Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A<sub>2</sub>B<sub>6</sub>-type POSS Monomer

Lin-Feng Fan; Cui-Ling Hou; Xing Wang; Li-Tang Yan; De-Cheng Wu

doi:10.1007/s10118-021-2598-8

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Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A₂B₆-type POSS Monomer

ARTICLE | Updated：2021-07-06

- Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A₂B₆-type POSS Monomer
- Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A₂B₆-type POSS Monomer
- Chinese Journal of Polymer Science 2021年39卷第12期页码：1562-1571
- Affiliations：
  
  a.Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Polymer Physics & Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
  c.State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100049, China
  d.Department of Biomedical Engineering, Southern University of Science and Technology, Shenzhen 518055, China
- Author bio：
  
  wangxing@iccas.ac.cn (X.W.)
  ltyan@mail.tsinghua.edu.cn (L.T.Y.)
  dcwu@iccas.ac.cn (D.C.W)
- Funds：
  
  This work was financially supported by the Ministry of Science and Technology of China (No. 2020YFA0908900), the National Natural Science Foundation of China (Nos. 51973226, 21935011, 21725403 and 81871782) and the Youth Innovation Promotion Association CAS (No. 2019031).
- DOI：10.1007/s10118-021-2598-8
  中图分类号：
- 收稿：2021-04-12，
  
  修回：2021-4-27，
  
  录用：2021-4-28，
  
  网络首发：2021-07-06，
  
  纸质出版：2021-10-18
- Accepted：
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Fan, L. F.; Hou, C. L.; Wang, X.; Yan, L. T.; Wu, D. C. Tunable multiple morphological transformation of supramolecular hyperbranched polymers based on an A₂B₆-type POSS monomer. Chinese J. Polym. Sci. 2021, 39, 1562–1571 DOI: 10.1007/s10118-021-2598-8.

Lin-Feng Fan, Cui-Ling Hou, Xing Wang, et al. Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A₂B₆-type POSS Monomer[J]. Chinese Journal of Polymer Science, 2021, 39(12): 1562-1571. DOI: 10.1007/s10118-021-2598-8.
Fan, L. F.; Hou, C. L.; Wang, X.; Yan, L. T.; Wu, D. C. Tunable multiple morphological transformation of supramolecular hyperbranched polymers based on an A₂B₆-type POSS monomer. Chinese J. Polym. Sci. 2021, 39, 1562–1571 DOI: 10.1007/s10118-021-2598-8. DOI：

Lin-Feng Fan, Cui-Ling Hou, Xing Wang, et al. Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A₂B₆-type POSS Monomer[J]. Chinese Journal of Polymer Science, 2021, 39(12): 1562-1571. DOI: 10.1007/s10118-021-2598-8. DOI：

摘要

Abstract

The growing demands of supramolecular hyperbranched polymers integrating noncovalent interaction and unique topological structure merits had received considerable interest in the fabrication of novel materials for advanced applications. Herein

we prepared A

-type POSS-containing supramolecular hyperbranched polymers with multiple morphologies including lamellar-like

branched

hollow

core-shell and porous spherical structures through regulating self-assembling monomer concentrations and solvent polarities. The incorporation of appropriate emulative guest molecules would further trigger morphological transformations (such as vesicles and spherical micelles) by synergistic effects of unique POSS aggregation ability

supramolecular complexations and hydrophilic-hydrophobic interactions. Thus

this facile and universal strategy may enable a modular nanofabrication of supramolecular hyperbranched polymers with diversiform topological structure and sophisticated multifunctionality for their potential applications.

关键词

Keywords

references

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Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A2B6-type POSS Monomer

DOI：10.1007/s10118-021-2598-8

摘要

Abstract

关键词

Keywords

references

Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A₂B₆-type POSS Monomer

Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A₂B₆-type POSS Monomer