Barium Titanate-reinforced Acrylonitrile-Butadiene Rubber: Synergy Effect of Carbon-based Secondary Filler

Wannarat Chueangchayaphan; Piyawadee Luangchuang; Narong Chueangchayaphan; Muhammad Azwadi Sulaiman; Yeampon Nakaramontri

doi:10.1007/s10118-021-2528-9

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Barium Titanate-reinforced Acrylonitrile-Butadiene Rubber: Synergy Effect of Carbon-based Secondary Filler

ARTICLE | Updated：2021-01-05

- Barium Titanate-reinforced Acrylonitrile-Butadiene Rubber: Synergy Effect of Carbon-based Secondary Filler
- Barium Titanate-reinforced Acrylonitrile-Butadiene Rubber: Synergy Effect of Carbon-based Secondary Filler
- Chinese Journal of Polymer Science 2021年39卷第6期页码：725-735
- Affiliations：
  
  a.Faculty of Science and Industrial Technology, Prince of Songkla University, Surat Thani Campus, 84000 Surat Thani, Thailand
  b.Advanced Materials Research Cluster, Faculty Bioengineering and Technology, Universiti Malaysia Kelantan, 17600 Jeli, Kelantan, Malaysia
  c.Sustainable Polymer & Innovative Composite Materials Research Group, Department of Chemistry, Faculty of Science, King Mongkut’s University of Technology Thonburi, 10140 Bangkok, Thailand
- Author bio：
  
  yeampon.nak@kmutt.ac.th
- Funds：
  
  This work was financially supported by a grant from the government budget of Prince of Songkla University and Natural Rubber Innovation Research Institute (NR-IRI) (No. SIT610284S), the graduate school of Prince of Songkla University and by Prince of Songkla University, Surat Thani Campus. The authors would like to express their gratitude to Faculty of Science, Department of Chemistry, King Mongkut’s University of Technology Thonburi, Bangkok, Thailand, and to the Faculty of Earth Science, Universiti Malaysia Kelantan for providing their facilities and equipment. We are grateful to Assoc. Prof. Dr. Seppo Karrila for his assistance with manuscript preparation.
- DOI：10.1007/s10118-021-2528-9
  中图分类号：
- 收稿：2020-07-12，
  
  修回：2020-11-1，
  
  录用：2020-11-19，
  
  网络首发：2021-01-05，
  
  纸质出版：2021-04-15
- Accepted：
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Chueangchayaphan, W.; Luangchuang, P.; Chueangchayaphan, N.; Sulaiman, M. A.; Nakaramontri, Y. Barium titanate-reinforced acrylonitrile-butadiene rubber: synergy effect of carbon-based secondary filler. Chinese J. Polym. Sci. 2021, 39, 725–735

Wannarat Chueangchayaphan, Piyawadee Luangchuang, Narong Chueangchayaphan, et al. Barium Titanate-reinforced Acrylonitrile-Butadiene Rubber: Synergy Effect of Carbon-based Secondary Filler[J]. Chinese Journal of Polymer Science, 2021, 39(6): 725-735.
Chueangchayaphan, W.; Luangchuang, P.; Chueangchayaphan, N.; Sulaiman, M. A.; Nakaramontri, Y. Barium titanate-reinforced acrylonitrile-butadiene rubber: synergy effect of carbon-based secondary filler. Chinese J. Polym. Sci. 2021, 39, 725–735 DOI： 10.1007/s10118-021-2528-9.

Wannarat Chueangchayaphan, Piyawadee Luangchuang, Narong Chueangchayaphan, et al. Barium Titanate-reinforced Acrylonitrile-Butadiene Rubber: Synergy Effect of Carbon-based Secondary Filler[J]. Chinese Journal of Polymer Science, 2021, 39(6): 725-735. DOI： 10.1007/s10118-021-2528-9.

摘要

Abstract

Acrylonitrile rubber (NBR) composites filled with barium titanate (BT) were prepared using an internal mixer and a two-roll mill. Also

a secondary filler

namely carbon nanotubes (CNT)

was added in order to find a potential synergistic blend ratio of BT and CNT. The cure characteristics

tensile and dielectric properties (dielectric constant and dielectric loss) of the composites were determined. It was found that NBR/BT composites with CNT secondary filler

at a proper BT:CNT ratio

exhibited shorter scorch time (

) and cure time (

c90

) together with superior tensile properties and reinforcement efficiency

relative to the one with only the primary filler. In addition

the NBR/BT-CNT composite with 80 phr BT and 1−2 phr CNT had dielectric constant of 100−500

dielectric loss of 12−100 and electrical conductivity below 10

−4

S/m together with high thermal stability. Thus

with a proper BT:CNT mix and filler loading

we can produce mechanically superior rubber composites that are easy to process and low-cost

for flexible dielectric materials application.

关键词

Keywords

references

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