Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to <italic style="font-style: italic">T</italic><sub>m</sub>=<italic style="font-style: italic">T</italic><sub>c</sub> Line

Zhi-Ning Xie; Hai-Mu Ye; Tong Chen; Tian-Ze Zheng; Jun Xu; Bao-Hua Guo

doi:10.1007/s10118-021-2530-2

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Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to T_m=T_c Line

ARTICLE | Updated：2020-12-11

- Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to T_m=T_c Line
- Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to T_m=T_c Line
- Chinese Journal of Polymer Science 2021年39卷第6期页码：745-755
- Affiliations：
  
  a.Advanced Materials Laboratory, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
  b.Department of Materials Science and Engineering, College of New Energy and Materials, China University of Petroleum, Beijing 102249, China
- Author bio：
  
  jun-xu@tsinghua.edu.cn (J.X.)
  bhguo@mail.tsinghua.edu.cn (B.H.G.)
- Funds：
  
  This work was financially supported by the National National Science Foundation of China (Nos. U1862205, 51473085, and 21873054) and Tsinghua University Initiative Scientific Research Program (No. 20194180048). The authors wish to thank Prof. Wei Miao from School of Materials, Tsinghua University, who kindly offers great help in WAXD data analysis. We thank Dr. Ying Lu from Changchun Institute of Applied Chemistry, and Dr. Yu Wang from the Institute of Chemistry Chinese Academy of Sciences, for their valuable advice and discussion in data analyses of SAXS. The authors declare no conflict of interest.
- DOI：10.1007/s10118-021-2530-2
  中图分类号：
- 收稿：2020-10-28，
  
  修回：2020-11-22，
  
  录用：2020-11-23，
  
  网络首发：2020-12-11，
  
  纸质出版：2021-04-15
- Accepted：
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Xie, Z. N.; Ye, H. M.; Chen, T.; Zheng, T. Z.; Xu, J.; Guo, B. H. Melting and annealing peak temperatures of poly(butylene succinate) on the same Hoffman-Weeks plot parallel to , T,_m=, T,_c line. Chinese J. Polym. Sci. 2021, 39, 745–755 DOI: 10.1007/s10118-021-2530-2.

Zhi-Ning Xie, Hai-Mu Ye, Tong Chen, et al. Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to T_m=T_c Line[J]. Chinese Journal of Polymer Science, 2021, 39(6): 745-755. DOI: 10.1007/s10118-021-2530-2.
Xie, Z. N.; Ye, H. M.; Chen, T.; Zheng, T. Z.; Xu, J.; Guo, B. H. Melting and annealing peak temperatures of poly(butylene succinate) on the same Hoffman-Weeks plot parallel to , T,_m=, T,_c line. Chinese J. Polym. Sci. 2021, 39, 745–755 DOI: 10.1007/s10118-021-2530-2. DOI：

Zhi-Ning Xie, Hai-Mu Ye, Tong Chen, et al. Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to T_m=T_c Line[J]. Chinese Journal of Polymer Science, 2021, 39(6): 745-755. DOI: 10.1007/s10118-021-2530-2. DOI：

摘要

Abstract

The crystallization and melting behavior of polymers is of theoretical importance. In this work

poly(butylene succinate) (PBS) was selected as an example to study such behavior at low supercooling

via

introduction of the extended-chain crystal (ECC) of the same polymer as nucleating agent. The crystallization of PBS with its ECC as nucleating agent in a wide temperature range (90–127 °C) and the following melting behavior were studied. It is revealed that the melting point (

for

≥113 °C) and the annealing peak temperature (

for

=90–100 °C) show similar asymptotic behavior. Both

and

approach to a value of

. 3.3 °C higher than the corresponding

when the crystallization time

approaches the starting point. That is to say

the Hoffman-Weeks plot is parallel to

line. The crystallization line became parallel to the melting line when PBS was crystallized at

higher than 102 °C. Based on these results

we propose that the parallel relationship and the intrinsic similarity between the

and the

observed at the two ends of the

range could be attributed to the metastable crystals formed at the beginning of crystallization.

关键词

Keywords

references

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Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to Tm=Tc Line

Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to Tm=Tc Line

DOI：10.1007/s10118-021-2530-2

摘要

Abstract

关键词

Keywords

references

Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to T_m=T_c Line

Melting and Annealing Peak Temperatures of Poly(butylene succinate) on the Same Hoffman-Weeks Plot Parallel to T_m=T_c Line