Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials

Bo-Han Cao; Wu Chen; Wan-Yuan Wei; Yu-Lan Chen; Yuan Yuan

doi:10.1007/s10118-021-2601-4

Your Location：

Home >

Browse articles >

Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials

ARTICLE | Updated：2021-07-01

- Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials
- Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials
- Chinese Journal of Polymer Science 2021年39卷第11期页码：1403-1411
- Affiliations：
  
  Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin 300354, China
- Author bio：
  
  yulan.chen@tju.edu.cn (Y.L.C.)
  yyuan@tju.edu.cn (Y.Y.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21905200, 21975178 and 21734006), and China Postdoctoral Science Foundation (No. 2019M661006).
- DOI：10.1007/s10118-021-2601-4
  中图分类号：
- 收稿：2021-03-25，
  
  修回：2021-4-29，
  
  录用：2021-5-4，
  
  网络首发：2021-07-01，
  
  纸质出版：2021-09-18
- Accepted：
Scan QR Code
Cao, B. H.; Chen, W.; Wei, W. Y.; Chen, Y. L.; Yuan, Y. Carbon dots intensified mechanochemiluminescence from waterborne polyurethanes as tunable force sensing materials. Chinese J. Polym. Sci. 2021, 39, 1403–1411

Bo-Han Cao, Wu Chen, Wan-Yuan Wei, et al. Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials[J]. Chinese Journal of Polymer Science, 2021, 39(11): 1403-1411.
Cao, B. H.; Chen, W.; Wei, W. Y.; Chen, Y. L.; Yuan, Y. Carbon dots intensified mechanochemiluminescence from waterborne polyurethanes as tunable force sensing materials. Chinese J. Polym. Sci. 2021, 39, 1403–1411 DOI： 10.1007/s10118-021-2601-4.

Bo-Han Cao, Wu Chen, Wan-Yuan Wei, et al. Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials[J]. Chinese Journal of Polymer Science, 2021, 39(11): 1403-1411. DOI： 10.1007/s10118-021-2601-4.

摘要

Abstract

2-Dioxetane is a well-known chemiluminescent mechanophore allowing real-time monitoring of polymer chain scission

but usually suffers from fluorescence quenching in polar environments. Herein

a series of mechanochemiluminescent waterborne polyurethanes/carbon dots composites (

WPU-CDs

) have been synthesized by incorporating fluorescent

s to promote the energy transfer process in different environments. The resulting bulk

WPU

and in particular

their swollen films filled with a large amount of polar solvents (water and ionic liquid) emit intense mechanochemiluminescence. Thus force-induced covalent bond scission and stress distribution within these different

WPU-CDs

films can be sensitively visualized. Furthermore

the ionic liquid containing films exhibited both electrical and luminescent signal changes under stretching

which offer a new kind of force sensor responsive at a broad detecting strain range and for multi-mode strain analysis. This study is expected to stimulate new research endeavors in mechanistic insight on waterborne polyurethanes and the corresponding stretchable sensing devices.

关键词

Keywords

references

Honarkar, H. . Waterborne polyurethanes: a review . J. Disper. Sci. Technol. , 2018 . 39 507 - 516 . DOI: 10.1080/01932691.2017.1327818 http://doi.org/10.1080/01932691.2017.1327818 .

Nelson, A. M.; Long, T. E. . Synthesis, properties, and applications of ion-containing polyurethane segmented copolymers . Macromol. Chem. Phys. , 2014 . 215 2161 - 2174 . DOI: 10.1002/macp.201400373 http://doi.org/10.1002/macp.201400373 .

Song, Y.; Gao, Y.; Pan, Z.; Zhang, Y.; Li, J.; Wang, K.; Li, J.; Tan, H.; Fu, Q. . Preparation and characterization of controlled heparin release waterborne polyurethane coating systems . Chinese J. Polym. Sci. , 2016 . 34 679 - 687 . DOI: 10.1007/s10118-016-1787-3 http://doi.org/10.1007/s10118-016-1787-3 .

Yang, N.; Yang, H.; Shao, Z.; Guo, M. . Ultrastrong and tough supramolecular hydrogels from multiurea linkage segmented copolymers with tractable processablity and recyclability . Macromol. Rapid Commun. , 2017 . 38 1700275 DOI: 10.1002/marc.201700275 http://doi.org/10.1002/marc.201700275 .

Sun, J.; Keplinger, C.; Whitesides, G. M.; Suo, Z. . Ionic skin . Adv. Mater. , 2014 . 26 7608 - 7614 . DOI: 10.1002/adma.201403441 http://doi.org/10.1002/adma.201403441 .

Li, T.; Wang, Y.; Li, S.; Liu, X.; Sun, J. . Mechanically robust, elastic, and healable ionogels for highly sensitive ultra-durable ionic skins . Adv. Mater. , 2020 . 32 2002706 DOI: 10.1002/adma.202002706 http://doi.org/10.1002/adma.202002706 .

Kim, N.; Lienemann, S.; Petsagkourakis, I.; Mengistie, D. A.; Kee, S.; Ederth, T.; Gueskine, V.; Leclere, P.; Lazzaroni, R.; Crispin, X.; Tybrandt, K. . Elastic conducting polymer composites in thermoelectric modules . Nat. Commun. , 2020 . 11 1424 - 1433 . DOI: 10.1038/s41467-020-15135-w http://doi.org/10.1038/s41467-020-15135-w .

Chen, Y.; Mellot, G.; van Luijk, D.; Creton, C.; Sijbesma, R. P. . Mechanochemical tools for polymer materials . Chem. Soc. Rev. , 2021 . 50 4100 - 4140 . DOI: 10.1039/D0CS00940G http://doi.org/10.1039/D0CS00940G .

Davis, D. A.; Hamilton, A.; Yang, J.; Cremar, L. D.; Van Gough, D.; Potisek, S. L.; Ong, M. T.; Braun, P. V.; Martínez, T. J.; White, S. R.; Moore, J. S.; Sottos, N. R. . Force-induced activation of covalent bonds in mechanoresponsive polymeric materials . Nature , 2009 . 459 68 - 72 . DOI: 10.1038/nature07970 http://doi.org/10.1038/nature07970 .

Wang, L.; Yang, K.; Zhou, Q.; Yang, H.; He, J.; Zhang, X. . Rhodamine mechanophore functionalized mechanochromic double network hydrogels with high sensitivity to stress . Chinese J. Polym. Sci. , 2020 . 38 24 - 36 . DOI: 10.1007/s10118-019-2293-1 http://doi.org/10.1007/s10118-019-2293-1 .

Chen, Y.; Spiering, A. J. H.; Karthikeyan, S.; Peters, G. W. M.; Meijer, E. W.; Sijbesma, R. P. . Mechanically induced chemiluminescence from polymers incorporating a 1,2-dioxetane unit in the main chain . Nat. Chem. , 2012 . 4 559 - 562 . DOI: 10.1038/nchem.1358 http://doi.org/10.1038/nchem.1358 .

Chen, Y.; Sijbesma, R. P. . Dioxetanes as mechanoluminescent probes in thermoplastic elastomers . Macromolecules , 2014 . 47 3797 - 3805 . DOI: 10.1021/ma500598t http://doi.org/10.1021/ma500598t .

Liu, S.; Yuan, Y.; Li, J.; Sun, S.; Chen, Y. . An optomechanical study of mechanoluminescent elastomeric polyurethanes with different hard segments . Polym. Chem. , 2020 . 11 1877 - 1884 . DOI: 10.1039/C9PY01850F http://doi.org/10.1039/C9PY01850F .

Yan, C.; Yang, F.; Wu, M.; Yuan, Y.; Chen, F.; Chen, Y. . Phase-locked dynamic and mechanoresponsive bonds design toward robust and mechanoluminescent self-healing polyurethanes: a microscopic view of self-healing behaviors . Macromolecules , 2019 . 52 9376 - 9382 . DOI: 10.1021/acs.macromol.9b02089 http://doi.org/10.1021/acs.macromol.9b02089 .

Yuan, W.; Yuan, Y.; Yang, F.; Wu, M.; Chen, Y. . Improving mechanoluminescent sensitivity of 1,2-dioxetane-containing thermoplastic polyurethanes by controlling energy transfer across polymer chains . Macromolecules , 2018 . 51 9019 - 9025 . DOI: 10.1021/acs.macromol.8b01668 http://doi.org/10.1021/acs.macromol.8b01668 .

Deng, Y.; Yuan, Y.; Chen, Y. . Covalently cross-linked and mechanochemiluminescent polyolefins capable of self-healing and self-reporting . CCS Chem. , 2020 . 2 1316 - 1324 . .

Ducrot, E.; Chen, Y.; Bulters, M.; Sijbesma, R. P.; Creton, C. . Toughening elastomers with sacrificial bonds and watching them break . Science , 2014 . 344 186 - 189 . DOI: 10.1126/science.1248494 http://doi.org/10.1126/science.1248494 .

Millereau, P.; Ducrot, E.; Clough, J. M.; Wiseman, M. E.; Brown, H. R.; Sijbesma, R. P.; Creton, C. . Mechanics of elastomeric molecular composites . Proc. Natl. Acad. Sci. U.S.A. , 2018 . 115 9110 - 9115 . DOI: 10.1073/pnas.1807750115 http://doi.org/10.1073/pnas.1807750115 .

Chen, W.; Yuan, Y.; Chen, Y. . Visualized bond scission in mechanochemiluminescent polymethyl acrylate/cellulose nanocrystals composites . ACS Macro Lett. , 2020 . 9 438 - 442 . DOI: 10.1021/acsmacrolett.0c00185 http://doi.org/10.1021/acsmacrolett.0c00185 .

Clough, J. M.; Creton, C.; Craig, S. L.; Sijbesma, R. P. . Covalent bond scission in the mullins effect of a filled elastomer: real-time visualization with mechanoluminescence . Adv. Funct. Mater. , 2016 . 26 9063 - 9074 . DOI: 10.1002/adfm.201602490 http://doi.org/10.1002/adfm.201602490 .

Yuan, Y.; Chen, W.; Ma, Z.; Deng, Y.; Chen, Y.; Chen, Y.; Hu, W. . Enhanced optomechanical properties of mechanochemiluminescent poly(methyl acrylate) composites with granulated fluorescent conjugated microporous polymer fillers . Chem. Sci. , 2019 . 10 2206 - 2211 . DOI: 10.1039/C8SC04701D http://doi.org/10.1039/C8SC04701D .

Matsumoto, M. . Advanced chemistry of dioxetane-based chemiluminescent substrates originating from bioluminescence . J. Photochem. Photobiol. C , 2004 . 5 27 - 53 . DOI: 10.1016/j.jphotochemrev.2004.02.001 http://doi.org/10.1016/j.jphotochemrev.2004.02.001 .

Yang, F.; Yuan, Y.; Sijbesma, R. P.; Chen, Y. . Sensitized mechanoluminescence design toward mechanically induced intense red emission from transparent polymer films . Macromolecules , 2020 . 53 905 - 912 . DOI: 10.1021/acs.macromol.9b02221 http://doi.org/10.1021/acs.macromol.9b02221 .

Yan, F.; Sun, Z.; Zhang, H.; Sun, X.; Jiang, Y.; Bai, Z. . The fluorescence mechanismof carbon dots, and methods for tuning their emission color: a review . Microchim. Acta , 2019 . 186 583 DOI: 10.1007/s00604-019-3688-y http://doi.org/10.1007/s00604-019-3688-y .

Baker, S. N.; Baker, G. A. . Luminescent carbon nanodots: emergent nanolights . Angew. Chem. Int. Ed. , 2010 . 49 6726 - 6744 . DOI: 10.1002/anie.200906623 http://doi.org/10.1002/anie.200906623 .

Du, X.; Wang, C.; Wu, G.; Chen, S. . The rapid and large-scale production of carbon quantum dots and their integration with polymers . Angew. Chem. Int. Ed. , 2021 . 60 8585 - 8595 . DOI: 10.1002/anie.202004109 http://doi.org/10.1002/anie.202004109 .

Lim, S. Y.; Shen, W.; Gao, Z. . Carbon quantum dots and their applications . Chem. Soc. Rev. , 2015 . 44 362 - 381 . DOI: 10.1039/C4CS00269E http://doi.org/10.1039/C4CS00269E .

Liu, J.; Li, R.; Yang, B. . Carbon dots: a new type of carbon-based nanomaterial with wide applications . ACS Cent. Sci. , 2020 . 6 2179 - 2195 . DOI: 10.1021/acscentsci.0c01306 http://doi.org/10.1021/acscentsci.0c01306 .

Liu, M.; Chen, B.; Li, C.; Huang, C. . Carbon dots: synthesis, formation mechanism, fluorescence origin and sensing applications . Green Chem. , 2019 . 21 449 - 471 . DOI: 10.1039/C8GC02736F http://doi.org/10.1039/C8GC02736F .

Qiang, T.; Han, M.; Wang, X. . Waterborne polyurethane/carbon quantum dot nanocomposite as a surface coating material exhibiting outstanding luminescent performance . Prog. Org. Coat. , 2020 . 138 105433 DOI: 10.1016/j.porgcoat.2019.105433 http://doi.org/10.1016/j.porgcoat.2019.105433 .

Tsuda, R.; Kodama, K.; Ueki, T.; Kokubo, H.; Imabayashi, S.; Watanabe, M. . LCST-type liquid-liquid phase separation behaviour of poly(ethylene oxide) derivatives in an ionic liquid . Chem. Commun. , 2008 . 4939 - 4941 . DOI: 10.1039/B810127B http://doi.org/10.1039/B810127B .

Jiang, K.; Sun, S.; Zhang, L.; Lu, Y.; Wu, A.; Cai, C.; Lin, H. . Red, green, and blue luminescence by carbon dots: full-color emission tuning and multicolor cellular imaging . Angew. Chem. Int. Ed. , 2015 . 54 5360 - 5363 . DOI: 10.1002/anie.201501193 http://doi.org/10.1002/anie.201501193 .

Shen, C.; Lou, Q.; Lv, C.; Zang, J.; Qu, S.; Dong, L.; Shan, C. . Bright and multicolor chemiluminescent carbon nanodots for advanced information encryption . Adv. Sci. , 2019 . 6 1802331 DOI: 10.1002/advs.201802331 http://doi.org/10.1002/advs.201802331 .

Zheng, A.; Guo, T.; Guan, F.; Chen, X.; Shu, Y.; Wang, J. . Ionic liquid mediated carbon dots: preparations, properties and applications . Trac-trend Anal. Chem. , 2019 . 119 115638 DOI: 10.1016/j.trac.2019.115638 http://doi.org/10.1016/j.trac.2019.115638 .

Liu, Y.; Liu, D.; Li, S.; Liang, H.; Zhu, F. . Investigation on viscoelasticity of waterborne polyurethane with azobenzene-containing pendant groups under ultraviolet and visible-light irradiation . Chinese J. Polym. Sci. , 2019 . 37 1267 - 1272 . DOI: 10.1007/s10118-019-2289-x http://doi.org/10.1007/s10118-019-2289-x .

Zhang, Q.; Wang, Y.; Xing, C.; Cai, Y.; Xi, K.; Jia, X. . Light and force dual-responsive waterborne polyurethane in multiple states . RSC Adv. , 2017 . 7 12682 - 12689 . DOI: 10.1039/C7RA00156H http://doi.org/10.1039/C7RA00156H .

浏览量

150

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Multifunctional Polyurethane with High Strength, Toughness, and Self-healing Capacity via Tannic Acid-modified Cellulose Nanocrystals

A Brief Review on Ultrasound Induced Drug Activation Systems

Fluorescent Polyurea-Carbon Dots: Preparation, Characterization and Use as Sensor for Doxycycline Detection

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair