Influence of Liquid Isoprene Rubber on Strain Softening of Carbon Black Filled Isoprene Rubber Nanocomposites

Feng-Yi Hou; Yi-Hu Song; Qiang Zheng

doi:10.1007/s10118-021-2550-y

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Influence of Liquid Isoprene Rubber on Strain Softening of Carbon Black Filled Isoprene Rubber Nanocomposites

ARTICLE | Updated：2021-04-14

- Influence of Liquid Isoprene Rubber on Strain Softening of Carbon Black Filled Isoprene Rubber Nanocomposites
- Influence of Liquid Isoprene Rubber on Strain Softening of Carbon Black Filled Isoprene Rubber Nanocomposites
- Chinese Journal of Polymer Science 2021年39卷第7期页码：887-895
- Affiliations：
  
  MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  s_yh0411@zju.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. U1908221, 51873190 and 51790503) and the Fundamental Research Funds for the Central Universities (No. 2020XZZX002-08).
- DOI：10.1007/s10118-021-2550-y
  中图分类号：
- 收稿：2020-12-03，
  
  修回：2021-1-1，
  
  录用：2021-1-11，
  
  网络首发：2021-04-14，
  
  纸质出版：2021-05-14
- Accepted：
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Hou, F. Y.; Song, Y. H.; Zheng, Q. Influence of liquid isoprene rubber on strain softening of carbon black filled isoprene rubber nanocomposites. Chinese J. Polym. Sci. 2021, 39, 887–895

Feng-Yi Hou, Yi-Hu Song, Qiang Zheng. Influence of Liquid Isoprene Rubber on Strain Softening of Carbon Black Filled Isoprene Rubber Nanocomposites[J]. Chinese Journal of Polymer Science, 2021, 39(7): 887-895.
Hou, F. Y.; Song, Y. H.; Zheng, Q. Influence of liquid isoprene rubber on strain softening of carbon black filled isoprene rubber nanocomposites. Chinese J. Polym. Sci. 2021, 39, 887–895 DOI： 10.1007/s10118-021-2550-y.

Feng-Yi Hou, Yi-Hu Song, Qiang Zheng. Influence of Liquid Isoprene Rubber on Strain Softening of Carbon Black Filled Isoprene Rubber Nanocomposites[J]. Chinese Journal of Polymer Science, 2021, 39(7): 887-895. DOI： 10.1007/s10118-021-2550-y.

摘要

Abstract

The reinforcement of rubbers by nanoparticles is always accompanied with enhanced dissipation of mechanical energy upon large deformations. Methods for solving the contradiction between improving reinforcement and reducing energy dissipation for rubber nanocomposites have not been well developed. Herein carbon black (CB) filled isoprene rubber (IR)/liquid isoprene rubber (LR) blend nanocomposites with similar crosslink density (

) are prepared and influence of LR on the strain softening behaviors including Payne effect under large amplitude shear deformation and Mullins effect under cyclic uniaxial deformation is investigated. The introduction of LR could improve the frequency sensitivity of loss modulus and reduce critical strain amplitude for Payne effect and loss modulus at the low amplitudes. Meanwhile

tuning

and LR content allows reducing mechanical hysteresis in Mullins effect without significant impact on the mechanical performances. The investigation is illuminating for manufacturing nanocomposite vulcanizates with balanced mechanical hysteresis and reinforcement effect.

关键词

Keywords

references

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