“Solid-Liquid” Vitrimers Based on Dynamic Boronic Ester Networks

Sheng Wang; Lu-Lu Xue; Xiao-Zhuang Zhou; Jia-Xi Cui

doi:10.1007/s10118-021-2592-1

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“Solid-Liquid” Vitrimers Based on Dynamic Boronic Ester Networks

ARTICLE | Updated：2021-07-25

- “Solid-Liquid” Vitrimers Based on Dynamic Boronic Ester Networks
- “Solid-Liquid” Vitrimers Based on Dynamic Boronic Ester Networks
- Chinese Journal of Polymer Science 2021年39卷第10期页码：1292-1298
- Affiliations：
  
  a.INM – Leibniz Institute for New Materials Campus D2 2, Saarbrücken 66123, Germany
  b.Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
  c.Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
- Author bio：
  
  Jiaxi.Cui@uestc.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51973023) and Sichuan Science and Technology Program (No. 2021JDRC0014).
- DOI：10.1007/s10118-021-2592-1
  中图分类号：
- 收稿：2021-03-04，
  
  修回：2021-4-16，
  
  录用：2021-6-10，
  
  网络首发：2021-07-25，
  
  纸质出版：2021-08-20
- Accepted：
Scan QR Code
Wang, S.; Xue, L. L.; Zhou, X. Z.; Cui, J. X. “Solid-liquid” vitrimers based on dynamic boronic ester networks. Chinese J. Polym. Sci. 2021, 39, 1292–1298

Sheng Wang, Lu-Lu Xue, Xiao-Zhuang Zhou, et al. “Solid-Liquid” Vitrimers Based on Dynamic Boronic Ester Networks[J]. Chinese Journal of Polymer Science, 2021, 39(10): 1292-1298.
Wang, S.; Xue, L. L.; Zhou, X. Z.; Cui, J. X. “Solid-liquid” vitrimers based on dynamic boronic ester networks. Chinese J. Polym. Sci. 2021, 39, 1292–1298 DOI： 10.1007/s10118-021-2592-1.

Sheng Wang, Lu-Lu Xue, Xiao-Zhuang Zhou, et al. “Solid-Liquid” Vitrimers Based on Dynamic Boronic Ester Networks[J]. Chinese Journal of Polymer Science, 2021, 39(10): 1292-1298. DOI： 10.1007/s10118-021-2592-1.

摘要

Abstract

The “solid-liquid” behavior of vitrimers have not been systematically investigated. Herein

a series of “solid-liquid” vitrimers bearing varying contents of dynamic boronic ester bonds were synthesized

via

thiol-ene click reactions. These vitrimers allow for flexibile modulation of their network structures and thus show a range of intriguing properties including high stretchability

flexible transition from elasticity to plasticity

strong strain rate dependence

and solid-liquid performance. The dynamic association rate of boronic ester bonds within these vitrimers could be apparently accelerated

via

increasing the content of boronic ester

which could be used to shape-program the flat vitrimer films into various complex 3D structures just with external force. Materials with such versatile dynamic behavior may open up a range of new applications.

关键词

Keywords

references

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