Preparation and Performance of HGM/PPENK-based High Temperature-resistant Thermal Insulating Coatings

Lei Song; Li-Shuai Zong; Jin-Yan Wang; Xi-Gao Jian

doi:10.1007/s10118-021-2551-x

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Preparation and Performance of HGM/PPENK-based High Temperature-resistant Thermal Insulating Coatings

ARTICLE | Updated：2021-04-25

- Preparation and Performance of HGM/PPENK-based High Temperature-resistant Thermal Insulating Coatings
- Preparation and Performance of HGM/PPENK-based High Temperature-resistant Thermal Insulating Coatings
- Chinese Journal of Polymer Science 2021年39卷第6期页码：770-778
- Affiliations：
  
  State Key Laboratory of Fine Chemicals, Department of Polymer Science and Materials, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
- Author bio：
  
  zongls@dlut.edu.cn (L.S.Z.)
  jian4616@dlut.edu.cn (X.G.J.)
- Funds：
  
  This study was financially supported by the National Natural Science Foundation of China (No. 51903028) and China Postdoctoral Science Foundation (No. 2017M611217).
- DOI：10.1007/s10118-021-2551-x
  中图分类号：
- 收稿：2020-11-08，
  
  修回：2020-12-22，
  
  录用：2021-1-13，
  
  网络首发：2021-04-25，
  
  纸质出版：2021-04-15
- Accepted：
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Song, L.; Zong, L. S.; Wang, J. Y.; Jian, X. G. Preparation and performance of HGM/PPENK-based high temperature-resistant thermal insulating coatings. Chinese J. Polym. Sci. 2021, 39, 770–778

Lei Song, Li-Shuai Zong, Jin-Yan Wang, et al. Preparation and Performance of HGM/PPENK-based High Temperature-resistant Thermal Insulating Coatings[J]. Chinese Journal of Polymer Science, 2021, 39(6): 770-778.
Song, L.; Zong, L. S.; Wang, J. Y.; Jian, X. G. Preparation and performance of HGM/PPENK-based high temperature-resistant thermal insulating coatings. Chinese J. Polym. Sci. 2021, 39, 770–778 DOI： 10.1007/s10118-021-2551-x.

Lei Song, Li-Shuai Zong, Jin-Yan Wang, et al. Preparation and Performance of HGM/PPENK-based High Temperature-resistant Thermal Insulating Coatings[J]. Chinese Journal of Polymer Science, 2021, 39(6): 770-778. DOI： 10.1007/s10118-021-2551-x.

摘要

Abstract

Novel high temperature-resistant coatings with high mechanical strength and thermal-insulating performance were prepared with poly(ether nitrile ketone) (PPENK) resin as matrix and hollow glass microspheres (HGMs) as thermal-insulating filler. The corresponding mechanical and thermal-insulating study indicated that the mechanical properties of the coatings decreased with the increase of HGM content

and were improved after surface modification of HGM by KH570 resulting in enhancement of interaction between HGM and PPENK resin. The thermal conductivity of HGM/PPENK thermal-insulating coating decreased with the increase of HGM content and coating thickness

along with the decrease of the true density. It also showed slight increase trend due to HGMs surface modification. The HGM/PPENK coating filled with modified HGMs showed better thermal resistance than that of unmodified HGM/PPENK coating. The thermal decomposition temperature at 5% weight loss of the coating containing modified HGMs was 10 °C lower than that of pure PPENK

and 40 °C higher than that of neat HGM/PPENK coating. The coating exhibited commendable appearance after 400 °C for 30 min. The merits of HGM/PPENK-based thermal coatings obviously demonstrated promising prospect in thermal protection fields.

关键词

Keywords

references

Hong, X. Y.; Feng, H. B.; Shen, L. Coatings chemistry (in Chinese), Science Press, Beijing, 2016 , p.2−3.

Yang, H.; Liu, Z.; Ding, Y.; Lin, R.; Ban, G.; Tao, R . Research progress of high temperature resistant anticorrosive coatings on metal surface . Surf. Technol. , 2017 . 46 216 - 222 . .

Jia, Z . Development of thermal barrier coating on resin matrix composites . Mater. Prot. , 2002 . 35 7 - 8 . .

Zhou, Q. F.; Fan, X. H.; Xie, X. F. High temperature resistant polymers and their composites (in Chinese), Chemical Industry Press, Beijing, 2004 , p.75−76.

Wang, H. Q.; Li, L.; Zhuang, G. S. Coating and coating technology (in Chinese), Chemical Industry Press, Beijing, 2012 , p.1−7.

Qi, Y.; Zhang, G.; Xia, J.; Lian, W.; Zhang, Y.; Ma, C.; Zhang, G . Progress in thermal insulation coatings . Paint Coat. Ind. , 2019 . 49 80 - 87 . .

Eduok, U.; Faye, O.; Szpunar, J . Recent developments and applications of protective silicone coatings: a review of pdms functional materials . Prog. Org. Coat. , 2017 . 111 124 - 163 . DOI: 10.1016/j.porgcoat.2017.05.012 http://doi.org/10.1016/j.porgcoat.2017.05.012 .

RodriGuez, R.; Carolina, D. L. H. A.; Ekanayake, P.; Mcdonald, P. J.; Keddie, J. L.; Barandiaran, M. A. J.; Asua, J. M . Correlation of silicone incorporation into hybrid acrylic coatings with the resulting hydrophobic and thermal properties . Macromolecules , 2008 . 41 8537 - 8546 . DOI: 10.1021/ma8006015 http://doi.org/10.1021/ma8006015 .

Gao, H.; Lin, C.; Wang, L.; Zhou, J.; Song, H . Preparation and characterization of surface microstructure of acrylate modified silicone resin coating . Paint Coat. Ind. , 2014 . 44 12 - 16 . .

Ba, M.; Zhang, Z.; Qi, Y . Research progress of silicone antifouling paints . Surf. Technol. (in Chinese) , 2017 . 46 1 - 8 . .

Mikhailova, A. M.; Tamboura, M.; Jia, M. Q . Synthesis, characterization, and analyses of mechanical, adhesion, and thermal properties of polysiloxane resin modified with segmented polyurethane . J. Coat. Technol. Res. , 2013 . 10 97 - 108 . DOI: 10.1007/s11998-012-9424-8 http://doi.org/10.1007/s11998-012-9424-8 .

Wang, J.; Jian, X . Progress in synthesis and applications of high performance phthalazinone-containing resins . Polym. Mater. Sci. Eng. , 2014 . 30 145 - 150 . .

Wang, J.; Jian, X . Applications of high performance phthalazinone-containing resins in insulating materials . Insulat. Mater. , 2016 . 49 17 - 23 . .

Yan, Q.; Wang, J.; Li, S.; Liu, Z.; Jian, X . Poly(phthalazinone ether nitrile ketone) for enamel wire . Chin. J. Mater. Res. , 2006 . 20 287 - 290 . .

Dong, N. Study on high temperature adhesive bearing aryl-s-triazine strcture . Dalian University of Technology, (Dalian), 2012 .

Ren, S.; Hu, X.; Ren, H.; Wang, M.; Guo, A.; Liu, J.; Du, H.; Xian, L . Development of a buoyancy material of hollow glass microspheres/SiO 2 for high-temperature application . J. Alloy. Compd. , 2017 . 721 213 - 219 . DOI: 10.1016/j.jallcom.2017.06.002 http://doi.org/10.1016/j.jallcom.2017.06.002 .

Herrera-Ramírez, L. C.; Cano, M.; Guzman de Villoria, R . Low thermal and high electrical conductivity in hollow glass microspheres covered with carbon nanofiber-polymer composites . Compos. Sci. Technol. , 2017 . 151 211 - 218 . DOI: 10.1016/j.compscitech.2017.08.020 http://doi.org/10.1016/j.compscitech.2017.08.020 .

Brown, J.; Oldenkamp, J.; Gamache, R.; Grbovic, D.; Kartalov, E . Hollow-microsphere composite offers depth-independent superior thermal insulation for diver suits . Mater. Res. Express , 2019 . 6 .

Yu, S. Z.; Li, X. D.; Guo, X. Y.; Li, Z. R.; Zou, M. S . Curing and characteristics of N , N' , N' -tetraepoxypropyl-4,4'-diaminodiphenylmethane epoxy resin-based buoyancy material . Polymers , 2019 . 11 15 .

Zhu, B. L.; Wang, J.; Zheng, H.; Ma, J.; Wu, J.; Gan, Z. H.; Liu, J . Thermal conductivity and dielectric properties of immiscible ldpe/epoxy blend filled with hybrid filler consisting of HGM and nitride particle . J. Alloy. Compd. , 2017 . 701 499 - 507 . DOI: 10.1016/j.jallcom.2017.01.182 http://doi.org/10.1016/j.jallcom.2017.01.182 .

Zou, Y.; Zhan, Y.; Zhao, R.; Liu, X . Low dielectric permittivity and high thermal stability composites based on crosslinkable poly (arylene ether nitrile) and hollow glass microsphere . J. Mater. Sci. Mater. Electron. , 2013 . 24 1238 - 1242 . DOI: 10.1007/s10854-012-0913-4 http://doi.org/10.1007/s10854-012-0913-4 .

Wang, Z.; Zhang, T.; Park, B. K.; Lee, W. I.; Hwang, D. J . Hybrid nanostructure formation on hollow glass microparticles as thermally insulating composite elements . Nanosci. Nanotechnol. Lett. , 2017 . 9 544 - 550 . DOI: 10.1166/nnl.2017.2363 http://doi.org/10.1166/nnl.2017.2363 .

Feng, C.; Zhang, H.; Ii, C.; Jia, W.; Lai, F. . The effects of hollow glass microsphere modification on the road performances and thermal performance of asphalt binder and mixture . Constr. Build Mater. , 2019 . 220 64 - 75 . DOI: 10.1016/j.conbuildmat.2019.05.183 http://doi.org/10.1016/j.conbuildmat.2019.05.183 .

Yu, X.; Xu, C . Influence of high-performance hollow glass microsphere on thermal insulation of coatings . Paint Coat. Ind. , 2014 . 44 1 - 5 . .

Wang, J.; Tian, Y.; Zhang, J . Thermal insulating epoxy composite coatings containing sepiolite/hollow glass microspheres as binary fillers: morphology, simulation and application . Sci. Eng. Compos. Mater. , 2017 . 24 379 - 386 . DOI: 10.1515/secm-2014-0397 http://doi.org/10.1515/secm-2014-0397 .

Zhang, D.; Li, H.; Qian, H.; Wang, L.; Li, X . Double layer water-borne heat insulation coatings containing hollow glass microspheres (HGMs) . Pigm. Resin. Technol. , 2016 . 45 346 - 353 . DOI: 10.1108/PRT-04-2015-0041 http://doi.org/10.1108/PRT-04-2015-0041 .

Li, B.; Yuan, J.; An, Z.; Zhang, J . Effect of microstructure and physical parameters of hollow glass microsphere on insulation performance . Mater. Lett. , 2011 . 65 1992 - 1994 . DOI: 10.1016/j.matlet.2011.03.062 http://doi.org/10.1016/j.matlet.2011.03.062 .

Hu, Y.; Mei, R.; An, Z.; Zhang, J . Silicon rubber/hollow glass microsphere composites: influence of broken hollow glass microsphere on mechanical and thermal insulation property . Compos. Sci. Technol. , 2013 . 79 64 - 69 . DOI: 10.1016/j.compscitech.2013.02.015 http://doi.org/10.1016/j.compscitech.2013.02.015 .

Ozkutlu, M.; Dilek, C.; Bayram, G . Effects of hollow glass microsphere density and surface modification on the mechanical and thermal properties of poly(methyl methacrylate) syntactic foams . Compos. Struct. , 2018 . 202 545 - 550 . DOI: 10.1016/j.compstruct.2018.02.088 http://doi.org/10.1016/j.compstruct.2018.02.088 .

Vahtrus, M.; Oras, S.; Antsov, M.; Reedo, V.; Maeorg, U.; Lohmus, A.; Saal, K.; Lohmus, R . Mechanical and thermal properties of epoxy composite thermal insulators filled with silica aerogel and hollow glass microspheres . P. Est. Acad. Sci. , 2017 . 66 339 - 346 . DOI: 10.3176/proc.2017.4.03 http://doi.org/10.3176/proc.2017.4.03 .

Patankar, S. N.; Das, A.; Kranov, Y. A. . Interface engineering via compatibilization in HDPE composite reinforced with sodium borosilicate hollow glass microspheres . Compos. Part A-Appl. S , 2009 . 40 879 - 903 . DOI: 10.1016/j.compositesa.2009.04.016 http://doi.org/10.1016/j.compositesa.2009.04.016 .

Kumar, B. R. B.; Zeltmann, S. E.; Doddamani, M.; Gupta, N.; Uzma; Gurupadu, S.; Sailaja, R. R. N . Effect of cenosphere surface treatment and blending method on the tensile properties of thermoplastic matrix syntactic foams . J. Appl. Polym. Sci. , 2016 . 133 .

Yan, Q. L. A study on high temperature resistant insulation lacquer and coatings prepared from poly(phthalazinone ether). PhD diss., Dalian University of Technology (Dalian), 2006 .

Kim, H. M.; Kim, H. S.; Kim, S. Y.; Youn, J. R . Silica aerogel/epoxy composites with preserved aerogel pores and low thermal conductivity . e-Polymers , 2015 . 15 111 - 117 . DOI: 10.1515/epoly-2014-0165 http://doi.org/10.1515/epoly-2014-0165 .

Zhu, B. L.; Zheng, H.; Wang, J.; Ma, J.; Wu, J.; Wu, R . Tailoring of thermal and dielectric properties of ldpe-matrix composites by the volume fraction, density, and surface modification of hollow glass microsphere filler . Compos. Pt. B-Eng. , 2014 . 58 91 - 102 . DOI: 10.1016/j.compositesb.2013.10.029 http://doi.org/10.1016/j.compositesb.2013.10.029 .

Davraz, M.; Koru, M.; Akdag, A. E. The effect of physical properties on thermal conductivity of lightweight aggregate. In World multidisciplinary earth sciences symposium, WMESS 2015 , Drusa, M.; Marschalko, M.; Yilmaz, I.; Segallini, A.; Ferrero, A. M.; Bednarik, M., Eds. 2015 ; Vol. 15, pp 85−92.

Skochdopole, R. E . The thermal conductivity of foam plastics . Chem. Eng. Prog. , 1961 . 57 55 - 59 . .

Hutter, C.; Büchi, D.; Zuber, V.; von Rohr, P. R . Heat transfer in metal foams and designed porous media . Chem. Eng. Sci. , 2011 . 66 3806 - 3814 . DOI: 10.1016/j.ces.2011.05.005 http://doi.org/10.1016/j.ces.2011.05.005 .

Aduda, B. O . Effective thermal conductivity of loose particulate systems . J. Mater. Sci. , 1996 . 31 6441 - 6448 . DOI: 10.1007/BF00356246 http://doi.org/10.1007/BF00356246 .

Liang, J. Z.; Li, F. H . Heat transfer in polymer composites filled with inorganic hollow micro-spheres: a theoretical model . Polym. Test. , 2007 . 26 1025 - 1030 . DOI: 10.1016/j.polymertesting.2007.07.002 http://doi.org/10.1016/j.polymertesting.2007.07.002 .

Yang, H.; Jiang, Y.; Liu, H.; Xie, D.; Wan, C.; Pan, H.; Jiang, S . Mechanical, thermal and fire performance of an inorganic-organic insulation material composed of hollow glass microspheres and phenolic resin . J. Colloid Interf. Sci. , 2018 . 530 163 - 170 . DOI: 10.1016/j.jcis.2018.06.075 http://doi.org/10.1016/j.jcis.2018.06.075 .

Rich, D. C.; Sichel, E. K.; Cebe, P . Effect of cure conditions on probimide 32 polyamide-imide . J. Appl. Polym. Sci. , 1997 . 63 1113 - 1126 . DOI: 10.1002/(SICI)1097-4628(19970228)63:9<1113::AID-APP3>3.0.CO;2-K http://doi.org/10.1002/(SICI)1097-4628(19970228)63:9<1113::AID-APP3>3.0.CO;2-K .

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