Synergistic Effects of Solvent Vapor Assisted Spin-coating and Thermal Annealing on Enhancing the Carrier Mobility of Poly(3-hexylthiophene) Field-effect Transistors

Xiao-Lan Qiao; Jie Yang; Lian-He Han; Ji-Dong Zhang; Mei-Fang Zhu

doi:10.1007/s10118-021-2577-0

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Synergistic Effects of Solvent Vapor Assisted Spin-coating and Thermal Annealing on Enhancing the Carrier Mobility of Poly(3-hexylthiophene) Field-effect Transistors

ARTICLE | Updated：2021-05-24

- Synergistic Effects of Solvent Vapor Assisted Spin-coating and Thermal Annealing on Enhancing the Carrier Mobility of Poly(3-hexylthiophene) Field-effect Transistors
- Synergistic Effects of Solvent Vapor Assisted Spin-coating and Thermal Annealing on Enhancing the Carrier Mobility of Poly(3-hexylthiophene) Field-effect Transistors
- Chinese Journal of Polymer Science 2021年39卷第7期页码：849-855
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  jdzhang@ciac.ac.cn (J.D.Z.)
  zmf@dhu.edu.cn (M.F.Z.)
- Funds：
  
  This work was financially supported by the International Cooperation Fund of the Science and Technology Commission of Shanghai Municipality (No. 20520741500), the Fundamental Research Funds for the Central Universities (No. 2232020D-01), Shanghai Rising-Star Program (No. 18QA1405000), the Innovation Program of Shanghai Municipal Education Commission (No. 2017-01-07-00-03-E00055), the Science and Technology Commission of Shanghai Municipality (No. 20JC1414900), and the Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (No. 2020-16).
- DOI：10.1007/s10118-021-2577-0
  中图分类号：
- 收稿：2021-02-03，
  
  修回：2021-3-2，
  
  录用：2021-3-9，
  
  网络首发：2021-05-24，
  
  纸质出版：2021-05-14
- Accepted：
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Qiao, X. L.; Yang, J.; Han, L. H.; Zhang, J. D.; Zhu, M. F. Synergistic effects of solvent vapor assisted spin-coating and thermal annealing on enhancing the carrier mobility of poly(3-hexylthiophene) field-effect transistors. Chinese J. Polym. Sci. 2021, 39, 849–855

Xiao-Lan Qiao, Jie Yang, Lian-He Han, et al. Synergistic Effects of Solvent Vapor Assisted Spin-coating and Thermal Annealing on Enhancing the Carrier Mobility of Poly(3-hexylthiophene) Field-effect Transistors[J]. Chinese Journal of Polymer Science, 2021, 39(7): 849-855.
Qiao, X. L.; Yang, J.; Han, L. H.; Zhang, J. D.; Zhu, M. F. Synergistic effects of solvent vapor assisted spin-coating and thermal annealing on enhancing the carrier mobility of poly(3-hexylthiophene) field-effect transistors. Chinese J. Polym. Sci. 2021, 39, 849–855 DOI： 10.1007/s10118-021-2577-0.

Xiao-Lan Qiao, Jie Yang, Lian-He Han, et al. Synergistic Effects of Solvent Vapor Assisted Spin-coating and Thermal Annealing on Enhancing the Carrier Mobility of Poly(3-hexylthiophene) Field-effect Transistors[J]. Chinese Journal of Polymer Science, 2021, 39(7): 849-855. DOI： 10.1007/s10118-021-2577-0.

摘要

Abstract

Poly(3-hexylthiophene) (P3HT) thin films

obtained by normal spin-coating and solvent vapor assisted spin-coating (SVASP) before and after thermal annealing (TA)

and the corresponding devices were prepared to unravel the microstructure-property relationship

which is of great importance for the development of organic electronics. When SVASP-TA films were used as the active layers of the organic field-effect transistors

a hole mobility up to 0.38 cm

·V

–1

·s

–1

was achieved. This mobility was one of the highest values and one order of magnitude higher than that of the normal spin-coating films based transistors. The relationship between the microstructure and the device performance was fully investigated by UV-Vis absorption spectra

grazing incident X-ray diffraction (GIXD)

and atomic force microscopy (AFM). The impressive mobility was attributed to the high crystallinity and ordered molecule packing

which stem from the synergistic effects of SVASP and thermal annealing.

关键词

Keywords

references

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