/10.1002/adfm.201804416 .

Hussain, I.; Sayed, S. M.; Liu, S. L.; Oderinde, O.; Yao, F.; Fu, G. D . Glycogen-based self-healing hydrogels with ultra-stretchable, flexible, and enhanced mechanical properties via sacrificial bond interactions . Int. J. Biol. Macromol. , 2018 . 117 648 - 658 . DOI: 10.1016/j.ijbiomac.2018.04.088 http://doi.org/10.1016/j.ijbiomac.2018.04.088 .

Lin, J.; Zheng, S. Y.; Xiao, R.; Yin, J.; Wu, Z. L.; Zheng, Q.; Qian, J . Constitutive behaviors of tough physical hydrogels with dynamic metal-coordinated bonds . J. Mech. Phys. Solids , 2020 . 139 103935 DOI: 10.1016/j.jmps.2020.103935 http://doi.org/10.1016/j.jmps.2020.103935 .

Li, S. D.; Chen, N.; Li, X. P.; Li, Y.; Xie, Z. P.; Ma, Z. Y.; Zhao, J.; Hou, X.; Yuan, X. B . Bioinspired double-dynamic-bond crosslinked bioadhesive enables post-wound closure care . Adv. Funct. Mater. , 2020 . 30 2000130 DOI: 10.1002/adfm.202000130 http://doi.org/10.1002/adfm.202000130 .

Liu, T. Q.; Peng, X.; Chen, Y. Y.; Zhang, J. N.; Jiao, C.; Wang, H. L . Solid-phase esterification between poly(vinyl alcohol) and malonic acid and its function in toughening hydrogels . Polym. Chem. , 2020 . 11 4787 - 4797 . DOI: 10.1039/D0PY00023J http://doi.org/10.1039/D0PY00023J .

Li, K.; Wang, J. X.; Li, P.; Fan, Y. B . Ternary hydrogel with tunable mechanical and self-healing properties based on the synergistic effects of multi-dynamic bonds . J. Mater. Chem. B , 2020 . 8 4660 - 4671 . DOI: 10.1039/C9TB02885D http://doi.org/10.1039/C9TB02885D .

Xu, C. H.; Zhan, W.; Tang, X. Z.; Mo, F.; Fu, L. H.; Lin, B. F . Self-healing chitosan/vanillin hydrogels based on Schiff-base bond/hydrogen bond hybrid linkages . Polym. Test. , 2018 . 66 155 - 163 . DOI: 10.1016/j.polymertesting.2018.01.016 http://doi.org/10.1016/j.polymertesting.2018.01.016 .

Kawamoto, K.; Grindy, S. C.; Liu, J.; Holten-Andersen, N.; Johnson, J. A . Dual role for 1,2,4,5-tetrazines in polymer networks: combining Diels-Alder reactions and metal coordination to generate functional supramolecular gels . ACS Macro Lett. , 2015 . 4 458 - 461 . DOI: 10.1021/acsmacrolett.5b00221 http://doi.org/10.1021/acsmacrolett.5b00221 .

Lv, Y. K.; Pan, Z.; Song, C. Z.; Chen, Y. L.; Qian, X . Locust bean gum/gellan gum double-network hydrogels with superior self-healing and pH-driven shape-memory properties . Soft Matter , 2019 . 15 6171 - 6179 . DOI: 10.1039/C9SM00861F http://doi.org/10.1039/C9SM00861F .

Qiao, L. Y.; Liu, C. D.; Liu, C.; Yang, L. Q.; Zhang, M. X.; Liu, W. T.; Wang, J. Y.; Jian, X. G . Self-healing alginate hydrogel based on dynamic acylhydrazone and multiple hydrogen bonds . J. Mater. Sci. , 2019 . 54 8814 - 8828 . DOI: 10.1007/s10853-019-03483-y http://doi.org/10.1007/s10853-019-03483-y .

Cong, H. P.; Wang, P.; Yu, S. H . Highly elastic and superstretchable graphene oxide/polyacrylamide hydrogels . Small , 2014 . 10 448 - 453 . DOI: 10.1002/smll.201301591 http://doi.org/10.1002/smll.201301591 .

Yang, J.; Wang, X. P.; Xie, X. M . In situ synthesis of poly(acrylic acid) physical hydrogels from silica nanoparticles . Soft Matter , 2012 . 8 1058 - 1063 . DOI: 10.1039/C1SM06647A http://doi.org/10.1039/C1SM06647A .

Zhang, Y. W.; Yuan, B.; Zhang, Y. Q.; Cao, Q. P.; Yang, C.; Li, Y.; Zhou, J. H . Biomimetic lignin/poly(ionic liquids) composite hydrogel dressing with excellent mechanical strength, self-healing properties, and reusability . Chem. Eng. J. , 2020 . 400 125984 DOI: 10.1016/j.cej.2020.125984 http://doi.org/10.1016/j.cej.2020.125984 .

Luo, F.; Sun, T. L.; Nakajima, T.; Kurokawa, T.; Zhao, Y.; Sato, K.; Ihsan, A. B.; Li, X. F.; Guo, H. L.; Gong, J. P . Oppositely charged polyelectrolytes form tough, self-healing, and rebuildable hydrogels . Adv. Mater. , 2015 . 27 2722 - 2727 . DOI: 10.1002/adma.201500140 http://doi.org/10.1002/adma.201500140 .

Wu, Z. N.; Yao, Q. F.; Zang, S. Q.; Xie, J. P . Aggregation-induced emission in luminescent metal nanoclusters . Natl. Sci. Rev. , 2020 . DOI: 10.1093/nsr/nwaa208 http://doi.org/10.1093/nsr/nwaa208 .

Zhao, X. X; Sun, W. W.; Geng, D. C.; Fu, W.; Dan, J. D.; Xie, Y.; Kent, P. R. C.; Zhou, W.; Pennycook, S. J.; Loh, K. P . Edge segregated polymorphism in 2D molybdenum carbide . Adv. Mater. , 2019 . 31 1808343 DOI: 10.1002/adma.201808343 http://doi.org/10.1002/adma.201808343 .

Hui, C. Y.; Long, R . A constitutive model for the large deformation of a self-healing gel . Soft Matter , 2012 . 8 8209 - 8216 . DOI: 10.1039/c2sm25367d http://doi.org/10.1039/c2sm25367d .

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