Improving Impact Toughness of Polylactide/Ethylene-<italic style="font-style: italic">co</italic>-vinyl-acetate Blends <italic style="font-style: italic">via</italic> Adding Fumed Silica Nanoparticles: Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica

Ting-Ting Zhang; Mei-Xi Zhou; Zhen-You Guo; You-Bo Zhao; Di Han; Hao Xiu; Hong-Wei Bai; Qin Zhang; Qiang Fu

doi:10.1007/s10118-021-2565-4

Your Location：

Home >

Browse articles >

Improving Impact Toughness of Polylactide/Ethylene-co-vinyl-acetate Blends via Adding Fumed Silica Nanoparticles: Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica

ARTICLE | Updated：2021-05-25

- Improving Impact Toughness of Polylactide/Ethylene-co-vinyl-acetate Blends via Adding Fumed Silica Nanoparticles: Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica
- Improving Impact Toughness of Polylactide/Ethylene-co-vinyl-acetate Blends via Adding Fumed Silica Nanoparticles: Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica
- Chinese Journal of Polymer Science 2021年39卷第8期页码：1040-1049
- Affiliations：
  
  College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  xiuhao@scu.edu.cn (H.X.)
  qiangfu@scu.edu.cn (Q.F.)
- Funds：
  
  We thank for the assistance with TEM experiments of the Sichuan University Analytical & Testing Center and Dr. Guiping Yuan. This work was financially supported by the National Natural Science Foundation of China (No. 51803130), China Postdoctoral Science Foundation (No. 2018M640915), Sichuan Science and Technology Program (No. 2019JDRC010) and Fundamental Research Funds for Central Universities.
- DOI：10.1007/s10118-021-2565-4
  中图分类号：
- 收稿：2021-01-05，
  
  修回：2021-1-31，
  
  录用：2021-2-9，
  
  网络首发：2021-05-25，
  
  纸质出版：2021-06-18
- Accepted：
Scan QR Code
Zhang, T. T.; Zhou, M. X.; Guo, Z. Y.; Zhao, Y. B.; Han, D.; Xiu, H.; Bai, H. W.; Zhang, Q.; Fu, Q. Improving impact toughness of polylactide/ethylene-co-vinyl-acetate blends via adding fumed silica nanoparticles: effects of specific surface area-dependent interfacial selective distribution of silica. Chinese J. Polym. Sci. 2021, 39, 1040–1049

Ting-Ting Zhang, Mei-Xi Zhou, Zhen-You Guo, et al. Improving Impact Toughness of Polylactide/Ethylene-co-vinyl-acetate Blends via Adding Fumed Silica Nanoparticles: Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica[J]. Chinese Journal of Polymer Science, 2021, 39(8): 1040-1049. DOI: 10.1007/s10118-021-2565-4.
Zhang, T. T.; Zhou, M. X.; Guo, Z. Y.; Zhao, Y. B.; Han, D.; Xiu, H.; Bai, H. W.; Zhang, Q.; Fu, Q. Improving impact toughness of polylactide/ethylene-co-vinyl-acetate blends via adding fumed silica nanoparticles: effects of specific surface area-dependent interfacial selective distribution of silica. Chinese J. Polym. Sci. 2021, 39, 1040–1049 DOI： 10.1007/s10118-021-2565-4.

Ting-Ting Zhang, Mei-Xi Zhou, Zhen-You Guo, et al. Improving Impact Toughness of Polylactide/Ethylene-co-vinyl-acetate Blends via Adding Fumed Silica Nanoparticles: Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica[J]. Chinese Journal of Polymer Science, 2021, 39(8): 1040-1049. DOI: 10.1007/s10118-021-2565-4. DOI：

摘要

Abstract

Adding fumed silica (SiO

) has been considered as an effective method for tailoring the phase morphology and performance of elastomer-toughened plastic binary blends. It has been demonstrated that the selective distribution of SiO

plays a decisive role in the mechanical properties of plastic/elastomer/SiO

nanocomposites

especially for the impact toughness. In this work

we aim to illuminate the role of specific surface area in controlling their selective distribution of fumed SiO

and consequent mechanical properties of plastic/elastomer binary blends. Three types of SiO

with different specific surface areas were incorporated into polylactide/ethylene-

-vinyl-acetate (PLA/EVA) model blends by melt blending directly. It was found that the selective distribution of SiO

is largely determined by their specific surface areas

i.e

. SiO

nanoparticles with low specific surface area has a stronger tendency to be located at the interface between PLA matrix and EVA dispersed phase as compared to those with high specific surface area. The specific surface area-dependent interfacial selective distribution of SiO

is mainly attributed to the extent of increased viscosity of EVA dispersed phase in which SiO

nanoparticles are initially dispersed and resultant migration rate of SiO

nanoparticles. The interfacial localized SiO

nanoparticles induce an obvious enhancement in the impact toughness with strength and modulus well maintained. More importantly

in the case of the same interfacial distribution

toughening efficiency is increased with the specific surface area of SiO

. Therefore

this is an optimum specific surface area of SiO

for the toughening. This work not only provides a novel way to manipulate the selective distribution of SiO

in elastomer-toughened plastic blends toward high-performance

but also gives a deep insight into the role of interfacial localized nanoparticles in the toughening mechanism.

关键词

Keywords

references

Busche, B. J.; Tonelli, A. E.; Balik, C. M. . Morphology of polystyrene/poly(dimethyl siloxane) blends compatibilized with star polymers containing a γ -cyclodextrin core and polystyrene arms . Polymer , 2010 . 51 1465 - 1471 . DOI: 10.1016/j.polymer.2010.01.019 http://doi.org/10.1016/j.polymer.2010.01.019 .

Cui, L. L.; Troeltzsch, C.; Yoon, P. J.; Paul, D. R. . Morphology and properties of nanocomposites formed from poly(ethylene- co -methacrylic acid) ionomers and organoclays: effect of acid neutralization . Macromolecules , 2009 . 42 2599 - 2608 . DOI: 10.1021/ma900105w http://doi.org/10.1021/ma900105w .

Fornes, T. D.; Hunter, D. L.; Paul, D. R. . Nylon-6 nanocomposites from alkylammonium-modified clay: the role of alkyl tails on exfoliation . Macromolecules , 2004 . 37 1793 - 1798 . DOI: 10.1021/ma0305481 http://doi.org/10.1021/ma0305481 .

Montaudo, G.; Puglisi, C.; Samperi, F. . Mechanism of exchange in PBT/PC and PET/PC blends. Composition of the copolymer formed in the melt mixing process . Macromolecules , 1998 . 31 650 - 661 . .

Ryan, A. J. . Polymer science - designer polymer blends . Nat. Mater. , 2002 . 1 8 - 10 . DOI: 10.1038/nmat720 http://doi.org/10.1038/nmat720 .

Tucker, C. L.; Moldenaers, P. . Microstructural evolution in polymer blends . Annu. Rev. Fluid Mech. , 2002 . 34 177 - 210 . DOI: 10.1146/annurev.fluid.34.082301.144051 http://doi.org/10.1146/annurev.fluid.34.082301.144051 .

Macosko, C. W. . Morphology development and control in immiscible polymer blends . Macromol. Symposia , 2000 . 149 171 - 184 . DOI: 10.1002/1521-3900(200001)149:1<171::AID-MASY171>3.0.CO;2-8 http://doi.org/10.1002/1521-3900(200001)149:1<171::AID-MASY171>3.0.CO;2-8 .

Kang, H. L.; Qiao, B.; Wang, R. G.; Wang, Z.; Zhang, L. Q.; Ma, J.; Coates, P. . Employing a novel bioelastomer to toughen polylactide . Polymer , 2013 . 54 2450 - 2458 . DOI: 10.1016/j.polymer.2013.02.053 http://doi.org/10.1016/j.polymer.2013.02.053 .

Utracki, L. A. Commercial polymer blends . Springer Science & amp; Business Media: 2013 .

Sun, C. B.; Mao, H. D. Chen, F.; Fu, Q. . Preparation of polylactide composite with excellent flame retardance and improved mechanical properties. . Chinese J. Polym. Sci. , 2018 . 36 1385 - 1393 . DOI: 10.1007/s10118-018-2150-7 http://doi.org/10.1007/s10118-018-2150-7 .

Premphet, K.; Paecharoenchai, W. . Polypropylene/metallocene ethylene-octene copolymer blends with a bimodal particle size distribution: mechanical properties and their controlling factors . J. Appl. Polym. Sci. , 2002 . 85 2412 - 2418 . DOI: 10.1002/app.10886 http://doi.org/10.1002/app.10886 .

Wu, M.; Wu, Z.; Wang, K.; Zhang, Q.; Fu, Q. . Simultaneous the thermodynamics favorable compatibility and morphology to achieve excellent comprehensive mechanics in PLA/OBC blend . Polymer , 2014 . 55 6409 - 6417 . DOI: 10.1016/j.polymer.2014.10.004 http://doi.org/10.1016/j.polymer.2014.10.004 .

Zolali, A. M.; Favis, B. D. . Toughening of cocontinuous polylactide/polyethylene blends via an interfacially percolated intermediate phase . Macromolecules , 2018 . 51 3572 - 3581 . DOI: 10.1021/acs.macromol.8b00464 http://doi.org/10.1021/acs.macromol.8b00464 .

Xiu, H.; Huang, C. M.; Bai, H. W.; Jiang, J.; Chen, F.; Deng, H.; Wang, K.; Zhang, Q.; Fu, Q. . Improving impact toughness of polylactide/poly(ether)urethane blends via designing the phase morphology assisted by hydrophilic silica nanoparticles . Polymer , 2014 . 55 1593 - 1600 . DOI: 10.1016/j.polymer.2014.01.057 http://doi.org/10.1016/j.polymer.2014.01.057 .

Guo, B. B.; Ji, X. Z.; Wang, W.; Chen, X. T.; Wang, P.; Wang, L. P.; Bai, J. M. . Highly flexible, thermally stable, and static dissipative nanocomposite with reduced functionalized graphene oxide processed through 3D printing . Compos. Part B: Eng. , 2020 . 108598 .

Taguet, A.; Cassagnau, P.; Lopez-Cuesta, J. M. . Structuration, selective dispersion and compatibilizing effect of (nano)fillers in polymer blends . Prog. Polym. Sci. , 2014 . 39 1526 - 1563 . DOI: 10.1016/j.progpolymsci.2014.04.002 http://doi.org/10.1016/j.progpolymsci.2014.04.002 .

Liu, L.; Wang, Y.; Li, Y.; Wu, J.; Zhou, Z.; Jiang, C. . Improved fracture toughness of immiscible polypropylene/ethylene- co -vinyl acetate blends with multiwalled carbon nanotubes . Polymer , 2009 . 50 3072 - 3078 . DOI: 10.1016/j.polymer.2009.04.067 http://doi.org/10.1016/j.polymer.2009.04.067 .

Cao, Y. W.; Zhang, J.; Feng, J. C.; Wu, P. Y. . Compatibilization of immiscible polymer blends using graphene oxide sheets . ACS Nano , 2011 . 5 5920 - 5927 . DOI: 10.1021/nn201717a http://doi.org/10.1021/nn201717a .

de Luna, M. S.; Causa, A.; Filippone, G. . Interfacially-located nanoparticles anticipate the onset of co-continuity in immiscible polymer blends . Polymers , 2017 . 9 393 .

Wu, D. F.; Zhang, Y. S.; Zhang, M.; Yu, W. . Selective localization of multiwalled carbon nanotubes in poly( ε -caprolactone)/polylactide blend . Biomacromolecules , 2009 . 10 417 - 424 . DOI: 10.1021/bm801183f http://doi.org/10.1021/bm801183f .

Chen, J.; Shi, Y. Y.; Yang, J. H.; Zhang, N.; Huang, T.; Chen, C.; Wang, Y.; Zhou, Z. W. . A simple strategy to achieve very low percolation threshold via the selective distribution of carbon nanotubes at the interface of polymer blends . J. Mater. Chem. , 2012 . 22 22398 - 22404 . DOI: 10.1039/c2jm34295b http://doi.org/10.1039/c2jm34295b .

Elias, L.; Fenouillot, F.; Majesté, J. C.; Cassagnau, P. . Morphology and rheology of immiscible polymer blends filled with silica nanoparticles . Polymer , 2007 . 48 6029 - 6040 . DOI: 10.1016/j.polymer.2007.07.061 http://doi.org/10.1016/j.polymer.2007.07.061 .

Mallette, J.; Marquez, A.; Manero, O.; Castro-Rodríguez, R. . Carbon black filled PET/PMMA blends: electrical and morphological studies . Polym. Eng. Sci. , 2000 . 40 2272 - 2278 . DOI: 10.1002/pen.11359 http://doi.org/10.1002/pen.11359 .

Premphet, K.; Horanont, P. . Phase structure of ternary polypropylene/elastomer/filler composites: effect of elastomer polarity . Polymer , 2000 . 41 9283 - 9290 . DOI: 10.1016/S0032-3861(00)00303-7 http://doi.org/10.1016/S0032-3861(00)00303-7 .

Schuster, R.; Meier, J.; Klüppel, M. . The role of interphase in filler partition in rubber blends . Kautschuk Gummi Kunststoffe , 2000 . 53 663 - 674 . .

Sirisinha, C.; Prayoonchatphan, N. . Study of carbon black distribution in BR/NBR blends based on damping properties: influences of carbon black particle size, filler, and rubber polarity . J. Appl. Polym. Sci. , 2001 . 81 3198 - 3203 . DOI: 10.1002/app.1773 http://doi.org/10.1002/app.1773 .

Liu, L.; Jia, C. Y.; He, J. M.; Zhao, F.; Fan, D. P.; Xing, L. X.; Wang, M. Q.; Wang, F.; Jiang, Z. X.; Huang, Y. D. . Interfacial characterization, control and modification of carbon fiber reinforced polymer composites . Compos. Sci. Technol. , 2015 . 121 56 - 72 . DOI: 10.1016/j.compscitech.2015.08.002 http://doi.org/10.1016/j.compscitech.2015.08.002 .

Xiu, H.; Bai, H. W.; Huang, C. M.; Xu, C.; Li, X.; Fu, Q. . Selective localization of titanium dioxide nanoparticles at the interface and its effect on the impact toughness of poly(L-lactide)/poly(ether) urethane blends . Express Polym. Lett. , 2013 . 7 261 - 271 . DOI: 10.3144/expresspolymlett.2013.24 http://doi.org/10.3144/expresspolymlett.2013.24 .

Li, X.; Fu, Z.; Gu, X. Y.; Liu, H. H.; Wang, H. T.; Li, Y. J. . Interfacially located nanoparticles: Barren nanorods versus polymer grafted nanorods . Compos. Part B: Eng. , 2020 . 198 108153 DOI: 10.1016/j.compositesb.2020.108153 http://doi.org/10.1016/j.compositesb.2020.108153 .

Callan, J.; Hess, W.; Scott, C. . Elastomer blends. Compatibility and relative response to fillers. . Rubber Chem. Technol. , 1971 . 44 814 - 837 . .

Liu, H. L.; Zhang, T. T.; Cai, Y.; Deng, S. H.; Bai, D. Y.; Bai, H. W.; Zhang, Q.; Fu, Q. . Towards polylactide/core-shell rubber blends with balanced stiffness and toughness via the formation of rubber particle network with the aid of stereocomplex crystallites . Polymer , 2018 . 159 23 - 31 . DOI: 10.1016/j.polymer.2018.11.013 http://doi.org/10.1016/j.polymer.2018.11.013 .

Sircar, A.; Lamond, T. . Carbon black transfer in blends of cis -poly (butadiene) with other elastomers . Rubber Chem. Technol. , 1973 . 46 178 - 191 . DOI: 10.5254/1.3545009 http://doi.org/10.5254/1.3545009 .

Zaikin, A.; Karimov, R.; Arkhireev, V. . A study of the redistribution conditions of carbon black particles from the bulk to the interface in heterogeneous polymer blends . Colloid J. , 2001 . 63 53 - 59 . DOI: 10.1023/A:1009490108111 http://doi.org/10.1023/A:1009490108111 .

Chiu, F. C.; Ting, M. H. . Thermal properties and phase morphology of melt-mixed poly(trimethylene terephthalate)/polycarbonate blends — mixing time effect . Polym. Test. , 2007 . 26 338 - 350 . DOI: 10.1016/j.polymertesting.2006.12.001 http://doi.org/10.1016/j.polymertesting.2006.12.001 .

Zhang, X.; Maira, B.; Hashimoto, Y.; Wada, T.; Chammingkwan, P.; Thakur, A.; Taniike, T. . Selective localization of aluminum oxide at interface and its effect on thermal conductivity in polypropylene/polyolefin elastomer blends . Compos. Part B-Eng. , 2019 . 162 662 - 670 . DOI: 10.1016/j.compositesb.2019.01.043 http://doi.org/10.1016/j.compositesb.2019.01.043 .

You, W.; Yu, W. . Control of the dispersed-to-continuous transition in polymer blends by viscoelastic asymmetry . Polymer , 2018 . 134 254 - 262 . DOI: 10.1016/j.polymer.2017.11.074 http://doi.org/10.1016/j.polymer.2017.11.074 .

Sui, G. P.; Liu, D. Y.; Liu, Y. H.; Ji, W. J.; Zhang, Q.; Fu, Q. . The dispersion of CNT in TPU matrix with different preparation methods: solution mixing vs melt mixing . Polymer , 2019 . 182 .

Zhang, L.; Lu, C.; Dong, P.; Wang, K. . Realizing self-reinforcement of polyethylene via high-speed shear processing . J. Polym. Res. , 2019 . 26 .

Zhang, L.; Lu, C.; Dong, P.; Wang, K.; Zhang, Q. . Realizing mechanically reinforced all-polyethylene material by dispersing UHMWPE via high-speed shear extrusion . Polymer , 2019 . 180 121711 DOI: 10.1016/j.polymer.2019.121711 http://doi.org/10.1016/j.polymer.2019.121711 .

Elias, L.; Fenouillot, F.; Majeste, J. C.; Alcouffe, P.; Cassagnau, P. . Immiscible polymer blends stabilized with nano-silica particles: rheology and effective interfacial tension . Polymer , 2008 . 49 4378 - 4385 . DOI: 10.1016/j.polymer.2008.07.018 http://doi.org/10.1016/j.polymer.2008.07.018 .

Gubbels, F.; Jerome, R.; Vanlathem, E.; Deltour, R.; Blacher, S.; Brouers, F. . Kinetic and thermodynamic control of the selective localization of carbon black at the interface of immiscible polymer blends . Chem. Mater , 1998 . 10 1227 - 1235 . DOI: 10.1021/cm970594d http://doi.org/10.1021/cm970594d .

Klonos, P.; Dapei, G.; Sulym, I. Y.; Zidropoulos, S.; Sternik, D.; Deryło-Marczewska, A.; Borysenko, M. V.; Gun’ko, V. M.; Kyritsis, A.; Pissis, P. . Morphology and molecular dynamics investigation of PDMS adsorbed on titania nanoparticles: Effects of polymer molecular weight . Eur. Polym. J. , 2016 . 74 64 - 80 . DOI: 10.1016/j.eurpolymj.2015.11.010 http://doi.org/10.1016/j.eurpolymj.2015.11.010 .

Barthel, H.; Heinemann, M.; Stintz, M.; Wessely, B. . Particle sizes of fumed silica . Chem. Eng. Technol. , 1998 . 21 745 - 752 . DOI: 10.1002/(SICI)1521-4125(199809)21:9<745::AID-CEAT745>3.0.CO;2-Q http://doi.org/10.1002/(SICI)1521-4125(199809)21:9<745::AID-CEAT745>3.0.CO;2-Q .

Zhang, W.; Zou, X. S.; Wei, F. Y.; Wang, H. L.; Zhang, G. Y.; Huang, Y. W.; Zhang, Y. . Grafting SiO 2 nanoparticles on polyvinyl alcohol fibers to enhance the interfacial bonding strength with cement . Compos. Part B-Eng. , 2019 . 162 500 - 507 . DOI: 10.1016/j.compositesb.2019.01.034 http://doi.org/10.1016/j.compositesb.2019.01.034 .

Ye, N.; Zheng, J. C.; Ye, X.; Xue, J. J.; Han, D. L.; Xu, H. S.; Wang, Z.; Zhang, L. Q. . Performance enhancement of rubber composites using VOC-Free interfacial silica coupling agent . Compos. Part B: Eng. , 2020 . 202 108301 DOI: 10.1016/j.compositesb.2020.108301 http://doi.org/10.1016/j.compositesb.2020.108301 .

Shi, Y. Y.; Yang, J. H.; Huang, T.; Zhang, N.; Chen, C.; Wang, Y. . Selective localization of carbon nanotubes at the interface of poly(L-lactide)/ethylene- co -vinyl acetate resulting in lowered electrical resistivity . Compos. Part B-Eng. , 2013 . 55 463 - 469 . DOI: 10.1016/j.compositesb.2013.07.012 http://doi.org/10.1016/j.compositesb.2013.07.012 .

Xiu, H.; Qi, X. D.; Bai, H. W.; Zhang, Q.; Fu, Q. . Simultaneously improving toughness and UV-resistance of polylactide/titanium dioxide nanocomposites by adding poly(ether)urethane . Polym. Degrad. Stabil. , 2017 . 143 136 - 144 . DOI: 10.1016/j.polymdegradstab.2017.07.002 http://doi.org/10.1016/j.polymdegradstab.2017.07.002 .

Xiu, H.; Qi, X.; Liu, Z.; Zhou, Y.; Bai, H.; Zhang, Q.; Fu, Q. . Simultaneously reinforcing and toughening of polylactide/carbon fiber composites via adding small amount of soft poly(ether)urethane . Compos. Sci. Technol. , 2016 . 127 54 - 61 . DOI: 10.1016/j.compscitech.2016.02.025 http://doi.org/10.1016/j.compscitech.2016.02.025 .

Xiu, H.; Zhou, Y.; Dai, J.; Huang, C. M.; Bai, H. W.; Zhang, Q.; Fu, Q. . Formation of new electric double percolation via carbon black induced co-continuous like morphology . RSC Adv. , 2014 . 4 37193 - 37196 . DOI: 10.1039/C4RA06836J http://doi.org/10.1039/C4RA06836J .

Xiu, H.; Zhou, Y.; Huang, C. M.; Bai, H. W.; Zhang, Q.; Fu, Q. . Deep insight into the key role of carbon black self-networking in the formation of co-continuous-like morphology in polylactide/poly(ether)urethane blends . Polymer , 2016 . 82 11 - 21 . DOI: 10.1016/j.polymer.2015.10.034 http://doi.org/10.1016/j.polymer.2015.10.034 .

Zhou, Y.; Xiu, H.; Dai, J.; Bai, H. W.; Zhang, Q.; Fu, Q. . Largely reinforced polyurethane via simultaneous incorporation of poly(lactic acid) and multiwalled carbon nanotubes . RSC Adv. , 2015 . 5 30912 - 30919 . DOI: 10.1039/C5RA05115K http://doi.org/10.1039/C5RA05115K .

Ma, P.; Hristova-Bogaerds, D. G.; Goossens, J. G. P.; Spoelstra, A. B.; Zhang, Y.; Lemstra, P. J. . Toughening of poly(lactic acid) by ethylene- co -vinyl acetate copolymer with different vinyl acetate contents . Eur. Polym. J. , 2012 . 48 146 - 154 . DOI: 10.1016/j.eurpolymj.2011.10.015 http://doi.org/10.1016/j.eurpolymj.2011.10.015 .

Khanra, S.; Ganguly, D.; Ghorai, S. K.; Goswami, D.; Chattopadhyay, S. . The synergistic effect of fluorosilicone and silica towards the compatibilization of silicone rubber and fluoroelastomer based high performance blend . J. Polym. Res. , 2020 . 27 .

Metivier, T.; Cassagnau, P. . Compatibilization of silicone/fluorosilicone blends by dynamic crosslinking and fumed silica addition . Polymer , 2018 . 147 20 - 29 . DOI: 10.1016/j.polymer.2018.05.070 http://doi.org/10.1016/j.polymer.2018.05.070 .

Kim, H. N.; Park, C. K.; Kim, I. S.; Kim, S. H. . Compatibilization of immiscible blends of polypropylene and isosorbide containing copolyester with silica nanoparticles . Polym. Eng. Sci. , 2020 . 60 1365 - 1376 . DOI: 10.1002/pen.25387 http://doi.org/10.1002/pen.25387 .

Sumita, M.; Sakata, K.; Asai, S.; Miyasaka, K.; Nakagawa, H. . Dispersion of fillers and the electrical-conductivity of plymer blends filled with carbon-black . Polym. Bull. , 1991 . 25 265 - 271 . DOI: 10.1007/BF00310802 http://doi.org/10.1007/BF00310802 .

Bose, S.; Bhattacharyya, A. R.; Kodgire, P. V.; Misra, A. . Fractionated crystallization in PA6/ABS blends: Influence of a reactive compatibilizer and multiwall carbon nanotubes . Polymer , 2007 . 48 356 - 362 . DOI: 10.1016/j.polymer.2006.11.019 http://doi.org/10.1016/j.polymer.2006.11.019 .

Wu, S. C. Polymer Interface and Adhesion . CRC Press, 1982 .

Lapčík, L.; Otyepka, M.; Otyepková, E.; Lapčíková, B.; Gabriel, R.; Gavenda, A.; Prudilová, B. . Surface heterogeneity: information from inverse gas chromatography and application to model pharmaceutical substances . Curr. Opin. Colloid In. , 2016 . 24 64 - 71 . DOI: 10.1016/j.cocis.2016.06.010 http://doi.org/10.1016/j.cocis.2016.06.010 .

Otsuka, H.; Nagasaki, Y.; Kataoka, K. . Dynamic wettability study on the functionalized PEGylated layer on a polylactide surface constructed by the coating of aldehyde-ended poly(ethylene glycol) (PEG)/polylactide (PLA) block copolymer . Sci. Technol. Adv. Mater. , 2000 . 1 21 - 29 . DOI: 10.1016/S1468-6996(99)00003-0 http://doi.org/10.1016/S1468-6996(99)00003-0 .

Guo, J. M.; Bian, L. C.; Gao, M. . Modeling of nonlinear thermal conduction coefficients of three-phase composites . Appl. Phys. A , 2018 . 124 867 DOI: 10.1007/s00339-018-2269-y http://doi.org/10.1007/s00339-018-2269-y .

Katada, A.; Buys, Y. F.; Tominaga, Y.; Asai, S.; Sumita, M. . Relationship between electrical resistivity and particle dispersion state for carbon black filled poly(ethylene- co -vinyl acetate)/poly(L-lactic acid) blend . Colloid Polym. Sci. , 2005 . 284 134 - 141 . DOI: 10.1007/s00396-005-1348-8 http://doi.org/10.1007/s00396-005-1348-8 .

AG, E. I. Silica Business Line: AEROSIL ® – Fumed Silica Technical Overview .

Ibarra-Gómez, R.; Márquez, A.; Ramos-de Valle, L. F.; Rodríguez-Fernández, O. S. . Influence of the blend viscosity and interface energies on the preferential location of CB and conductivity of BR/EPDM blends . Rubber Chem. Technol. , 2003 . 76 969 - 978 . DOI: 10.5254/1.3547785 http://doi.org/10.5254/1.3547785 .

Garlotta, D. . A Literature review of poly(lactic acid) . J. Polym. Environ. , 2001 . 9 63 - 84 . DOI: 10.1023/A:1020200822435 http://doi.org/10.1023/A:1020200822435 .

Dil, E. J.; Favis, B. D. . Localization of micro- and nano-silica particles in heterophase poly(lactic acid)/poly(butylene adipate-co-terephthalate) blends . Polymer , 2015 . 76 295 - 306 . DOI: 10.1016/j.polymer.2015.08.046 http://doi.org/10.1016/j.polymer.2015.08.046 .

Suzuki, N.; Yatsuyanagi, F.; Ito, M.; Kaidou, H. . Effects of surface chemistry of silica particles on secondary structure and tensile properties of silica-filled rubber systems . J. Appl. Polym. Sci. , 2002 . 86 1622 - 1629 . DOI: 10.1002/app.11050 http://doi.org/10.1002/app.11050 .

Wang, M. J.; Morris, M. D.; Kutsovsky, Y. . Effect of fumed silica surface area on silicone rubber reinforcement . Kautschuk Gummi Kunststoffe , 2008 . 61 107 - 117 . .

Yue, Y. L.; Zhang, H.; Zhang, Z.; Chen, Y. F. . Polymer–filler interaction of fumed silica filled polydimethylsiloxane investigated by bound rubber . Compos. Sci. Technol. , 2013 . 86 1 - 8 . DOI: 10.1016/j.compscitech.2013.06.019 http://doi.org/10.1016/j.compscitech.2013.06.019 .

Moller, K.; Kobler, J.; Bein, T. . Colloidal suspensions of nanometer-sized mesoporous silica . Adv. Funct. Mater. , 2007 . 17 605 - 612 . DOI: 10.1002/adfm.200600578 http://doi.org/10.1002/adfm.200600578 .

Nofar, M.; Salehiyan, R.; Ciftci, U.; Jalali, A.; Durmus, A. . Ductility improvements of PLA-based binary and ternary blends with controlled morphology using PBAT, PBSA, and nanoclay . Compos. Part B-Eng. , 2020 . 182 .

Wang, J. F.; Jin, X. X.; Li, C. H.; Wang, W. J.; Wu, H.; Guo, S. Y. . Graphene and graphene derivatives toughening polymers: Toward high toughness and strength . Chem. Eng. J. , 2019 . 370 831 - 854 . DOI: 10.1016/j.cej.2019.03.229 http://doi.org/10.1016/j.cej.2019.03.229 .

浏览量

147

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Synergistic Efficiency of Tricresyl Phosphate and Montmorillonite on the Mechanical Characteristics and Flame Retardant Properties of Polylactide and Poly(butylene succinate) Blends

Crystallization Properties, Heat Resistance, and Hydrolytic Resistance of Poly(L-lactide)/Poly(D-lactide) Blend Enhanced by In situ Formation of Stereocomplex Polylactide

Phenylimino-pyridine-phenolate Zinc Complexes for Polylactide Synthesis and Chemical Recycling to Monomers

Design of Tough, yet Strong, Heat-resistant PLA/PBAT Blends with Reconfigurable Shape Memory Behavior by Engineering Exchangeable Covalent Crosslinks

Tunable Circularly Polarized Luminescence of Helical Poly(phenylacetylene)s via Side-chain-to-Backbone Förster Resonance Energy Transfer

Improving Impact Toughness of Polylactide/Ethylene-co-vinyl-acetate Blends via Adding Fumed Silica Nanoparticles: Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica

Improving Impact Toughness of Polylactide/Ethylene-co-vinyl-acetate Blends via Adding Fumed Silica Nanoparticles: Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica

DOI：10.1007/s10118-021-2565-4

摘要

Abstract

关键词

Keywords

references