Dithienylmaleimide-based D-A Conjugated Polymer Film: Photo-responsive Behavior and Application in Electrical Memory and Logic Gates

Wei Lv; Chun Wang; Xing-Chi Lin; Xiao-Fei Mei; Wen Wang; E Yang; Qi-Dan Ling; Zheng-Huan Lin

doi:10.1007/s10118-021-2594-z

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Dithienylmaleimide-based D-A Conjugated Polymer Film: Photo-responsive Behavior and Application in Electrical Memory and Logic Gates

ARTICLE | Updated：2021-06-15

- Dithienylmaleimide-based D-A Conjugated Polymer Film: Photo-responsive Behavior and Application in Electrical Memory and Logic Gates
- Dithienylmaleimide-based D-A Conjugated Polymer Film: Photo-responsive Behavior and Application in Electrical Memory and Logic Gates
- Chinese Journal of Polymer Science 2021年39卷第9期页码：1177-1184
- Affiliations：
  
  a.College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
  b.Fujian Provincial Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, China
- Author bio：
  
  qdling@fjnu.edu.cn (Q.D.L.)
  zhlin@fjnu.edu.cn (Z.H.L.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 22075044 and 21574021), the Natural Science Foundation of Fujian Province (No. 2018J01670), Educational Commission of Fujian Province (No. JAT170129), and the Scientific Research Starting Foundation for researchers with PhD of Fujian Normal University.
- DOI：10.1007/s10118-021-2594-z
  中图分类号： M
- 收稿：2020-11-10，
  
  修回：2021-4-18，
  
  录用：2021-4-20，
  
  网络首发：2021-06-15，
  
  纸质出版：2021-07-18
- Accepted：
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Lv, W.; Wang, C.; Lin, X. C.; Mei, X. F.; Wang, W.; Yang, E.; Ling, Q. D.; Lin, Z. H. Dithienylmaleimide-based D-A conjugated polymer film: photo-responsive behavior and application in electrical memory and logic gates. Chinese J. Polym. Sci. 2021, 39, 1177–1184

Wei Lv, Chun Wang, Xing-Chi Lin, et al. Dithienylmaleimide-based D-A Conjugated Polymer Film: Photo-responsive Behavior and Application in Electrical Memory and Logic Gates[J]. Chinese Journal of Polymer Science, 2021, 39(9): 1177-1184.
Lv, W.; Wang, C.; Lin, X. C.; Mei, X. F.; Wang, W.; Yang, E.; Ling, Q. D.; Lin, Z. H. Dithienylmaleimide-based D-A conjugated polymer film: photo-responsive behavior and application in electrical memory and logic gates. Chinese J. Polym. Sci. 2021, 39, 1177–1184 DOI： 10.1007/s10118-021-2594-z.

Wei Lv, Chun Wang, Xing-Chi Lin, et al. Dithienylmaleimide-based D-A Conjugated Polymer Film: Photo-responsive Behavior and Application in Electrical Memory and Logic Gates[J]. Chinese Journal of Polymer Science, 2021, 39(9): 1177-1184. DOI： 10.1007/s10118-021-2594-z.

摘要

Abstract

Solid-stated smart polymers responsive to external stimuli have attracted much attention for potential application in the field of photoelectron devices

logic gates

sensor

data storage and security. However

it is a bigger challenge for polymers than that for small molecules in solid state to acquire stimuli-responsive properties

because polymers with high molecular weight are not as easy to change the packing structure as small molecules under external stimulation. Here

a D-A type alternating copolymer PTMF-o containing 3

4-bisthienylmaleimide (A unit) and fluorene (D unit) is designed and synthesized. Upon irradiation of sunlight

PTMF-o film exhibits a photo-response with the color altering from purple to colorless. It is attributed to the structure of copolymer transformed from ring-opening form (PTMF-o) to ring-closure form (PTMF-c)

resulting from the oxidative photocyclization of 3

4-bisthienylmaleimide unit. Consequently

the ability of charge transfer (CT) from fluorene to 3

4-bisthienylmaleimide unit in PTMF-o can be easily weakened by light stimuli. PTMF-o film displays a WORM-type resistive storage performance for the strong CT. Interestingly

after exposure

the electrical memory behavior

in situ

transfers into FLASH type

due to weak CT in PTMF-c. PTMF-o film can also be employed as smart material to construct NAND and NOR logic gates by using light as input condition. The work provides a simple way to modify the electronic properties of polymers and realize stimuli-response in solid states.

关键词

Keywords

references

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