Tough Double Metal-ion Cross-linked Elastomers with Temperature-adaptable Self-healing and Luminescence Properties

Qi-Yan Yin; Cheng-Hao Dai; Huan Chen; Kai Gou; Hong-Zhou Guan; Peng-Han Wang; Jing-Tao Jiang; Geng-Sheng Weng

doi:10.1007/s10118-021-2517-z

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Tough Double Metal-ion Cross-linked Elastomers with Temperature-adaptable Self-healing and Luminescence Properties

ARTICLE | Updated：2020-11-05

- Tough Double Metal-ion Cross-linked Elastomers with Temperature-adaptable Self-healing and Luminescence Properties
- Tough Double Metal-ion Cross-linked Elastomers with Temperature-adaptable Self-healing and Luminescence Properties
- Chinese Journal of Polymer Science 2021年39卷第5期页码：554-565
- Affiliations：
  
  a.School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
  b.Ningbo Key Laboratory of Specialty Polymers, State Key Laboratory Base of Novel Functional Materials and Preparation Science, Ningbo University, Ningbo 315211, China
- Author bio：
  
  wenggengsheng@nbu.edu.cn
- Funds：
  
  G.W. is grateful for the financial support of Natural Science Foundation of Zhejiang Province (No. LY19E030002), Ningbo Municipal Science and Technology Bureau (No. 2019A610133) and K. C. Wong Magna Fund in Ningbo University.
- DOI：10.1007/s10118-021-2517-z
  中图分类号：
- 收稿：2020-08-13，
  
  修回：2020-9-14，
  
  录用：2020-10-8，
  
  网络首发：2020-11-05，
  
  纸质出版：2021-01-01
- Accepted：
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Yin, Q. Y.; Dai, C. H.; Chen, H.; Gou, K.; Guan, H. Z.; Wang, P. H.; Jiang, J. T.; Weng, G. S. Tough double metal-ion cross-linked elastomers with temperature-adaptable self-healing and luminescence properties. Chinese J. Polym. Sci. 2021, 39, 554–565

Qi-Yan Yin, Cheng-Hao Dai, Huan Chen, et al. Tough Double Metal-ion Cross-linked Elastomers with Temperature-adaptable Self-healing and Luminescence Properties[J]. Chinese Journal of Polymer Science, 2021, 39(5): 554-565.
Yin, Q. Y.; Dai, C. H.; Chen, H.; Gou, K.; Guan, H. Z.; Wang, P. H.; Jiang, J. T.; Weng, G. S. Tough double metal-ion cross-linked elastomers with temperature-adaptable self-healing and luminescence properties. Chinese J. Polym. Sci. 2021, 39, 554–565 DOI： 10.1007/s10118-021-2517-z.

Qi-Yan Yin, Cheng-Hao Dai, Huan Chen, et al. Tough Double Metal-ion Cross-linked Elastomers with Temperature-adaptable Self-healing and Luminescence Properties[J]. Chinese Journal of Polymer Science, 2021, 39(5): 554-565. DOI： 10.1007/s10118-021-2517-z.

摘要

Abstract

Smart materials with a combination of tough solid-like properties

fast self-healing and optical responsiveness are of interests for the development of new soft machines and wearable electronics. In this work

tough physically cross-linked elastomers that show high mechanical strength

intriguing temperature-adaptable self-healing and fluorochromic response properties are designed using aluminum (Al) and fluorescent europium (Eu) ions as cross-linkers. The ionic Al-COOH binding is incorporated to construct the strong polymer network which mainly contributes to the mechanical robustness of the elastomer consisting of two interpenetrated networks. The Eu-iminodiacetate (IDA) coordination is mainly used to build the weaker but more dynamic network which dominate the elasticity

self-healing and luminescence of the elastomer. Moderate Eu

and Al

contents give these supramolecular elastomers high toughness. The temperature-sensitive Eu-IDA coordination enables tunable self-healing rate and efficiency along with fast Eu-centered “ON/OFF” switchable red emission. The mechanical

self-healing and luminescence properties of these elastomers can be adjusted by tuning the ratio of the two types of metal ions. This elastomer is potentially applicable for biosensors

wearable optoelectronics and anticounterfeiting materials.

关键词

Keywords

references

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