Enhanced Gas Separation Performance by Embedding Submicron Poly(ethylene glycol) Capsules into Polyetherimide Membrane

Ying-Ying Ma; Min Liu; Jing-Tao Wang; Bin Zhu; Yi-Fan Li

doi:10.1007/s10118-021-2521-3

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Enhanced Gas Separation Performance by Embedding Submicron Poly(ethylene glycol) Capsules into Polyetherimide Membrane

ARTICLE | Updated：2020-11-12

- Enhanced Gas Separation Performance by Embedding Submicron Poly(ethylene glycol) Capsules into Polyetherimide Membrane
- Enhanced Gas Separation Performance by Embedding Submicron Poly(ethylene glycol) Capsules into Polyetherimide Membrane
- Chinese Journal of Polymer Science 2021年39卷第3期页码：355-364
- Affiliations：
  
  a.School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China
  b.College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
- Author bio：
  
  yf_li@zzu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 21878277), Natural Science Foundation of Henan province (No. 182300410268), China Postdoctoral Science Foundation (No. 2017T100538), and Outstanding Young Talent Research Fund of Zhengzhou University (No. 1521324002). In addition, we would like to express our gratitude for the instrument support received from Center of Advanced Analysis & Computational Science, Zhengzhou University.
- DOI：10.1007/s10118-021-2521-3
  中图分类号：
- 收稿：2020-05-06，
  
  修回：2020-10-8，
  
  录用：2020-10-21，
  
  网络首发：2020-11-12，
  
  纸质出版：2021-01-02
- Accepted：
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Ma, Y. Y.; Liu, M.; Wang, J. T.; Zhu, B.; Li, Y. F. Enhanced gas separation performance by embedding submicron poly(ethylene glycol) capsules into polyetherimide membrane. Chinese J. Polym. Sci. 2021, 39, 355–364

Ying-Ying Ma, Min Liu, Jing-Tao Wang, et al. Enhanced Gas Separation Performance by Embedding Submicron Poly(ethylene glycol) Capsules into Polyetherimide Membrane[J]. Chinese Journal of Polymer Science, 2021, 39(3): 355-364.
Ma, Y. Y.; Liu, M.; Wang, J. T.; Zhu, B.; Li, Y. F. Enhanced gas separation performance by embedding submicron poly(ethylene glycol) capsules into polyetherimide membrane. Chinese J. Polym. Sci. 2021, 39, 355–364 DOI： 10.1007/s10118-021-2521-3.

Ying-Ying Ma, Min Liu, Jing-Tao Wang, et al. Enhanced Gas Separation Performance by Embedding Submicron Poly(ethylene glycol) Capsules into Polyetherimide Membrane[J]. Chinese Journal of Polymer Science, 2021, 39(3): 355-364. DOI： 10.1007/s10118-021-2521-3.

摘要

Abstract

Recently

hollow filler as an emerging concept is attracting more attention in preparation of mixed matrix membranes (MMMs). Herein

poly(ethylene glycol) microcapsules (PMC) are synthesized

via

distillation precipitation polymerization and embedded into the polyetherimide (Ultem

1000) matrix to fabricate MMMs for CO

capture. The PMC exhibits a preferential hollow structure within the Ultem matrix to furnish highways within membrane

and thus achieve high gas permeability. Meanwhile

the favorable affinity of poly(ethylene glycol) (PEG) microcapsule with ether oxygen group (EO) towards CO

enhances the CO

solubility selectivity. Such integration of physical and chemical microenvironments in the as-designed PEG microcapsule affords highly enhanced CO

separation performance. Compared to pristine Ultem

1000

the membrane with 2.5 wt% PMC loading exhibits 310% increment in CO

permeability and 22% increment in CO

selectivity

which shows the promising prospects of designing PEG-containing microcapsules as the filler of MMMs for CO

capture.

关键词

Keywords

references

Du, N.; Park, H. B.; Dal-Cin, M. M.; Guiver, M. D. . Advances in high permeability polymeric membrane materials for CO 2 separations . Energy Environ. Sci. , 2012 . 5 7306 - 7322 . DOI: 10.1039/C1EE02668B http://doi.org/10.1039/C1EE02668B .

Sanders, D. F.; Smith, Z. P.; Guo, R.; Robeson, L. M.; McGrath, J. E.; Paul, D. R.; Freeman, B. D. . Energy-efficient polymeric gas separation membranes for a sustainable future: a review . Polymer , 2013 . 54 4729 - 4761 . DOI: 10.1016/j.polymer.2013.05.075 http://doi.org/10.1016/j.polymer.2013.05.075 .

D'Alessandro, D. M.; Smit, B.; Long, J. R. . Carbon dioxide capture: prospects for new materials . Angew. Chem. Int. Ed. , 2010 . 49 6058 - 6082 . DOI: 10.1002/anie.201000431 http://doi.org/10.1002/anie.201000431 .

Vu, D. Q.; Koros, W. J.; Miller, S. J. . Mixed matrix membranes using carbon molecular sieves-I Preparation and experimental results . J. Membr. Sci. , 2003 . 211 311 - 334 . .

Jamil, A.; Oh, P. C.; Shariff, A. F. . Polyetherimide-montmorillonite mixed matrix hollow fibre membranes: effect of inorganic/ organic montmorillonite on the CO 2 /CH 4 separation . Sep. Purif. Technol. , 2018 . 206 256 - 267 . DOI: 10.1016/j.seppur.2018.05.054 http://doi.org/10.1016/j.seppur.2018.05.054 .

Jeong, M. K.; Park, J. H.; Nam, S. Y. . Fabrication of PEG-polyimide copolymer hollow fiber membranes for gas separation . J. Nanosci. Nanotechnol. , 2017 . 17 7490 - 7496 . DOI: 10.1166/jnn.2017.14787 http://doi.org/10.1166/jnn.2017.14787 .

Yong, W. F.; Li, F. Y.; Xiao, Y. C.; Chung, T. S.; Tong, Y. W. . High performance PIM-1/Matrimid hollow fiber membranes for CO 2 /CH 4 , O 2 /N 2 and CO 2 /N 2 separation . J. Membr. Sci. , 2013 . 443 156 - 169 . DOI: 10.1016/j.memsci.2013.04.037 http://doi.org/10.1016/j.memsci.2013.04.037 .

Dong, G. X.; Li, H. Y.; Chen, V. . Factors affect defect-free Matrimid (R) hollow fiber gas separation performance in natural gas purification . J. Membr. Sci. , 2010 . 353 17 - 27 . DOI: 10.1016/j.memsci.2010.02.012 http://doi.org/10.1016/j.memsci.2010.02.012 .

Park, H. B.; Jung, C. H.; Lee, Y. M.; Hill, A. J.; Pas, S. J.; Mudie, S. T.; van Wagner, E.; Freeman, B. D.; Cookson, D. J. . Polymers with cavities tuned for fast selective transport of small molecules and ions . Science , 2007 . 318 254 - 258 . DOI: 10.1126/science.1146744 http://doi.org/10.1126/science.1146744 .

Zhang, C.; Liu, B.; Wang, G.; Yu, G.; Zou, X.; Zhu, G. . Small-pore CAU-21 and porous PIM-1 in mixed-matrix membranes for improving selectivity and permeability in hydrogen separation . Chem. Commun. , 2019 . 55 7101 - 7104 . DOI: 10.1039/C9CC02537E http://doi.org/10.1039/C9CC02537E .

Yeong, Y. F.; Khoo, T. S. . Fabrication of amino-functionalized CAU-1/cellulose acetate mixed matrix membranes for CO 2 /N 2 separation . Key Eng. Mater. , 2019 . 797 39 - 47 . DOI: 10.4028/www.scientific.net/KEM.797.39 http://doi.org/10.4028/www.scientific.net/KEM.797.39 .

Hossain, I.; Nam, S. Y.; Rizzuto, C.; Barbieri, G.; Tocci, E.; Kim, T. H. . PIM-polyimide multiblock copolymer-based membranes with enhanced CO 2 separation performances . J. Membr. Sci. , 2019 . 574 270 - 281 . DOI: 10.1016/j.memsci.2018.12.084 http://doi.org/10.1016/j.memsci.2018.12.084 .

Bernabe, D. P.; Caparanga, A. R.; Hu, C. C.; You, S. J.; Lee, K. R.; Lai, J. Y. . MOF-modified high permeability polyimide membrane for gas separation . Key Eng. Mater. , 2019 . 801 313 - 318 . DOI: 10.4028/www.scientific.net/KEM.801.313 http://doi.org/10.4028/www.scientific.net/KEM.801.313 .

Swaidan, R.; Ghanem, B. S.; Litwiller, E.; Pinnau, I. . Pure- and mixed-gas CO 2 /CH 4 separation properties of PIM-1 and an amidoxime-functionalized PIM-1 . J. Membr. Sci. , 2014 . 457 95 - 102 . DOI: 10.1016/j.memsci.2014.01.055 http://doi.org/10.1016/j.memsci.2014.01.055 .

Guan, W.; Dai, Y.; Dong, C.; Yang, X.; Xi, Y. . Zeolite imidazolate framework (ZIF)-based mixed matrix membranes for CO 2 separation: a review . J. Appl. Polym. Sci. , 2020 . 48968 .

Sabetghadam, A.; Liu, X.; Benzaqui, M.; Gkaniatsou, E.; Orsi, A.; Lozinska, M. M.; Sicard, C.; Johnson, T.; Steunou, N.; Wright, P. A.; Serre, C.; Gascon, J.; Kapteijn, F. . Influence of filler pore structure and polymer on the performance of MOF-based mixed-matrix membranes for CO 2 capture . Chem. Eur. J. , 2018 . 24 7949 - 7956 . DOI: 10.1002/chem.201800253 http://doi.org/10.1002/chem.201800253 .

Yu, G. L.; Wang, Z. Y.; Liu, X. T.; Zhu, G. S.; Zou, X. Q. . Mixed matrix membranes derived from nanoscale porous organic frameworks for permeable and selective CO 2 separation . J. Membr. Sci. , 2019 . 591 117343 DOI: 10.1016/j.memsci.2019.117343 http://doi.org/10.1016/j.memsci.2019.117343 .

Ishaq, S.; Tamime, R.; Bilad, M. R.; Khan, A. L. . Mixed matrix membranes comprising of polysulfone and microporous Bio-MOF-1: preparation and gas separation properties . Sep. Purif. Technol. , 2019 . 210 442 - 451 . DOI: 10.1016/j.seppur.2018.08.031 http://doi.org/10.1016/j.seppur.2018.08.031 .

Dong, G.; Zhang, J.; Wang, Z.; Wang, J.; Zhao, P.; Cao, X.; Zhang, Y. . Interfacial property modulation of PIM-1 through polydopamine-derived submicrospheres for enhanced CO 2 /N 2 separation performance . ACS Appl. Mater. Interfaces , 2019 . 11 19613 - 19622 . DOI: 10.1021/acsami.9b02281 http://doi.org/10.1021/acsami.9b02281 .

Ding, X.; Tan, F.; Zhao, H.; Hua, M.; Wang, M.; Xin, Q.; Zhang, Y. . Enhancing gas permeation and separation performance of polymeric membrane by incorporating hollow polyamide nanoparticles with dense shell . J. Membr. Sci. , 2019 . 570-571 53 - 60 . DOI: 10.1016/j.memsci.2018.10.033 http://doi.org/10.1016/j.memsci.2018.10.033 .

Lee, J. H.; Kwon, H. T.; Bae, S.; Kim, J.; Kim, J. H. . Mixed-matrix membranes containing nanocage-like hollow ZIF-8 polyhedral nanocrystals in graft copolymers for carbon dioxide/methane separation . Sep. Purif. Technol. , 2018 . 207 427 - 434 . DOI: 10.1016/j.seppur.2018.06.076 http://doi.org/10.1016/j.seppur.2018.06.076 .

Zhu, B.; Liu, J.; Wang, S.; Wang, J.; Liu, M.; Yan, Z.; Shi, F.; Li, J.; Li, Y. . Mixed matrix membranes containing well-designed composite microcapsules for CO 2 separation . J. Membr. Sci. , 2019 . 572 650 - 657 . DOI: 10.1016/j.memsci.2018.11.039 http://doi.org/10.1016/j.memsci.2018.11.039 .

Xiao, Y. C.; Low, B. T.; Hosseini, S. S.; Chung, T. S.; Paul, D. R. . The strategies of molecular architecture and modification of polyimide-based membranes for CO 2 removal from natural gas-a review . Prog. Polym. Sci. , 2009 . 34 561 - 580 . DOI: 10.1016/j.progpolymsci.2008.12.004 http://doi.org/10.1016/j.progpolymsci.2008.12.004 .

G. Castruita-de León, Yeverino-Miranda, C. Y.; Montes-Luna, A. D. J.; Meléndez-Ortiz, H. I.; Alvarado-Tenorio, G.; García-Cerda, L. A. . Amine-impregnated natural zeolite as filler in mixed matrix membranes for CO 2 /CH 4 separation . J. Appl. Polym. Sci. , 2019 . 137 48286 .

Ma, C.; Urban, J. J. . Enhanced CO 2 capture and hydrogen purification by hydroxy metal-organic framework/polyimide mixed matrix membranes . ChemSusChem , 2019 . 12 4405 - 4411 . DOI: 10.1002/cssc.201902248 http://doi.org/10.1002/cssc.201902248 .

Wang, S. F.; Feng, J. Y.; Wu, H.; Li, Y. F.; Liu, Y.; Li, X. Q.; Xin, Q. P.; Jiang, Z. Y. . Enhanced CO 2 separation properties by incorporating poly(ethylene glycol)-containing polymeric submicrospheres into polyimide membrane . J. Membr. Sci. , 2015 . 473 310 - 317 . DOI: 10.1016/j.memsci.2014.09.035 http://doi.org/10.1016/j.memsci.2014.09.035 .

Zhang, H.; Guo, R.; Zhang, J.; Li, X. . Facilitating CO 2 transport across mixed matrix membranes containing multifunctional nanocapsules . ACS Appl. Mater. Interfaces , 2018 . 10 43031 - 43039 . DOI: 10.1021/acsami.8b15269 http://doi.org/10.1021/acsami.8b15269 .

Zornoza, B.; Esekhile, O.; Koros, W. J.; Téllez, C.; Coronas, J. . Hollow silicalite-1 sphere-polymer mixed matrix membranes for gas separation . Sep. Purif. Technol. , 2011 . 77 137 - 145 . DOI: 10.1016/j.seppur.2010.11.033 http://doi.org/10.1016/j.seppur.2010.11.033 .

Hou, J.; Li, X.; Guo, R.; Zhang, J.; Wang, Z. . Mixed matrix membranes with fast and selective transport pathways for efficient CO 2 separation . Nanotechnology , 2018 . 29 125706 DOI: 10.1088/1361-6528/aaa80c http://doi.org/10.1088/1361-6528/aaa80c .

Hwang, S.; Chi, W. S.; Lee, S. J.; Im, S. H.; Kim, J. H.; Kim, J. . Hollow ZIF-8 nanoparticles improve the permeability of mixed matrix membranes for CO 2 /CH 4 gas separation . J. Membr. Sci. , 2015 . 480 11 - 19 . DOI: 10.1016/j.memsci.2015.01.038 http://doi.org/10.1016/j.memsci.2015.01.038 .

Ghanem, A. S.; Ba-Shammakh, M.; Usman, M.; Khan, M. F.; Dafallah, H.; Habib, M. A. M.; Al-Maythalony, B. A. . High gas permselectivity in ZIF-302/polyimide self-consistent mixed-matrix membrane . J. Appl. Polym. Sci. , 2019 . 137 48513 .

Aguilar-Lugo, C.; Suárez-García, F.; Hernández, A.; Miguel, J. A.; Lozano, Á. E.; de la Campa, J. G.; Álvarez, C. . New materials for gas separation applications: mixed matrix membranes made from linear polyimides and porous polymer networks having lactam groups . Ind. Eng. Chem. Res. , 2019 . 58 9585 - 9595 . DOI: 10.1021/acs.iecr.9b01402 http://doi.org/10.1021/acs.iecr.9b01402 .

Zhu, H.; Jie, X.; Wang, L.; Kang, G.; Liu, D.; Cao, Y. . Enhanced gas separation performance of mixed matrix hollow fiber membranes containing post-functionalized S-MIL-53 . J. Energy Chem. , 2018 . 27 781 - 790 . DOI: 10.1016/j.jechem.2017.04.016 http://doi.org/10.1016/j.jechem.2017.04.016 .

Kang, Z.; Peng, Y.; Qian, Y.; Yuan, D.; Addicoat, M. A.; Heine, T.; Hu, Z.; Tee, L.; Guo, Z.; Zhao, D. . Mixed matrix membranes (MMMs) comprising exfoliated 2D covalent organic frameworks (COFs) for efficient CO 2 separation . Chem. Mat. , 2016 . 28 1277 - 1285 . DOI: 10.1021/acs.chemmater.5b02902 http://doi.org/10.1021/acs.chemmater.5b02902 .

Werner Stober, A. F. . Controlled growth of monodisperse silica spheres in the micron size range . J. Colloid Interface Sci. , 1968 . 26 62 - 69 . DOI: 10.1016/0021-9797(68)90272-5 http://doi.org/10.1016/0021-9797(68)90272-5 .

Bai, F.; Yang, X.; Huang, W. . Synthesis of narrow or monodisperse poly(divinylbenzene) microspheres by distillation-precipitation polymerization . Macromolecules , 2004 . 37 9746 - 9752 . DOI: 10.1021/ma048566l http://doi.org/10.1021/ma048566l .

Tin, P. . Effects of cross-linking modification on gas separation performance of matrimid membranes . J. Membr. Sci. , 2003 . 225 77 - 90 . DOI: 10.1016/j.memsci.2003.08.005 http://doi.org/10.1016/j.memsci.2003.08.005 .

Ahmad, J.; Hägg, M. B. . Development of matrimid/zeolite 4A mixed matrix membranes using low boiling point solvent . Sep. Purif. Technol. , 2013 . 115 190 - 197 . DOI: 10.1016/j.seppur.2013.04.049 http://doi.org/10.1016/j.seppur.2013.04.049 .

Aziz, F.; Ismail, A. F. . Preparation and characterization of cross-linked Matrimid® membranes using para -phenylenediamine for O 2 /N 2 separation . Sep. Purif. Technol. , 2010 . 73 421 - 428 . DOI: 10.1016/j.seppur.2010.05.002 http://doi.org/10.1016/j.seppur.2010.05.002 .

Wang, S. F.; Liu, Y.; Huang, S. X.; Wu, H.; Li, Y. F.; Tian, Z. Z.; Jiang, Z. Y. . Pebax-PEG-MWCNT hybrid membranes with enhanced CO 2 capture properties . J. Membr. Sci. , 2014 . 460 62 - 70 . DOI: 10.1016/j.memsci.2014.02.036 http://doi.org/10.1016/j.memsci.2014.02.036 .

Vanherck, K.; Aerts, A.; Martens, J. Vankelecom, I. . Hollow filler based mixed matrix membranes . Chem. Commun. , 2010 . 46 2492 - 2494 . DOI: 10.1039/b924086a http://doi.org/10.1039/b924086a .

Peng, F. B.; Sun, H. L; Wang, Y. Q.; Liu, J. Q.; Jiang, Z. Y. . Hybrid organic-inorganic membrane: solving the tradeoff between permeability and selectivity . Chem. Mater. , 2015 . 17 6790 - 6796 . .

Lin, H.; Freeman, B. D. . Materials selection guidelines for membranes that remove CO 2 from gas mixtures . J. Mol. Struct. , 2005 . 739 57 - 74 . DOI: 10.1016/j.molstruc.2004.07.045 http://doi.org/10.1016/j.molstruc.2004.07.045 .

Dai, Y.; Karvan, Sholl, S.; Koros, W. J. . Ultem ® ZIF-8 mixed matrix hollow fiber membranes for CO 2 /N 2 separations . J. Membr. Sci. , 2012 . 401−402 76 - 82 . DOI: 10.1016/j.memsci.2012.01.044 http://doi.org/10.1016/j.memsci.2012.01.044 .

Bae, T. H.; Lee, J. S.; Qiu, W. L.; Koros, W. J.; Jones, C. W.; Nair, S. . A high-performance gas-separation membrane containing submicrometer-sized metal-organic framework crystals . Angew. Chem. Int. Ed. , 2010 . 49 9863 - 9866 . DOI: 10.1002/anie.201006141 http://doi.org/10.1002/anie.201006141 .

Mubashir, M.; Yeong, Y. F.; Lau, K. K.; Chew, T. L.; Norwahyu, J. . Efficient CO 2 /N 2 and CO 2 /CH 4 separation using NH 2 -MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes . Sep. Purif. Technol. , 2018 . 199 140 - 151 . DOI: 10.1016/j.seppur.2018.01.038 http://doi.org/10.1016/j.seppur.2018.01.038 .

Hao, L.; Li, P.; Chung, T. S. . PIM-1 as an organic filler to enhance the gas separation performance of Ultem polyetherimide . J. Membr. Sci. , 2014 . 453 614 - 623 . DOI: 10.1016/j.memsci.2013.11.045 http://doi.org/10.1016/j.memsci.2013.11.045 .

Ismail, A. F.; Hashemifard, S. A.; Matsuura, T. . Facilitated transport effect of Ag + ion exchanged halloysite nanotubes on the performance of polyetherimide mixed matrix membrane for gas separation . J. Membr. Sci. , 2011 . 379 378 - 385 . DOI: 10.1016/j.memsci.2011.06.010 http://doi.org/10.1016/j.memsci.2011.06.010 .

Husain, S.; Koros, W. J. . Mixed matrix hollow fiber membranes made with modified HSSZ-13 zeolite in polyetherimide polymer matrix for gas separation . J. Membr. Sci. , 2007 . 288 195 - 207 . DOI: 10.1016/j.memsci.2006.11.016 http://doi.org/10.1016/j.memsci.2006.11.016 .

Koolivand, H.; Sharif, A.; Kashani, M. R.; Karimi, M.; Salooki, M. K.; Semsarzadeh, M. A. . Functionalized graphene oxide/polyimide nanocomposites as highly CO 2 -selective membranes . J. Polym. Res. , 2014 . 21 599 DOI: 10.1007/s10965-014-0599-9 http://doi.org/10.1007/s10965-014-0599-9 .

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