Metal-free Synthesis of Pyridyl Conjugated Microporous Polymers for Photocatalytic Hydrogen Evolution

Qin-Ruo Zeng; Zhong-Hua Cheng; Chen Yang; Yan He; Nan Meng; Charl F. J. Faul; Yao-Zu Liao

doi:10.1007/s10118-021-2574-3

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Metal-free Synthesis of Pyridyl Conjugated Microporous Polymers for Photocatalytic Hydrogen Evolution

ARTICLE | Updated：2021-05-25

- Metal-free Synthesis of Pyridyl Conjugated Microporous Polymers for Photocatalytic Hydrogen Evolution
- Metal-free Synthesis of Pyridyl Conjugated Microporous Polymers for Photocatalytic Hydrogen Evolution
- Chinese Journal of Polymer Science 2021年39卷第8期页码：1004-1012
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.School of Chemistry, University of Bristol, BS8 1TS Bristol, U.K.
- Author bio：
  
  yzliao@dhu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52073046, 51873036 and 51673039), the Chang Jiang Scholars Program (No. Q2019152), the Fundamental Research Funds for the Central Universities (No. 2232019A3-01), the Shanghai Shuguang Program (No. 19SG28), the Shanghai Natural Science Foundation (No. 19D3859), the Shanghai Pujiang Talent Program (No. 20PJ1400600) and the International Joint Laboratory for Advanced Fiber and Low-Dimension Materials (No. 18520750400).
- DOI：10.1007/s10118-021-2574-3
  中图分类号：
- 收稿：2020-12-26，
  
  修回：2021-1-19，
  
  录用：2021-2-25，
  
  网络首发：2021-05-25，
  
  纸质出版：2021-06-18
- Accepted：
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Zeng, Q. R.; Cheng, Z. H.; Yang, C.; He, Y.; Meng, N.; Faul, C. F. J.; Liao, Y. Z. Metal-free synthesis of pyridyl conjugated microporous polymers for photocatalytic hydrogen evolution. Chinese J. Polym. Sci. 2021, 39, 1004–1012

Qin-Ruo Zeng, Zhong-Hua Cheng, Chen Yang, et al. Metal-free Synthesis of Pyridyl Conjugated Microporous Polymers for Photocatalytic Hydrogen Evolution[J]. Chinese Journal of Polymer Science, 2021, 39(8): 1004-1012.
Zeng, Q. R.; Cheng, Z. H.; Yang, C.; He, Y.; Meng, N.; Faul, C. F. J.; Liao, Y. Z. Metal-free synthesis of pyridyl conjugated microporous polymers for photocatalytic hydrogen evolution. Chinese J. Polym. Sci. 2021, 39, 1004–1012 DOI： 10.1007/s10118-021-2574-3.

Qin-Ruo Zeng, Zhong-Hua Cheng, Chen Yang, et al. Metal-free Synthesis of Pyridyl Conjugated Microporous Polymers for Photocatalytic Hydrogen Evolution[J]. Chinese Journal of Polymer Science, 2021, 39(8): 1004-1012. DOI： 10.1007/s10118-021-2574-3.

摘要

Abstract

Developing efficient

stable and sustainable photocatalysts for water splitting is one of the most significant methods for generating hydrogen. Conjugated microporous polymers

as a new type of organic semiconductor photocatalyst

have adjustable bandgaps and high specific surface areas

and can be synthesized using diverse methods. In this work

we report the design and synthesis of a series of pyridyl conjugated microporous polymers (PCMPs) utilizing polycondensation of aromatic aldehydes and aromatic ketones in the presence of ammonium acetate. PCMPs with different chemical structures were synthesized

via

adjusting monomers with different geometries and contents of nitrogen element

which could adjust the bandgap and photocatalytic performance. Photocatalytic hydrogen evolution rate (HER) up to 1198.9 μmol·h

−1

·g

−1

was achieved on the optimized polymer with a specific surface area of 312 m

·g

−1

under UV-Vis light irradiation (

320 nm). This metal-free synthetic method provides a new avenue to preparing an efficient photocatalyst for hydrogen evolution.

关键词

Keywords

references

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