a.College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China
b.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
jcyu@suda.edu.cn (J.C.Y.)
zhangym@dhu.edu.cn (Y.M.Z.)
zhjpan@suda.edu.cn (Z.J.P.)
收稿:2020-10-09,
修回:2021-1-20,
录用:2021-2-1,
网络首发:2021-04-30,
纸质出版:2021-05-14
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Yu, J. C.; Chen, K.; Ji, H.; Zhang, Y.; Zhang, Y. M.; Pan, Z. J. Facile and large-scale fabrication of self-crimping elastic fibers for large strain sensors. Chinese J. Polym. Sci. 2021, 39, 914–924
Jin-Chao Yu, Kang Chen, Hong Ji, et al. Facile and Large-scale Fabrication of Self-crimping Elastic Fibers for Large Strain Sensors[J]. Chinese Journal of Polymer Science, 2021, 39(7): 914-924.
Yu, J. C.; Chen, K.; Ji, H.; Zhang, Y.; Zhang, Y. M.; Pan, Z. J. Facile and large-scale fabrication of self-crimping elastic fibers for large strain sensors. Chinese J. Polym. Sci. 2021, 39, 914–924 DOI: 10.1007/s10118-021-2560-1.
Jin-Chao Yu, Kang Chen, Hong Ji, et al. Facile and Large-scale Fabrication of Self-crimping Elastic Fibers for Large Strain Sensors[J]. Chinese Journal of Polymer Science, 2021, 39(7): 914-924. DOI: 10.1007/s10118-021-2560-1.
Stretchable conductive fibers offer unparalleled advantages in the development of wearable strain sensors for smart textiles due to their excellent flexibility and weaveability. However
the practical applications of these fibers in wearable devices are hindered by either contradictory properties of conductive fibers (high stretchability versus high sensing stability)
or lack of manufacturing scalability. Herein
we present a facile approach for highly stretchable self-crimping fiber strain sensors based on a polyether-ester (TPEE) elastomer matrix using a side-by-side bicomponent melt-spinning process involving two parallel but attached components with different shrinkage properties. The TPEE component serves as a highly elastic mechanical support layer within the bicomponent fibers
while the conductive component (E-TPEE) of carbon black (CB)
multiwalled carbon nanotubes (MWCNTs) and TPEE works as a strain-sensitive layer. In addition to the intrinsic elasticity of the matrix
the TPEE/E-TPEE bicomponent fibers present an excellent form of elasticity due to self-crimping. The self-crimping elongation of the fibers can provide a large deformation
and after the crimp disappears
the intrinsic elastic deformation is responsible for monitoring the strain sensing. The reliable strain sensing range of the TPEE/E-TPEE composite fibers was 160%−270% and could be regulated by adjusting the crimp structure. More importantly
the TPEE/E-TPEE fibers had a diameter of 30−40 μm and tenacity of 40−50 MPa
showing the necessary practicality. This work introduces new possibilities for fiber strain sensors produced in standard industrial spinning machines.
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