A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly

Wen-Zhang Fang; Li Peng; Ying-Jun Liu; Fang Wang; Zhen Xu; Chao Gao

doi:10.1007/s10118-021-2515-1

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A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly

REVIEW | Updated：2020-11-26

- A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly
- A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly
- Chinese Journal of Polymer Science 2021年39卷第3期页码：267-308
- Affiliations：
  
  Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  Chao Gao received his Ph.D. degree from Shanghai Jiao Tong University (SJTU) in 2001. He was appointed as an Associate Professor at SJTU in 2002. He did postdoctoral research at the University of Sussex with Prof. Sir Harry Kroto and AvH research at the Bayreuth University with Prof. Axel H. E. Müller. He joined the Department of Polymer Science and Engineering, Zhejiang University, in 2008 and was promoted as a Qiushi Distinguished Professor in 2014. He leads a Nanopolymer group working on graphene chemistry, macroscopic assembly, and energy storage
- Funds：
  
  This work was financially supported by the National Key R&D Program of China (No. 2016YFA0200200), the National Natural Science Foundation of China (Nos. 51533008, 51703194, 51873191, and 21805242), Hundred Talents Program of Zhejiang University (No. 188020*194231701/113), Key Research and Development Plan of Zhejiang Province (No. 2018C01049), Fujian Provincial Science and Technology Major Projects (No. 2018HZ0001-2), and Key Laboratory of Novel Adsorption and Separation Materials and Application Technology of Zhejiang Province (No. 512301-I21502).
- DOI：10.1007/s10118-021-2515-1
  中图分类号：
- 收稿：2020-08-28，
  
  修回：2020-9-29，
  
  录用：2020-10-5，
  
  网络首发：2020-11-26，
  
  纸质出版：2021-01-02
- Accepted：
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Fang, W. Z.; Peng, L.; Liu, Y. J.; Wang, F.; Xu, Z.; Gao, C. A review on graphene oxide two-dimensional macromolecules: from single molecules to macro-assembly. Chinese J. Polym. Sci. 2021, 39, 267–308

Wen-Zhang Fang, Li Peng, Ying-Jun Liu, et al. A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly[J]. Chinese Journal of Polymer Science, 2021, 39(3): 267-308.
Fang, W. Z.; Peng, L.; Liu, Y. J.; Wang, F.; Xu, Z.; Gao, C. A review on graphene oxide two-dimensional macromolecules: from single molecules to macro-assembly. Chinese J. Polym. Sci. 2021, 39, 267–308 DOI： 10.1007/s10118-021-2515-1.

Wen-Zhang Fang, Li Peng, Ying-Jun Liu, et al. A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly[J]. Chinese Journal of Polymer Science, 2021, 39(3): 267-308. DOI： 10.1007/s10118-021-2515-1.

摘要

Abstract

Graphene oxide (GO)

which consists of two-dimensional (2D) sp

carbon hexagonal networks and oxygen-contained functional groups

has laid the foundation of mass production and applications of graphene materials. Made by chemical oxidation of graphite

GO is highly dispersible or even solubilized in water and polar organic solvents

which resolves the hard problem of graphene processing and opens a door to wet-processing of graphene. Despite its defects

GO is easy to functionalize

dope

punch holes

cut into pieces

conduct chemical reduction

form lyotropic liquid crystal

and assemble into macroscopic materials with tunable structures and properties as a living building block. GO sheet has been viewed as a single molecule

a particle

as well as a soft polymer material. An overview on GO as a 2D macromolecule is essential for studying its intrinsic properties and guiding the development of relevant subjects. This review mainly focuses on recent advances of GO sheets

from single macromolecular behavior to macro-assembled graphene material properties. The first part of this review offers a brief introduction to the synthesis of GO molecules. Then the chemical structure and physical properties of GO are presented

as well as its polarity in solvent and rheology behavior. Several key parameters governing the ultimate stability of GO colloidal behavior

including size

pH and the presence of cation in aqueous dispersions

are highlighted. Furthermore

the discovery of GO liquid crystal and functionalization of GO molecules have built solid new foundations of preparing highly ordered

architecture-tunable

macro-assembled graphene materials

including 1D graphene fibers

2D graphene films

and 3D graphene architectures. The GO-based composites are also viewed and the interactions between these target materials and GO are carefully discussed. Finally

an outlook is provided in this field

where GO is regarded as macromolecules

pointing out the challenges and opportunities that exist in the field. We hope that this review will be beneficial to the understanding of GO in terms of chemical structure

molecular properties

macro-assembly and potential applications

and encourage further development to extend its investigations from basic research to practical applications.

关键词

Keywords

references

Xu, Z.; Gao, C. . Graphene in macroscopic order: liquid crystals and wet-spun fibers . Acc. Chem. Res. , 2014 . 47 1267 - 1276 . DOI: 10.1021/ar4002813 http://doi.org/10.1021/ar4002813 .

Dai, L. . Functionalization of graphene for efficient energy conversion and storage . Acc. Chem. Res. , 2013 . 46 31 - 42 . DOI: 10.1021/ar300122m http://doi.org/10.1021/ar300122m .

Radha, B.; Esfandiar, A.; Wang, F. C.; Rooney, A. P.; Gopinadhan, K.; Keerthi, A.; Mishchenko, A.; Janardanan, A.; Blake, P.; Fumagalli, L.; Lozada-Hidalgo, M.; Garaj, S.; Haigh, S. J.; Grigorieva, I. V.; Wu, H. A.; Geim, A. K. . Molecular transport through capillaries made with atomic-scale precision . Nature , 2016 . 538 222 - 225 . DOI: 10.1038/nature19363 http://doi.org/10.1038/nature19363 .

Lozada-Hidalgo, M.; Zhang, S.; Hu, S.; Kravets, V. G.; Rodriguez, F. J.; Berdyugin, A.; Grigorenko, A.; Geim, A. K. . Giant photoeffect in proton transport through graphene membranes . Nat. Nanotechnol. , 2018 . 13 300 - 303 . DOI: 10.1038/s41565-017-0051-5 http://doi.org/10.1038/s41565-017-0051-5 .

Nedoliuk, I. O.; Hu, S.; Geim, A. K.; Kuzmenko, A. B. . Colossal infrared and terahertz magneto-optical activity in a two-dimensional Dirac material . Nat. Nanotechnol. , 2019 . 14 756 - 761 . DOI: 10.1038/s41565-019-0489-8 http://doi.org/10.1038/s41565-019-0489-8 .

Geim, A. K.; Novoselov, K. S. . The rise of graphene . Nat. Mater. , 2007 . 6 183 - 191 . DOI: 10.1038/nmat1849 http://doi.org/10.1038/nmat1849 .

Khan, M. B.; Parvaz, M.; Khan, Z. H., Graphene oxide: synthesis and characterization. In Recent trends in nanomaterials: synthesis and properties . Khan, Z. H. Ed., Springer Singapore, Singapore, 2017 , pp. 1−28.

Hummers, W. S.; Offeman, R. E. . Preparation of graphitic oxide . J. Am. Chem. Soc. , 1958 . 80 1339 - 1339 . DOI: 10.1021/ja01539a017 http://doi.org/10.1021/ja01539a017 .

Xu, Z.; Gao, C. . Aqueous liquid crystals of graphene oxide . ACS Nano , 2011 . 5 2908 - 2915 . DOI: 10.1021/nn200069w http://doi.org/10.1021/nn200069w .

Kim, J. E.; Han, T. H.; Lee, S. H.; Kim, J. Y.; Ahn, C. W.; Yun, J. M.; Kim, S. O. . Graphene oxide liquid crystals . Angew. Chem. Int. Ed. , 2011 . 50 3043 - 3047 . DOI: 10.1002/anie.201004692 http://doi.org/10.1002/anie.201004692 .

McAllister, M. J.; Li, J. L.; Adamson, D. H.; Schniepp, H. C.; Abdala, A. A.; Liu, J.; Herrera-Alonso, M.; Milius, D. L.; Car, R.; Prud'homme, R. K.; Aksay, I. A. . Single sheet functionalized graphene by oxidation and thermal expansion of graphite . Chem. Mater. , 2007 . 19 4396 - 4404 . DOI: 10.1021/cm0630800 http://doi.org/10.1021/cm0630800 .

Brodie, B. C. . XXIII. Researches on the atomic weight of graphite . Q. J. Chem. Soc. , 1860 . 12 261 - 268 . DOI: 10.1039/QJ8601200261 http://doi.org/10.1039/QJ8601200261 .

Staudenmaier, L. . Verfahren zur darstellung der graphitsäure . Ber. Dtsch. Chem. Ges. , 1898 . 31 1481 - 1487 . DOI: 10.1002/cber.18980310237 http://doi.org/10.1002/cber.18980310237 .

Chen, J.; Yao, B.; Li, C.; Shi, G. . An improved Hummers method for eco-friendly synthesis of graphene oxide . Carbon , 2013 . 64 225 - 229 . DOI: 10.1016/j.carbon.2013.07.055 http://doi.org/10.1016/j.carbon.2013.07.055 .

Shen, J.; Hu, Y.; Shi, M.; Lu, X.; Qin, C.; Li, C.; Ye, M. . Fast and facile preparation of graphene oxide and reduced graphene oxide nanoplatelets . Chem. Mater. , 2009 . 21 3514 - 3520 . DOI: 10.1021/cm901247t http://doi.org/10.1021/cm901247t .

Chen, J.; Li, Y.; Huang, L.; Li, C.; Shi, G. . High-yield preparation of graphene oxide from small graphite flakes via an improved Hummers method with a simple purification process . Carbon , 2015 . 81 826 - 834 . DOI: 10.1016/j.carbon.2014.10.033 http://doi.org/10.1016/j.carbon.2014.10.033 .

Abdelkader, A. M.; Kinloch, I. A.; Dryfe, R. A. W. . High-yield electro-oxidative preparation of graphene oxide . Chem. Commun. , 2014 . 50 8402 - 8404 . DOI: 10.1039/C4CC03260H http://doi.org/10.1039/C4CC03260H .

Huang, H.; Peng, L.; Fang, W.; Cai, S.; Chu, X.; Liu, Y.; Gao, W.; Xu, Z.; Gao, C. . A polyimide-pyrolyzed carbon waste approach for the scalable and controlled electrochemical preparation of size-tunable graphene . Nanoscale , 2020 . 12 11971 - 11978 . DOI: 10.1039/D0NR00725K http://doi.org/10.1039/D0NR00725K .

Posudievsky, O. Y.; Khazieieva, O. A.; Koshechko, V. G.; Pokhodenko, V. D. . Preparation of graphene oxide by solvent-free mechanochemical oxidation of graphite . J. Mater. Chem. , 2012 . 22 12465 - 12467 . DOI: 10.1039/c2jm16073k http://doi.org/10.1039/c2jm16073k .

Dash, P.; Dash, T.; Rout, T. K.; Sahu, A. K.; Biswal, S. K.; Mishra, B. K. . Preparation of graphene oxide by dry planetary ball milling process from natural graphite . RSC Adv. , 2016 . 6 12657 - 12668 . DOI: 10.1039/C5RA26491J http://doi.org/10.1039/C5RA26491J .

Xu, Z.; Sun, H.; Zhao, X.; Gao, C. . Ultrastrong fibers assembled from giant graphene oxide sheets . Adv. Mater. , 2013 . 25 188 - 193 . DOI: 10.1002/adma.201203448 http://doi.org/10.1002/adma.201203448 .

Liu, Z.; Robinson, J. T.; Sun, X.; Dai, H. . Pegylated nanographene oxide for delivery of water-insoluble cancer drugs . J. Am. Chem. Soc. , 2008 . 130 10876 - 10877 . DOI: 10.1021/ja803688x http://doi.org/10.1021/ja803688x .

Wang, X.; Bai, H.; Shi, G. . Size fractionation of graphene oxide sheets by pH-assisted selective sedimentation . J. Am. Chem. Soc. , 2011 . 133 6338 - 6342 . DOI: 10.1021/ja200218y http://doi.org/10.1021/ja200218y .

Zhao, J.; Pei, S.; Ren, W.; Gao, L.; Cheng, H. M. . Efficient preparation of large-area graphene oxide sheets for transparent conductive films . ACS Nano , 2010 . 4 5245 - 5252 . DOI: 10.1021/nn1015506 http://doi.org/10.1021/nn1015506 .

Pan, S.; Aksay, I. A. . Factors controlling the size of graphene oxide sheets produced via the graphite oxide route . ACS Nano , 2011 . 5 4073 - 4083 . DOI: 10.1021/nn200666r http://doi.org/10.1021/nn200666r .

Li, J. L.; Kudin, K. N.; McAllister, M. J.; Prud’homme, R. K.; Aksay, I. A.; Car, R. . Oxygen-driven unzipping of graphitic materials . Phys. Rev. Lett. , 2006 . 96 176101 DOI: 10.1103/PhysRevLett.96.176101 http://doi.org/10.1103/PhysRevLett.96.176101 .

Dong, L.; Chen, Z.; Lin, S.; Wang, K.; Ma, C.; Lu, H. . Reactivity-controlled preparation of ultralarge graphene oxide by chemical expansion of graphite . Chem. Mater. , 2017 . 29 564 - 572 . DOI: 10.1021/acs.chemmater.6b03748 http://doi.org/10.1021/acs.chemmater.6b03748 .

Su, C. Y.; Xu, Y.; Zhang, W.; Zhao, J.; Tang, X.; Tsai, C. H.; Li, L. J. . Electrical and spectroscopic characterizations of ultra-large reduced graphene oxide monolayers . Chem. Mater. , 2009 . 21 5674 - 5680 . DOI: 10.1021/cm902182y http://doi.org/10.1021/cm902182y .

Qi, X.; Zhou, T.; Deng, S.; Zong, G.; Yao, X.; Fu, Q. . Size-specified graphene oxide sheets: ultrasonication assisted preparation and characterization . J. Mater. Sci. , 2014 . 49 1785 - 1793 . DOI: 10.1007/s10853-013-7866-8 http://doi.org/10.1007/s10853-013-7866-8 .

Chen, J.; Zhang, X.; Zheng, X.; Liu, C.; Cui, X.; Zheng, W. . Size distribution-controlled preparation of graphene oxide nanosheets with different C/O ratios . Mater. Chem. Phys. , 2013 . 139 8 - 11 . DOI: 10.1016/j.matchemphys.2012.12.025 http://doi.org/10.1016/j.matchemphys.2012.12.025 .

Khan, U.; O’Neill, A.; Porwal, H.; May, P.; Nawaz, K.; Coleman, J. N. . Size selection of dispersed, exfoliated graphene flakes by controlled centrifugation . Carbon , 2012 . 50 470 - 475 . DOI: 10.1016/j.carbon.2011.09.001 http://doi.org/10.1016/j.carbon.2011.09.001 .

Xu, X.; Liu, L.; Geng, H.; Wang, J.; Zhou, J.; Jiang, Y.; Doi, M. . Directional freezing of binary colloidal suspensions: a model for size fractionation of graphene oxide . Soft Matter , 2019 . 15 243 - 251 . DOI: 10.1039/C8SM01626G http://doi.org/10.1039/C8SM01626G .

Geng, H.; Yao, B.; Zhou, J.; Liu, K.; Bai, G.; Li, W.; Song, Y.; Shi, G.; Doi, M.; Wang, J. . Size fractionation of graphene oxide nanosheets via controlled directional freezing . J. Am. Chem. Soc. , 2017 . 139 12517 - 12523 . DOI: 10.1021/jacs.7b05490 http://doi.org/10.1021/jacs.7b05490 .

Chen, J.; Li, Y.; Huang, L.; Jia, N.; Li, C.; Shi, G. . Size fractionation of graphene oxide sheets via filtration through track-etched membranes . Adv. Mater. , 2015 . 27 3654 - 3660 . DOI: 10.1002/adma.201501271 http://doi.org/10.1002/adma.201501271 .

Zhang, W.; Zou, X.; Li, H.; Hou, J.; Zhao, J.; Lan, J.; Feng, B.; Liu, S. . Size fractionation of graphene oxide sheets by the polar solvent-selective natural deposition method . RSC Adv. , 2015 . 5 146 - 152 . DOI: 10.1039/C4RA08516G http://doi.org/10.1039/C4RA08516G .

Davardoostmanesh, M.; Goharshadi, E. K.; Ahmadzadeh, H. . Electrophoretic size fractionation of graphene oxide nanosheets . New J. Chem. , 2019 . 43 5047 - 5054 . DOI: 10.1039/C8NJ06411C http://doi.org/10.1039/C8NJ06411C .

Zhang, S.; Li, Y.; Sun, J.; Wang, J.; Qin, C.; Dai, L. . Size fractionation of graphene oxide sheets assisted by circular flow and their graphene aerogels with size-dependent adsorption . RSC Adv. , 2016 . 6 74053 - 74060 . DOI: 10.1039/C6RA16363G http://doi.org/10.1039/C6RA16363G .

Liu, F.; Jang, M. H.; Ha, H. D.; Kim, J. H.; Cho, Y. H.; Seo, T. S. . Facile synthetic method for pristine graphene quantum dots and graphene oxide quantum dots: origin of blue and green luminescence . Adv. Mater. , 2013 . 25 3657 - 3662 . DOI: 10.1002/adma.201300233 http://doi.org/10.1002/adma.201300233 .

Park, M.; Ha, H. D.; Kim, Y. T.; Jung, J. H.; Kim, S. H.; Kim, D. H.; Seo, T. S. . Combination of a sample pretreatment microfluidic device with a photoluminescent graphene oxide quantum dot sensor for trace lead detection . Anal. Chem. , 2015 . 87 10969 - 10975 . DOI: 10.1021/acs.analchem.5b02907 http://doi.org/10.1021/acs.analchem.5b02907 .

Yeh, T. F.; Teng, C. Y.; Chen, S. J.; Teng, H. . Nitrogen-doped graphene oxide quantum dots as photocatalysts for overall water-splitting under visible light illumination . Adv. Mater. , 2014 . 26 3297 - 3303 . DOI: 10.1002/adma.201305299 http://doi.org/10.1002/adma.201305299 .

Erickson, K.; Erni, R.; Lee, Z.; Alem, N.; Gannett, W.; Zettl, A. . Determination of the local chemical structure of graphene oxide and reduced graphene oxide . Adv. Mater. , 2010 . 22 4467 - 4472 . DOI: 10.1002/adma.201000732 http://doi.org/10.1002/adma.201000732 .

Chen, H.; Du, W.; Liu, J.; Qu, L.; Li, C. . Efficient room-temperature production of high-quality graphene by introducing removable oxygen functional groups to the precursor . Chem. Sci. , 2019 . 10 1244 - 1253 . DOI: 10.1039/C8SC03695K http://doi.org/10.1039/C8SC03695K .

Wang, X.; Jiao, L.; Sheng, K.; Li, C.; Dai, L.; Shi, G. . Solution-processable graphene nanomeshes with controlled pore structures . Sci. Rep. , 2013 . 3 1996 DOI: 10.1038/srep01996 http://doi.org/10.1038/srep01996 .

Zhou, S.; Kim, S.; Bongiorno, A. . Chemical structure of oxidized multilayer epitaxial graphene: a density functional theory study . J. Phys. Chem. C , 2013 . 117 6267 - 6274 . DOI: 10.1021/jp400128t http://doi.org/10.1021/jp400128t .

Lee, V.; Dennis, R. V.; Schultz, B. J.; Jaye, C.; Fischer, D. A.; Banerjee, S. . Soft X-ray absorption spectroscopy studies of the electronic structure recovery of graphene oxide upon chemical defunctionalization . J. Phys. Chem. C , 2012 . 116 20591 - 20599 . DOI: 10.1021/jp306497f http://doi.org/10.1021/jp306497f .

Paredes, J. I.; Villar-Rodil, S.; Martínez-Alonso, A.; Tascón, J. M. D. . Graphene oxide dispersions in organic solvents . Langmuir , 2008 . 24 10560 - 10564 . DOI: 10.1021/la801744a http://doi.org/10.1021/la801744a .

Neklyudov, V. V.; Agieienko, V. N.; Ziganshin, M. A.; Dimiev, A. M. . On the solvation behavior of graphene oxide in ethylene glycol/water mixtures . ChemPhysChem , 2018 . 19 1344 - 1348 . DOI: 10.1002/cphc.201800042 http://doi.org/10.1002/cphc.201800042 .

Kim, D. H.; Yun, Y. S.; Jin, H. J. . Difference of dispersion behavior between graphene oxide and oxidized carbon nanotubes in polar organic solvents . Curr. Appl. Phys. , 2012 . 12 637 - 642 . DOI: 10.1016/j.cap.2011.09.015 http://doi.org/10.1016/j.cap.2011.09.015 .

Konios, D.; Stylianakis, M. M.; Stratakis, E.; Kymakis, E. . Dispersion behaviour of graphene oxide and reduced graphene oxide . J. Colloid Interf. Sci. , 2014 . 430 108 - 112 . DOI: 10.1016/j.jcis.2014.05.033 http://doi.org/10.1016/j.jcis.2014.05.033 .

Park, S.; An, J.; Jung, I.; Piner, R. D.; An, S. J.; Li, X.; Velamakanni, A.; Ruoff, R. S. . Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents . Nano Lett. , 2009 . 9 1593 - 1597 . DOI: 10.1021/nl803798y http://doi.org/10.1021/nl803798y .

Neklyudov, V. V.; Khafizov, N. R.; Sedov, I. A.; Dimiev, A. M. . New insights into the solubility of graphene oxide in water and alcohols . Phys. Chem. Chem. Phys. , 2017 . 19 17000 - 17008 . DOI: 10.1039/C7CP02303K http://doi.org/10.1039/C7CP02303K .

Kim, J.; Cote, L. J.; Kim, F.; Yuan, W.; Shull, K. R.; Huang, J. . Graphene oxide sheets at interfaces . J. Am. Chem. Soc. , 2010 . 132 8180 - 8186 . DOI: 10.1021/ja102777p http://doi.org/10.1021/ja102777p .

Luo, J.; Cote, L. J.; Tung, V. C.; Tan, A. T. L.; Goins, P. E.; Wu, J.; Huang, J. . Graphene oxide nanocolloids . J. Am. Chem. Soc. , 2010 . 132 17667 - 17669 . DOI: 10.1021/ja1078943 http://doi.org/10.1021/ja1078943 .

Kim, F.; Cote, L. J.; Huang, J. . Graphene oxide: surface activity and two-dimensional assembly . Adv. Mater. , 2010 . 22 1954 - 1958 . DOI: 10.1002/adma.200903932 http://doi.org/10.1002/adma.200903932 .

Li, D.; Müller, M. B.; Gilje, S.; Kaner, R. B.; Wallace, G. G. . Processable aqueous dispersions of graphene nanosheets . Nat. Nanotechnol. , 2008 . 3 101 - 105 . DOI: 10.1038/nnano.2007.451 http://doi.org/10.1038/nnano.2007.451 .

Bepete, G.; Anglaret, E.; Ortolani, L.; Morandi, V.; Huang, K.; Pénicaud, A.; Drummond, C. . Surfactant-free single-layer graphene in water . Nat. Chem. , 2017 . 9 347 - 352 . DOI: 10.1038/nchem.2669 http://doi.org/10.1038/nchem.2669 .

Bai, G.; Gao, D.; Liu, Z.; Zhou, X.; Wang, J. . Probing the critical nucleus size for ice formation with graphene oxide nanosheets . Nature , 2019 . 576 437 - 441 . DOI: 10.1038/s41586-019-1827-6 http://doi.org/10.1038/s41586-019-1827-6 .

Koltonow, A. R.; Luo, C.; Luo, J.; Huang, J. . Graphene oxide sheets in solvents: to crumple or not to crumple? . ACS Omega , 2017 . 2 8005 - 8009 . DOI: 10.1021/acsomega.7b01647 http://doi.org/10.1021/acsomega.7b01647 .

Tang, B.; Yun, X.; Xiong, Z.; Wang, X. . Formation of graphene oxide nanoscrolls in organic solvents: toward scalable device fabrication . ACS Appl. Nano Mater. , 2018 . 1 686 - 697 . DOI: 10.1021/acsanm.7b00160 http://doi.org/10.1021/acsanm.7b00160 .

Tang, B.; Xiong, Z.; Yun, X.; Wang, X. . Rolling up graphene oxide sheets through solvent-induced self-assembly in dispersions . Nanoscale , 2018 . 10 4113 - 4122 . DOI: 10.1039/C7NR08415C http://doi.org/10.1039/C7NR08415C .

Tang, B.; Gao, E.; Xiong, Z.; Dang, B.; Xu, Z.; Wang, X. . Transition of graphene oxide from nanomembrane to nanoscroll mediated by organic solvent in dispersion . Chem. Mater. , 2018 . 30 5951 - 5960 . DOI: 10.1021/acs.chemmater.8b02083 http://doi.org/10.1021/acs.chemmater.8b02083 .

Chen, C.; Xu, Z.; Han, Y.; Sun, H.; Gao, C. . Redissolution of flower-shaped graphene oxide powder with high density . ACS Appl. Mater. Interfaces , 2016 . 8 8000 - 8007 . DOI: 10.1021/acsami.6b00126 http://doi.org/10.1021/acsami.6b00126 .

Zhang, M.; Wang, Y.; Huang, L.; Xu, Z.; Li, C.; Shi, G. . Multifunctional pristine chemically modified graphene films as strong as stainless steel . Adv. Mater. , 2015 . 27 6708 - 6713 . DOI: 10.1002/adma.201503045 http://doi.org/10.1002/adma.201503045 .

Deng, S.; Berry, V. . Wrinkled, rippled and crumpled graphene: an overview of formation mechanism, electronic properties, and applications . Mater. Today , 2016 . 19 197 - 212 . DOI: 10.1016/j.mattod.2015.10.002 http://doi.org/10.1016/j.mattod.2015.10.002 .

Ma, X.; Zachariah, M. R.; Zangmeister, C. D. . Crumpled nanopaper from graphene oxide . Nano Lett. , 2012 . 12 486 - 489 . DOI: 10.1021/nl203964z http://doi.org/10.1021/nl203964z .

Lee, W. K.; Kang, J.; Chen, K. S.; Engel, C. J.; Jung, W. B.; Rhee, D.; Hersam, M. C.; Odom, T. W. . Multiscale, hierarchical patterning of graphene by conformal wrinkling . Nano Lett. , 2016 . 16 7121 - 7127 . DOI: 10.1021/acs.nanolett.6b03415 http://doi.org/10.1021/acs.nanolett.6b03415 .

Xiao, Y.; Xu, Z.; Liu, Y.; Peng, L.; Xi, J.; Fang, B.; Guo, F.; Li, P.; Gao, C. . Sheet collapsing approach for rubber-like graphene papers . ACS Nano , 2017 . 11 8092 - 8102 . DOI: 10.1021/acsnano.7b02915 http://doi.org/10.1021/acsnano.7b02915 .

Abraham, F. F.; Kardar, M. . Folding and unbinding transitions in tethered membranes . Science , 1991 . 252 419 DOI: 10.1126/science.252.5004.419 http://doi.org/10.1126/science.252.5004.419 .

Wen, X.; Garland, C. W.; Hwa, T.; Kardar, M.; Kokufuta, E.; Li, Y.; Orkisz, M.; Tanaka, T. . Crumpled and collapsed conformation in graphite oxide membranes . Nature , 1992 . 355 426 - 428 . DOI: 10.1038/355426a0 http://doi.org/10.1038/355426a0 .

Bowick, M.; Falcioni, M.; Thorleifsson, G. . Numerical observation of a tubular phase in anisotropic membranes . Phys. Rev. Lett. , 1997 . 79 885 - 888 . DOI: 10.1103/PhysRevLett.79.885 http://doi.org/10.1103/PhysRevLett.79.885 .

Wang, Y.; Wang, S. J.; Li, P.; Rajendran, S.; Xu, Z.; Liu, S. P.; Guo, F.; He, Y. H.; Li, Z. S.; Xu, Z. P.; Gao, C. . Conformational phase map of two-dimensional macromolecular graphene oxide in solution . Matter , 2020 . 3 230 - 245 . DOI: 10.1016/j.matt.2020.04.023 http://doi.org/10.1016/j.matt.2020.04.023 .

Shih, C. J.; Lin, S.; Sharma, R.; Strano, M. S.; Blankschtein, D. . Understanding the pH-dependent behavior of graphene oxide aqueous solutions: a comparative experimental and molecular dynamics simulation study . Langmuir , 2012 . 28 235 - 241 . DOI: 10.1021/la203607w http://doi.org/10.1021/la203607w .

Wu, L.; Liu, L.; Gao, B.; Muñoz-Carpena, R.; Zhang, M.; Chen, H.; Zhou, Z.; Wang, H. . Aggregation kinetics of graphene oxides in aqueous solutions: experiments, mechanisms, and modeling . Langmuir , 2013 . 29 15174 - 15181 . DOI: 10.1021/la404134x http://doi.org/10.1021/la404134x .

Chowdhury, I.; Duch, M. C.; Mansukhani, N. D.; Hersam, M. C.; Bouchard, D. . Colloidal properties and stability of graphene oxide nanomaterials in the aquatic environment . Environ. Sci. Technol. , 2013 . 47 6288 - 6296 . DOI: 10.1021/es400483k http://doi.org/10.1021/es400483k .

Yang, K.; Chen, B.; Zhu, X.; Xing, B. . Aggregation, adsorption, and morphological transformation of graphene oxide in aqueous solutions containing different metal cations . Environ. Sci. Technol. , 2016 . 50 11066 - 11075 . DOI: 10.1021/acs.est.6b04235 http://doi.org/10.1021/acs.est.6b04235 .

Gudarzi, M. M. . Colloidal stability of graphene oxide: aggregation in two dimensions . Langmuir , 2016 . 32 5058 - 5068 . DOI: 10.1021/acs.langmuir.6b01012 http://doi.org/10.1021/acs.langmuir.6b01012 .

Yeh, C. N.; Raidongia, K.; Shao, J.; Yang, Q. H.; Huang, J. . On the origin of the stability of graphene oxide membranes in water . Nat. Chem. , 2015 . 7 166 - 170 . DOI: 10.1038/nchem.2145 http://doi.org/10.1038/nchem.2145 .

Guo, F.; Jiang, Y.; Xu, Z.; Xiao, Y.; Fang, B.; Liu, Y.; Gao, W.; Zhao, P.; Wang, H.; Gao, C. . Highly stretchable carbon aerogels . Nat. Commun. , 2018 . 9 881 DOI: 10.1038/s41467-018-03268-y http://doi.org/10.1038/s41467-018-03268-y .

He, Y.; Liu, Y.; Guo, F.; Pang, K.; Fang, B.; Wang, Y.; Chang, D.; Xu, Z.; Gao, C. . Dynamic dispersion stability of graphene oxide with metal ions . Chin. Chem. Lett. , 2020 . 31 1625 - 1629 . DOI: 10.1016/j.cclet.2019.10.010 http://doi.org/10.1016/j.cclet.2019.10.010 .

Del, Giudice F.; Shen, A. Q. . Shear rheology of graphene oxide dispersions . Curr. Opin. Chem. Eng. , 2017 . 16 23 - 30 . DOI: 10.1016/j.coche.2017.04.003 http://doi.org/10.1016/j.coche.2017.04.003 .

Naficy, S.; Jalili, R.; Aboutalebi, S. H.; Gorkin Iii, R. A.; Konstantinov, K.; Innis, P. C.; Spinks, G. M.; Poulin, P.; Wallace, G. G. . Graphene oxide dispersions: tuning rheology to enable fabrication . Mater. Horiz. , 2014 . 1 326 - 331 . DOI: 10.1039/C3MH00144J http://doi.org/10.1039/C3MH00144J .

Tesfai, W.; Singh, P.; Shatilla, Y.; Iqbal, M. Z.; Abdala, A. A. . Rheology and microstructure of dilute graphene oxide suspension . J. Nanopart. Res. , 2013 . 15 1989 DOI: 10.1007/s11051-013-1989-3 http://doi.org/10.1007/s11051-013-1989-3 .

Vallés, C.; Young, R. J.; Lomax, D. J.; Kinloch, I. A. . The rheological behaviour of concentrated dispersions of graphene oxide . J. Mater. Sci. , 2014 . 49 6311 - 6320 . DOI: 10.1007/s10853-014-8356-3 http://doi.org/10.1007/s10853-014-8356-3 .

Jiang, Y.; Xu, Z.; Huang, T.; Liu, Y.; Guo, F.; Xi, J.; Gao, W.; Gao, C. . Direct 3D printing of ultralight graphene oxide aerogel microlattices . Adv. Funct. Mater. , 2018 . 28 1707024 DOI: 10.1002/adfm.201707024 http://doi.org/10.1002/adfm.201707024 .

Stankovich, S.; Dikin, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y.; Wu, Y.; Nguyen, S. T.; Ruoff, R. S. . Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide . Carbon , 2007 . 45 1558 - 1565 . DOI: 10.1016/j.carbon.2007.02.034 http://doi.org/10.1016/j.carbon.2007.02.034 .

Fan, X.; Peng, W.; Li, Y.; Li, X.; Wang, S.; Zhang, G.; Zhang, F. . Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation . Adv. Mater. , 2008 . 20 4490 - 4493 . DOI: 10.1002/adma.200801306 http://doi.org/10.1002/adma.200801306 .

Becerril, H. A.; Mao, J.; Liu, Z.; Stoltenberg, R. M.; Bao, Z.; Chen, Y. . Evaluation of solution-processed reduced graphene oxide films as transparent conductors . ACS Nano , 2008 . 2 463 - 470 . DOI: 10.1021/nn700375n http://doi.org/10.1021/nn700375n .

Pei, S.; Zhao, J.; Du, J.; Ren, W.; Cheng, H. M. . Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids . Carbon , 2010 . 48 4466 - 4474 . DOI: 10.1016/j.carbon.2010.08.006 http://doi.org/10.1016/j.carbon.2010.08.006 .

Haubner, K.; Murawski, J.; Olk, P.; Eng, L. M.; Ziegler, C.; Adolphi, B.; Jaehne, E. . The route to functional graphene oxide . ChemPhysChem , 2010 . 11 2131 - 2139 . DOI: 10.1002/cphc.201000132 http://doi.org/10.1002/cphc.201000132 .

Yang, D.; Velamakanni, A.; Bozoklu, G.; Park, S.; Stoller, M.; Piner, R. D.; Stankovich, S.; Jung, I.; Field, D. A.; Ventrice, C. A.; Ruoff, R. S. . Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and micro-Raman spectroscopy . Carbon , 2009 . 47 145 - 152 . DOI: 10.1016/j.carbon.2008.09.045 http://doi.org/10.1016/j.carbon.2008.09.045 .

Wu, J. B.; Lin, M. L.; Cong, X.; Liu, H. N.; Tan, P. H. . Raman spectroscopy of graphene-based materials and its applications in related devices . Chem. Soc. Rev. , 2018 . 47 1822 - 1873 . DOI: 10.1039/C6CS00915H http://doi.org/10.1039/C6CS00915H .

Balandin, A. A. . Thermal properties of graphene and nanostructured carbon materials . Nat. Mater. , 2011 . 10 569 - 581 . DOI: 10.1038/nmat3064 http://doi.org/10.1038/nmat3064 .

Song, N. J.; Chen, C. M.; Lu, C.; Liu, Z.; Kong, Q. Q.; Cai, R. . Thermally reduced graphene oxide films as flexible lateral heat spreaders . J. Mater. Chem. A , 2014 . 2 16563 - 16568 . DOI: 10.1039/C4TA02693D http://doi.org/10.1039/C4TA02693D .

Xin, G.; Yao, T.; Sun, H.; Scott, S. M.; Shao, D.; Wang, G.; Lian, J. . Highly thermally conductive and mechanically strong graphene fibers . Science , 2015 . 349 1083 - 1087 . DOI: 10.1126/science.aaa6502 http://doi.org/10.1126/science.aaa6502 .

Peng, L.; Xu, Z.; Liu, Z.; Guo, Y.; Li, P.; Gao, C. . Ultrahigh thermal conductive yet superflexible graphene films . Adv. Mater. , 2017 . 29 1700589 DOI: 10.1002/adma.201700589 http://doi.org/10.1002/adma.201700589 .

Williams, G.; Seger, B.; Kamat, P. V. . TiO 2 -graphene nanocomposites. UV-assisted photocatalytic reduction of graphene oxide . ACS Nano , 2008 . 2 1487 - 1491 . DOI: 10.1021/nn800251f http://doi.org/10.1021/nn800251f .

Williams, G.; Kamat, P. V. . Graphene-semiconductor nanocomposites: excited-state interactions between ZnO nanoparticles and graphene oxide . Langmuir , 2009 . 25 13869 - 13873 . DOI: 10.1021/la900905h http://doi.org/10.1021/la900905h .

Ng, Y. H.; Iwase, A.; Kudo, A.; Amal, R. . Reducing graphene oxide on a visible-light BiVO 4 photocatalyst for an enhanced photoelectrochemical water splitting . J. Phys. Chem. Lett. , 2010 . 1 2607 - 2612 . DOI: 10.1021/jz100978u http://doi.org/10.1021/jz100978u .

Liu, Y.; Li, P.; Wang, F.; Fang, W.; Xu, Z.; Gao, W.; Gao, C. . Rapid roll-to-roll production of graphene films using intensive Joule heating . Carbon , 2019 . 155 462 - 468 . DOI: 10.1016/j.carbon.2019.09.021 http://doi.org/10.1016/j.carbon.2019.09.021 .

Zhang, Y.; Guo, L.; Wei, S.; He, Y.; Xia, H.; Chen, Q.; Sun, H. B.; Xiao, F. S. . Direct imprinting of microcircuits on graphene oxides film by femtosecond laser reduction . Nano Today , 2010 . 5 15 - 20 . DOI: 10.1016/j.nantod.2009.12.009 http://doi.org/10.1016/j.nantod.2009.12.009 .

Voiry, D.; Yang, J.; Kupferberg, J.; Fullon, R.; Lee, C.; Jeong, H. Y.; Shin, H. S.; Chhowalla, M. . High-quality graphene via microwave reduction of solution-exfoliated graphene oxide . Science , 2016 . 353 1413 DOI: 10.1126/science.aah3398 http://doi.org/10.1126/science.aah3398 .

Chen, Y.; Fu, K.; Zhu, S.; Luo, W.; Wang, Y.; Li, Y.; Hitz, E.; Yao, Y.; Dai, J.; Wan, J.; Danner, V. A.; Li, T.; Hu, L. . Reduced graphene oxide films with ultrahigh conductivity as Li-ion battery current collectors . Nano Lett. , 2016 . 16 3616 - 3623 . DOI: 10.1021/acs.nanolett.6b00743 http://doi.org/10.1021/acs.nanolett.6b00743 .

Wang, Z.; Zhou, X.; Zhang, J.; Boey, F.; Zhang, H. . Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase . J. Phys. Chem. C , 2009 . 113 14071 - 14075 . DOI: 10.1021/jp906348x http://doi.org/10.1021/jp906348x .

An, S. J.; Zhu, Y.; Lee, S. H.; Stoller, M. D.; Emilsson, T.; Park, S.; Velamakanni, A.; An, J.; Ruoff, R. S. . Thin film fabrication and simultaneous anodic reduction of deposited graphene oxide platelets by electrophoretic deposition . J. Phys. Chem. Lett. , 2010 . 1 1259 - 1263 . DOI: 10.1021/jz100080c http://doi.org/10.1021/jz100080c .

Zhou, M.; Wang, Y.; Zhai, Y.; Zhai, J.; Ren, W.; Wang, F.; Dong, S. . Controlled synthesis of large-area and patterned electrochemically reduced graphene oxide films . Chem. Eur. J. , 2009 . 15 6116 - 6120 . DOI: 10.1002/chem.200900596 http://doi.org/10.1002/chem.200900596 .

Johns, J. E.; Hersam, M. C. . Atomic covalent functionalization of graphene . Acc. Chem. Res. , 2013 . 46 77 - 86 . DOI: 10.1021/ar300143e http://doi.org/10.1021/ar300143e .

Li, X.; Wang, H.; Robinson, J. T.; Sanchez, H.; Diankov, G.; Dai, H. . Simultaneous nitrogen doping and reduction of graphene oxide . J. Am. Chem. Soc. , 2009 . 131 15939 - 15944 . DOI: 10.1021/ja907098f http://doi.org/10.1021/ja907098f .

Sheng, Z. H.; Shao, L.; Chen, J. J.; Bao, W. J.; Wang, F. B.; Xia, X. H. . Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis . ACS Nano , 2011 . 5 4350 - 4358 . DOI: 10.1021/nn103584t http://doi.org/10.1021/nn103584t .

Kumar, N. A.; Nolan, H.; McEvoy, N.; Rezvani, E.; Doyle, R. L.; Lyons, M. E. G.; Duesberg, G. S. . Plasma-assisted simultaneous reduction and nitrogen doping of graphene oxide nanosheets . J. Mater. Chem. A , 2013 . 1 4431 - 4435 . DOI: 10.1039/c3ta10337d http://doi.org/10.1039/c3ta10337d .

Zhang, H.; Kuila, T.; Kim, N. H.; Yu, D. S.; Lee, J. H. . Simultaneous reduction, exfoliation, and nitrogen doping of graphene oxide via a hydrothermal reaction for energy storage electrode materials . Carbon , 2014 . 69 66 - 78 . DOI: 10.1016/j.carbon.2013.11.059 http://doi.org/10.1016/j.carbon.2013.11.059 .

Wang, X.; Wang, J.; Wang, D.; Dou, S.; Ma, Z.; Wu, J.; Tao, L.; Shen, A.; Ouyang, C.; Liu, Q.; Wang, S. . One-pot synthesis of nitrogen and sulfur co-doped graphene as efficient metal-free electrocatalysts for the oxygen reduction reaction . Chem. Commun. , 2014 . 50 4839 - 4842 . DOI: 10.1039/C4CC00440J http://doi.org/10.1039/C4CC00440J .

Yu, Q.; Xu, J.; Wan, C.; Wu, C.; Guan, L. . Porous cobalt-nitrogen-doped hollow graphene spheres as a superior electrocatalyst for enhanced oxygen reduction in both alkaline and acidic solutions . J. Mater. Chem. A , 2015 . 3 16419 - 16423 . DOI: 10.1039/C5TA04852D http://doi.org/10.1039/C5TA04852D .

Xu, K.; Fu, Y.; Zhou, Y.; Hennersdorf, F.; Machata, P.; Vincon, I.; Weigand, J. J.; Popov, A. A.; Berger, R.; Feng, X. . Cationic nitrogen-doped helical nanographenes . Angew. Chem. Int. Ed. , 2017 . 56 15876 - 15881 . DOI: 10.1002/anie.201707714 http://doi.org/10.1002/anie.201707714 .

Lee, S. H.; Kim, H. W.; Hwang, J. O.; Lee, W. J.; Kwon, J.; Bielawski, C. W.; Ruoff, R. S.; Kim, S. O. . Three-dimensional self-assembly of graphene oxide platelets into mechanically flexible macroporous carbon films . Angew. Chem. Int. Ed. , 2010 . 122 10282 - 10286 . DOI: 10.1002/ange.201006240 http://doi.org/10.1002/ange.201006240 .

Schedin, F.; Geim, A. K.; Morozov, S. V.; Hill, E. W.; Blake, P.; Katsnelson, M. I.; Novoselov, K. S. . Detection of individual gas molecules adsorbed on graphene . Nat. Mater. , 2007 . 6 652 - 655 . DOI: 10.1038/nmat1967 http://doi.org/10.1038/nmat1967 .

Melucci, M.; Treossi, E.; Ortolani, L.; Giambastiani, G.; Morandi, V.; Klar, P.; Casiraghi, C.; Samorì, P.; Palermo, V. . Facile covalent functionalization of graphene oxide using microwaves: bottom-up development of functional graphitic materials . J. Mater. Chem. , 2010 . 20 9052 - 9060 . DOI: 10.1039/c0jm01242d http://doi.org/10.1039/c0jm01242d .

Liu, H.; Xi, P.; Xie, G.; Shi, Y.; Hou, F.; Huang, L.; Chen, F.; Zeng, Z.; Shao, C.; Wang, J. . Simultaneous reduction and surface functionalization of graphene oxide for hydroxyapatite mineralization . J. Phys. Chem. C , 2012 . 116 3334 - 3341 . DOI: 10.1021/jp2102226 http://doi.org/10.1021/jp2102226 .

Xue, Y.; Liu, Y.; Lu, F.; Qu, J.; Chen, H.; Dai, L. . Functionalization of graphene oxide with polyhedral oligomeric silsesquioxane (POSS) for multifunctional applications . J. Phys. Chem. Lett. , 2012 . 3 1607 - 1612 . DOI: 10.1021/jz3005877 http://doi.org/10.1021/jz3005877 .

Kang, S. M.; Park, S.; Kim, D.; Park, S. Y.; Ruoff, R. S.; Lee, H. . Simultaneous reduction and surface functionalization of graphene oxide by mussel-inspired chemistry . Adv. Funct. Mater. , 2011 . 21 108 - 112 . DOI: 10.1002/adfm.201001692 http://doi.org/10.1002/adfm.201001692 .

Lin, Y.; Jin, J.; Song, M. . Preparation and characterisation of covalent polymer functionalized graphene oxide . J. Mater. Chem. , 2011 . 21 3455 - 3461 . DOI: 10.1039/C0JM01859G http://doi.org/10.1039/C0JM01859G .

Ou, J.; Wang, J.; Liu, S.; Mu, B.; Ren, J.; Wang, H.; Yang, S. . Tribology study of reduced graphene oxide sheets on silicon substrate synthesized via covalent assembly . Langmuir , 2010 . 26 15830 - 15836 . DOI: 10.1021/la102862d http://doi.org/10.1021/la102862d .

Sonin, A. S. . Inorganic lyotropic liquid crystals . J. Mater. Chem. , 1998 . 8 2557 - 2574 . DOI: 10.1039/a802666a http://doi.org/10.1039/a802666a .

Davidson, P.; Gabriel, J. C. P. . Mineral liquid crystals . Curr. Opin. Colloid Interface Sci. , 2005 . 9 377 - 383 . DOI: 10.1016/j.cocis.2004.12.001 http://doi.org/10.1016/j.cocis.2004.12.001 .

Emerson, W. W. . Liquid crystals of montmorillonite . Nature , 1956 . 178 1248 - 1249 . DOI: 10.1038/1781248a0 http://doi.org/10.1038/1781248a0 .

Thiele, H. . Viskosität und gelbildung der graphitsäure . Kolloid-Z. , 1948 . 111 15 - 19 . DOI: 10.1007/BF01522013 http://doi.org/10.1007/BF01522013 .

Dan, B.; Behabtu, N.; Martinez, A.; Evans, J. S.; Kosynkin, D. V.; Tour, J. M.; Pasquali, M.; Smalyukh, I. I. . Liquid crystals of aqueous, giant graphene oxide flakes . Soft Matter , 2011 . 7 11154 - 11159 . DOI: 10.1039/c1sm06418e http://doi.org/10.1039/c1sm06418e .

Zamora-Ledezma, C.; Puech, N.; Zakri, C.; Grelet, E.; Moulton, S. E.; Wallace, G. G.; Gambhir, S.; Blanc, C.; Anglaret, E.; Poulin, P. . Liquid crystallinity and dimensions of surfactant-stabilized sheets of reduced graphene oxide . J. Phys. Chem. Lett. , 2012 . 3 2425 - 2430 . DOI: 10.1021/jz3008479 http://doi.org/10.1021/jz3008479 .

Jalili, R.; Aboutalebi, S. H.; Esrafilzadeh, D.; Konstantinov, K.; Moulton, S. E.; Razal, J. M.; Wallace, G. G. . Organic solvent-based graphene oxide liquid crystals: a facile route toward the next generation of self-assembled layer-by-layer multifunctional 3D architectures . ACS Nano , 2013 . 7 3981 - 3990 . DOI: 10.1021/nn305906z http://doi.org/10.1021/nn305906z .

Gudarzi, M. M.; Moghadam, M. H. M.; Sharif, F. . Spontaneous exfoliation of graphite oxide in polar aprotic solvents as the route to produce graphene oxide-organic solvents liquid crystals . Carbon , 2013 . 64 403 - 415 . DOI: 10.1016/j.carbon.2013.07.093 http://doi.org/10.1016/j.carbon.2013.07.093 .

Onsager, L. . The effects of shape on the interaction of colloidal particles . Ann. N. Y. Acad. Sci. , 1949 . 51 627 - 659 . DOI: 10.1111/j.1749-6632.1949.tb27296.x http://doi.org/10.1111/j.1749-6632.1949.tb27296.x .

Aboutalebi, S. H.; Gudarzi, M. M.; Zheng, Q. B.; Kim, J. K. . Spontaneous formation of liquid crystals in ultralarge graphene oxide dispersions . Adv. Funct. Mater. , 2011 . 21 2978 - 2988 . DOI: 10.1002/adfm.201100448 http://doi.org/10.1002/adfm.201100448 .

Kumar, P.; Maiti, U. N.; Lee, K. E.; Kim, S. O. . Rheological properties of graphene oxide liquid crystal . Carbon , 2014 . 80 453 - 461 . DOI: 10.1016/j.carbon.2014.08.085 http://doi.org/10.1016/j.carbon.2014.08.085 .

Xu, Z.; Gao, C. . Graphene chiral liquid crystals and macroscopic assembled fibres . Nat. Commun. , 2011 . 2 571 DOI: 10.1038/ncomms1583 http://doi.org/10.1038/ncomms1583 .

Jiang, Y.; Guo, F.; Xu, Z.; Gao, W.; Gao, C. . Artificial colloidal liquid metacrystals by shearing microlithography . Nat. Commun. , 2019 . 10 4111 DOI: 10.1038/s41467-019-11941-z http://doi.org/10.1038/s41467-019-11941-z .

Liu, Z.; Xu, Z.; Hu, X.; Gao, C. . Lyotropic liquid crystal of polyacrylonitrile-grafted graphene oxide and its assembled continuous strong nacre-mimetic fibers . Macromolecules , 2013 . 46 6931 - 6941 . DOI: 10.1021/ma400681v http://doi.org/10.1021/ma400681v .

Yao, B.; Chen, J.; Huang, L.; Zhou, Q.; Shi, G. . Base-induced liquid crystals of graphene oxide for preparing elastic graphene foams with long-range ordered microstructures . Adv. Mater. , 2016 . 28 1623 - 1629 . DOI: 10.1002/adma.201504594 http://doi.org/10.1002/adma.201504594 .

Shen, T. Z.; Hong, S. H.; Song, J. K. . Electro-optical switching of graphene oxide liquid crystals with an extremely large Kerr coefficient . Nat. Mater. , 2014 . 13 394 - 399 . DOI: 10.1038/nmat3888 http://doi.org/10.1038/nmat3888 .

Wang, B.; Liu, J.; Zhao, Y.; Li, Y.; Xian, W.; Amjadipour, M.; MacLeod, J.; Motta, N. . Role of graphene oxide liquid crystals in hydrothermal reduction and supercapacitor performance . ACS Appl. Mater. Interfaces , 2016 . 8 22316 - 22323 . DOI: 10.1021/acsami.6b05779 http://doi.org/10.1021/acsami.6b05779 .

Guo, F.; Kim, F.; Han, T. H.; Shenoy, V. B.; Huang, J.; Hurt, R. H. . Hydration-responsive folding and unfolding in graphene oxide liquid crystal phases . ACS Nano , 2011 . 5 8019 - 8025 . DOI: 10.1021/nn2025644 http://doi.org/10.1021/nn2025644 .

Park, H.; Lee, K. H.; Kim, Y. B.; Ambade, S. B.; Noh, S. H.; Eom, W.; Hwang, J. Y.; Lee, W. J.; Huang, J.; Han, T. H. . Dynamic assembly of liquid crystalline graphene oxide gel fibers for ion transport . Sci. Adv. , 2018 . 4 eaau2104 DOI: 10.1126/sciadv.aau2104 http://doi.org/10.1126/sciadv.aau2104 .

Hu, X.; Xu, Z.; Liu, Z.; Gao, C. . Liquid crystal self-templating approach to ultrastrong and tough biomimic composites . Sci. Rep. , 2013 . 3 2374 DOI: 10.1038/srep02374 http://doi.org/10.1038/srep02374 .

Akbari, A.; Sheath, P.; Martin, S. T.; Shinde, D. B.; Shaibani, M.; Banerjee, P. C.; Tkacz, R.; Bhattacharyya, D.; Majumder, M. . Large-area graphene-based nanofiltration membranes by shear alignment of discotic nematic liquid crystals of graphene oxide . Nat. Commun. , 2016 . 7 10891 DOI: 10.1038/ncomms10891 http://doi.org/10.1038/ncomms10891 .

Zakri, C.; Blanc, C.; Grelet, E.; Zamora-Ledezma, C.; Puech, N.; Anglaret, E.; Poulin, P. . Liquid crystals of carbon nanotubes and graphene . Philos. Trans. R. Soc. A , 2013 . 371 20120499 DOI: 10.1098/rsta.2012.0499 http://doi.org/10.1098/rsta.2012.0499 .

Yang, Q.; Xu, Z.; Gao, C. . Graphene fiber based supercapacitors: strategies and perspective toward high performances . J. Energy Chem. , 2018 . 27 6 - 11 . DOI: 10.1016/j.jechem.2017.10.023 http://doi.org/10.1016/j.jechem.2017.10.023 .

Fang, B.; Chang, D.; Xu, Z.; Gao, C. . A review on graphene fibers: expectations, advances, and prospects . Adv. Mater. , 2020 . 32 1902664 DOI: 10.1002/adma.201902664 http://doi.org/10.1002/adma.201902664 .

Liu, Y.; Xu, Z.; Gao, W.; Cheng, Z.; Gao, C. . Graphene and other 2D colloids: liquid crystals and macroscopic fibers . Adv. Mater. , 2017 . 29 1606794 DOI: 10.1002/adma.201606794 http://doi.org/10.1002/adma.201606794 .

Dong, Z.; Jiang, C.; Cheng, H.; Zhao, Y.; Shi, G.; Jiang, L.; Qu, L. . Facile fabrication of light, flexible and multifunctional graphene fibers . Adv. Mater. , 2012 . 24 1856 - 1861 . DOI: 10.1002/adma.201200170 http://doi.org/10.1002/adma.201200170 .

Xin, G.; Sun, H.; Hu, T.; Fard, H. R.; Sun, X.; Koratkar, N.; Borca-Tasciuc, T.; Lian, J. . Large-area freestanding graphene paper for superior thermal management . Adv. Mater. , 2014 . 26 4521 - 4526 . DOI: 10.1002/adma.201400951 http://doi.org/10.1002/adma.201400951 .

Dikin, D. A.; Stankovich, S.; Zimney, E. J.; Piner, R. D.; Dommett, G. H. B.; Evmenenko, G.; Nguyen, S. T.; Ruoff, R. S. . Preparation and characterization of graphene oxide paper . Nature , 2007 . 448 457 DOI: 10.1038/nature06016 http://doi.org/10.1038/nature06016 .

Xu, Z.; Zhang, Y.; Li, P.; Gao, C. . Strong, conductive, lightweight, neat graphene aerogel fibers with aligned pores . ACS Nano , 2012 . 6 7103 - 7113 . DOI: 10.1021/nn3021772 http://doi.org/10.1021/nn3021772 .

Xu, Z.; Liu, Y.; Zhao, X.; Peng, L.; Sun, H.; Xu, Y.; Ren, X.; Jin, C.; Xu, P.; Wang, M.; Gao, C. . Ultrastiff and strong graphene fibers via full-scale synergetic defect engineering . Adv. Mater. , 2016 . 28 6449 - 6456 . DOI: 10.1002/adma.201506426 http://doi.org/10.1002/adma.201506426 .

Li, P.; Liu, Y.; Shi, S.; Xu, Z.; Ma, W.; Wang, Z.; Liu, S.; Gao, C. . Highly crystalline graphene fibers with superior strength and conductivities by plasticization spinning . Adv. Funct. Mater. , 2020 . n/a 2006584 .

Park, S.; Lee, K. S.; Bozoklu, G.; Cai, W.; Nguyen, S. T.; Ruoff, R. S. . Graphene oxide papers modified by divalent ions—enhancing mechanical properties via chemical cross-linking . ACS Nano , 2008 . 2 572 - 578 . DOI: 10.1021/nn700349a http://doi.org/10.1021/nn700349a .

Ma, T.; Gao, H. L.; Cong, H. P.; Yao, H. B.; Wu, L.; Yu, Z. Y.; Chen, S. M.; Yu, S. H. . A bioinspired interface design for improving the strength and electrical conductivity of graphene-based fibers . Adv. Mater. , 2018 . 30 1706435 DOI: 10.1002/adma.201706435 http://doi.org/10.1002/adma.201706435 .

Kim, I. H.; Yun, T.; Kim, J. E.; Yu, H.; Sasikala, S. P.; Lee, K. E.; Koo, S. H.; Hwang, H.; Jung, H. J.; Park, J. Y.; Jeong, H. S.; Kim, S. O. . Mussel-inspired defect engineering of graphene liquid crystalline fibers for synergistic enhancement of mechanical strength and electrical conductivity . Adv. Mater. , 2018 . 30 1803267 DOI: 10.1002/adma.201803267 http://doi.org/10.1002/adma.201803267 .

Shin, M. K.; Lee, B.; Kim, S. H.; Lee, J. A.; Spinks, G. M.; Gambhir, S.; Wallace, G. G.; Kozlov, M. E.; Baughman, R. H.; Kim, S. J. . Synergistic toughening of composite fibres by self-alignment of reduced graphene oxide and carbon nanotubes . Nat. Commun. , 2012 . 3 650 DOI: 10.1038/ncomms1661 http://doi.org/10.1038/ncomms1661 .

Ni, H.; Xu, F.; Tomsia, A. P.; Saiz, E.; Jiang, L.; Cheng, Q. . Robust bioinspired graphene film via π - π cross-linking . ACS Appl. Mater. Interfaces , 2017 . 9 24987 - 24992 . DOI: 10.1021/acsami.7b07748 http://doi.org/10.1021/acsami.7b07748 .

Zhang, X.; Guo, Y.; Liu, Y.; Li, Z.; Fang, W.; Peng, L.; Zhou, J.; Xu, Z.; Gao, C. . Ultrathick and highly thermally conductive graphene films by self-fusion . Carbon , 2020 . 167 249 - 255 . DOI: 10.1016/j.carbon.2020.05.051 http://doi.org/10.1016/j.carbon.2020.05.051 .

Hicks, J.; Behnam, A.; Ural, A. . A computational study of tunneling-percolation electrical transport in graphene-based nanocomposites . Appl. Phys. Lett. , 2009 . 95 213103 DOI: 10.1063/1.3267079 http://doi.org/10.1063/1.3267079 .

Vaneski, A.; Susha, A. S.; Rodríguez-Fernández, J.; Berr, M.; Jäckel, F.; Feldmann, J.; Rogach, A. L. . Hybrid colloidal heterostructures of anisotropic semiconductor nanocrystals decorated with noble metals: synthesis and function . Adv. Funct. Mater. , 2011 . 21 1547 - 1556 . DOI: 10.1002/adfm.201002444 http://doi.org/10.1002/adfm.201002444 .

Yu, D.; Goh, K.; Wang, H.; Wei, L.; Jiang, W.; Zhang, Q.; Dai, L.; Chen, Y. . Scalable synthesis of hierarchically structured carbon nanotube-graphene fibres for capacitive energy storage . Nat. Nanotechnol. , 2014 . 9 555 - 562 . DOI: 10.1038/nnano.2014.93 http://doi.org/10.1038/nnano.2014.93 .

Wang, H.; Wang, C.; Jian, M.; Wang, Q.; Xia, K.; Yin, Z.; Zhang, M.; Liang, X.; Zhang, Y. . Superelastic wire-shaped supercapacitor sustaining 850% tensile strain based on carbon nanotube@graphene fiber . Nano Res. , 2018 . 11 2347 - 2356 . DOI: 10.1007/s12274-017-1782-1 http://doi.org/10.1007/s12274-017-1782-1 .

Cai, S.; Huang, T.; Chen, H.; Salman, M.; Gopalsamy, K.; Gao, C. . Wet-spinning of ternary synergistic coaxial fibers for high performance yarn supercapacitors . J. Mater. Chem. A , 2017 . 5 22489 - 22494 . DOI: 10.1039/C7TA07937K http://doi.org/10.1039/C7TA07937K .

Choi, S. J.; Yu, H.; Jang, J. S.; Kim, M. H.; Kim, S. J.; Jeong, H. S.; Kim, I. D. . Nitrogen-doped single graphene fiber with platinum water dissociation catalyst for wearable humidity sensor . Small , 2018 . 14 1703934 DOI: 10.1002/smll.201703934 http://doi.org/10.1002/smll.201703934 .

Li, G.; Hong, G.; Dong, D.; Song, W.; Zhang, X. . Multiresponsive graphene-aerogel-directed phase-change smart fibers . Adv. Mater. , 2018 . 30 1801754 DOI: 10.1002/adma.201801754 http://doi.org/10.1002/adma.201801754 .

Zheng, X.; Zhang, K.; Yao, L.; Qiu, Y.; Wang, S. . Hierarchically porous sheath-core graphene-based fiber-shaped supercapacitors with high energy density . J. Mater. Chem. A , 2018 . 6 896 - 907 . DOI: 10.1039/C7TA08362A http://doi.org/10.1039/C7TA08362A .

Meng, J.; Nie, W.; Zhang, K.; Xu, F.; Ding, X.; Wang, S.; Qiu, Y. . Enhancing electrochemical performance of graphene fiber-based supercapacitors by plasma treatment . ACS Appl. Mater. Interfaces , 2018 . 10 13652 - 13659 . DOI: 10.1021/acsami.8b04438 http://doi.org/10.1021/acsami.8b04438 .

Chen, Z.; Ren, W.; Gao, L.; Liu, B.; Pei, S.; Cheng, H. M. . Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition . Nat. Mater. , 2011 . 10 424 - 428 . DOI: 10.1038/nmat3001 http://doi.org/10.1038/nmat3001 .

Wu, G.; Tan, P.; Wu, X.; Peng, L.; Cheng, H.; Wang, C. F.; Chen, W.; Yu, Z.; Chen, S. . High-performance wearable micro-supercapacitors based on microfluidic-directed nitrogen-doped graphene fiber electrodes . Adv. Funct. Mater. , 2017 . 27 1702493 DOI: 10.1002/adfm.201702493 http://doi.org/10.1002/adfm.201702493 .

Zhang, Y.; Li, Y.; Ming, P.; Zhang, Q.; Liu, T.; Jiang, L.; Cheng, Q. . Ultrastrong bioinspired graphene-based fibers via synergistic toughening . Adv. Mater. , 2016 . 28 2834 - 2839 . DOI: 10.1002/adma.201506074 http://doi.org/10.1002/adma.201506074 .

Qu, G.; Cheng, J.; Li, X.; Yuan, D.; Chen, P.; Chen, X.; Wang, B.; Peng, H. . A fiber supercapacitor with high energy density based on hollow graphene/conducting polymer fiber electrode . Adv. Mater. , 2016 . 28 3646 - 3652 . DOI: 10.1002/adma.201600689 http://doi.org/10.1002/adma.201600689 .

Lu, Z.; Foroughi, J.; Wang, C.; Long, H.; Wallace, G. G. . Superelastic hybrid CNT/graphene fibers for wearable energy storage . Adv. Energy Mater. , 2018 . 8 1702047 DOI: 10.1002/aenm.201702047 http://doi.org/10.1002/aenm.201702047 .

Kou, L.; Huang, T.; Zheng, B.; Han, Y.; Zhao, X.; Gopalsamy, K.; Sun, H.; Gao, C. . Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics . Nat. Commun. , 2014 . 5 3754 DOI: 10.1038/ncomms4754 http://doi.org/10.1038/ncomms4754 .

Meng, Y.; Zhao, Y.; Hu, C.; Cheng, H.; Hu, Y.; Zhang, Z.; Shi, G.; Qu, L. . All-graphene core-sheath microfibers for all-solid-state, stretchable fibriform supercapacitors and wearable electronic textiles . Adv. Mater. , 2013 . 25 2326 - 2331 . DOI: 10.1002/adma.201300132 http://doi.org/10.1002/adma.201300132 .

Chen, G.; Chen, T.; Hou, K.; Ma, W.; Tebyetekerwa, M.; Cheng, Y.; Weng, W.; Zhu, M. . Robust, hydrophilic graphene/cellulose nanocrystal fiber-based electrode with high capacitive performance and conductivity . Carbon , 2018 . 127 218 - 227 . DOI: 10.1016/j.carbon.2017.11.012 http://doi.org/10.1016/j.carbon.2017.11.012 .

Wang, R.; Xu, Z.; Zhuang, J.; Liu, Z.; Peng, L.; Li, Z.; Liu, Y.; Gao, W.; Gao, C. . Highly stretchable graphene fibers with ultrafast electrothermal response for low-voltage wearable heaters . Adv. Electron. Mater. , 2017 . 3 1600425 DOI: 10.1002/aelm.201600425 http://doi.org/10.1002/aelm.201600425 .

Liu, Y.; Xu, Z.; Zhan, J.; Li, P.; Gao, C. . Superb electrically conductive graphene fibers via doping strategy . Adv. Mater. , 2016 . 28 7941 - 7947 . DOI: 10.1002/adma.201602444 http://doi.org/10.1002/adma.201602444 .

Liu, Y.; Liang, H.; Xu, Z.; Xi, J.; Chen, G.; Gao, W.; Xue, M.; Gao, C. . Superconducting continuous graphene fibers via calcium intercalation . ACS Nano , 2017 . 11 4301 - 4306 . DOI: 10.1021/acsnano.7b01491 http://doi.org/10.1021/acsnano.7b01491 .

Zhou, Q.; Zhang, M.; Chen, J.; Hong, J. D.; Shi, G. . Nitrogen-doped holey graphene film-based ultrafast electrochemical capacitors . ACS Appl. Mater. Interfaces , 2016 . 8 20741 - 20747 . DOI: 10.1021/acsami.6b05601 http://doi.org/10.1021/acsami.6b05601 .

Yin, S.; Zhang, Y.; Kong, J.; Zou, C.; Li, C. M.; Lu, X.; Ma, J.; Boey, F. Y. C.; Chen, X. . Assembly of graphene sheets into hierarchical structures for high-performance energy storage . ACS Nano , 2011 . 5 3831 - 3838 . DOI: 10.1021/nn2001728 http://doi.org/10.1021/nn2001728 .

Yang, X.; Cheng, C.; Wang, Y.; Qiu, L.; Li, D. . Liquid-mediated dense integration of graphene materials for compact capacitive energy storage . Science , 2013 . 341 534 DOI: 10.1126/science.1239089 http://doi.org/10.1126/science.1239089 .

Cai, S.; Bai, T.; Chen, H.; Fang, W.; Xu, Z.; Lai, H.; Huang, T.; Xu, H.; Chu, X.; Ling, J.; Gao, C. . Heavy water enables high-voltage aqueous electrochemistry via the deuterium isotope effect . J. Phys. Chem. Lett. , 2020 . 11 303 - 310 . DOI: 10.1021/acs.jpclett.9b03267 http://doi.org/10.1021/acs.jpclett.9b03267 .

Zhang, L.; Ding, Y.; Zhang, C.; Zhou, Y.; Zhou, X.; Liu, Z.; Yu, G. . Enabling graphene-oxide-based membranes for large-scale energy storage by controlling hydrophilic microstructures . Chem , 2018 . 4 1035 - 1046 . DOI: 10.1016/j.chempr.2018.02.003 http://doi.org/10.1016/j.chempr.2018.02.003 .

Dong, X.; Xu, H.; Chen, H.; Wang, L.; Wang, J.; Fang, W.; Chen, C.; Salman, M.; Xu, Z.; Gao, C. . Commercial expanded graphite as high-performance cathode for low-cost aluminum-ion battery . Carbon , 2019 . 148 134 - 140 . DOI: 10.1016/j.carbon.2019.03.080 http://doi.org/10.1016/j.carbon.2019.03.080 .

Chen, H.; Xu, H.; Wang, S.; Huang, T.; Xi, J.; Cai, S.; Guo, F.; Xu, Z.; Gao, W.; Gao, C. . Ultrafast all-climate aluminum-graphene battery with quarter-million cycle life . Sci. Adv. , 2017 . 3 eaao7233 DOI: 10.1126/sciadv.aao7233 http://doi.org/10.1126/sciadv.aao7233 .

Chen, H.; Guo, F.; Liu, Y.; Huang, T.; Zheng, B.; Ananth, N.; Xu, Z.; Gao, W.; Gao, C. . A defect-free principle for advanced graphene cathode of aluminum-ion battery . Adv. Mater. , 2017 . 29 1605958 DOI: 10.1002/adma.201605958 http://doi.org/10.1002/adma.201605958 .

Chen, L.; Shi, G.; Shen, J.; Peng, B.; Zhang, B.; Wang, Y.; Bian, F.; Wang, J.; Li, D.; Qian, Z.; Xu, G.; Liu, G.; Zeng, J.; Zhang, L.; Yang, Y.; Zhou, G.; Wu, M.; Jin, W.; Li, J.; Fang, H. . Ion sieving in graphene oxide membranes via cationic control of interlayer spacing . Nature , 2017 . 550 380 - 383 . DOI: 10.1038/nature24044 http://doi.org/10.1038/nature24044 .

Yang, Q.; Su, Y.; Chi, C.; Cherian, C. T.; Huang, K.; Kravets, V. G.; Wang, F. C.; Zhang, J. C.; Pratt, A.; Grigorenko, A. N.; Guinea, F.; Geim, A. K.; Nair, R. R. . Ultrathin graphene-based membrane with precise molecular sieving and ultrafast solvent permeation . Nat. Mater. , 2017 . 16 1198 - 1202 . DOI: 10.1038/nmat5025 http://doi.org/10.1038/nmat5025 .

Zhou, K. G.; Vasu, K. S.; Cherian, C. T.; Neek-Amal, M.; Zhang, J. C.; Ghorbanfekr-Kalashami, H.; Huang, K.; Marshall, O. P.; Kravets, V. G.; Abraham, J.; Su, Y.; Grigorenko, A. N.; Pratt, A.; Geim, A. K.; Peeters, F. M.; Novoselov, K. S.; Nair, R. R. . Electrically controlled water permeation through graphene oxide membranes . Nature , 2018 . 559 236 - 240 . DOI: 10.1038/s41586-018-0292-y http://doi.org/10.1038/s41586-018-0292-y .

Wang, J.; Sun, L.; Zou, M.; Gao, W.; Liu, C.; Shang, L.; Gu, Z.; Zhao, Y. . Bioinspired shape-memory graphene film with tunable wettability . Sci. Adv. , 2017 . 3 e1700004 DOI: 10.1126/sciadv.1700004 http://doi.org/10.1126/sciadv.1700004 .

Zhou, F.; Tien, H. N.; Xu, W. L.; Chen, J. T.; Liu, Q.; Hicks, E.; Fathizadeh, M.; Li, S.; Yu, M. . Ultrathin graphene oxide-based hollow fiber membranes with brush-like CO 2 -philic agent for highly efficient CO 2 capture . Nat. Commun. , 2017 . 8 2107 DOI: 10.1038/s41467-017-02318-1 http://doi.org/10.1038/s41467-017-02318-1 .

Zhang, Y. F.; Han, D.; Zhao, Y. H.; Bai, S. L. . High-performance thermal interface materials consisting of vertically aligned graphene film and polymer . Carbon , 2016 . 109 552 - 557 . DOI: 10.1016/j.carbon.2016.08.051 http://doi.org/10.1016/j.carbon.2016.08.051 .

Zhang, P.; Li, J.; Lv, L.; Zhao, Y.; Qu, L. . Vertically aligned graphene sheets membrane for highly efficient solar thermal generation of clean water . ACS Nano , 2017 . 11 5087 - 5093 . DOI: 10.1021/acsnano.7b01965 http://doi.org/10.1021/acsnano.7b01965 .

Zhang, P.; Liu, F.; Liao, Q.; Yao, H.; Geng, H.; Cheng, H.; Li, C.; Qu, L. . A microstructured graphene/poly( N -isopropylacrylamide) membrane for intelligent solar water evaporation . Angew. Chem. Int. Ed. , 2018 . 57 16343 - 16347 . DOI: 10.1002/anie.201810345 http://doi.org/10.1002/anie.201810345 .

Xi, J.; Li, Y.; Zhou, E.; Liu, Y.; Gao, W.; Guo, Y.; Ying, J.; Chen, Z.; Chen, G.; Gao, C. . Graphene aerogel films with expansion enhancement effect of high-performance electromagnetic interference shielding . Carbon , 2018 . 135 44 - 51 . DOI: 10.1016/j.carbon.2018.04.041 http://doi.org/10.1016/j.carbon.2018.04.041 .

Zhou, E.; Xi, J.; Guo, Y.; Liu, Y.; Xu, Z.; Peng, L.; Gao, W.; Ying, J.; Chen, Z.; Gao, C. . Synergistic effect of graphene and carbon nanotube for high-performance electromagnetic interference shielding films . Carbon , 2018 . 133 316 - 322 . DOI: 10.1016/j.carbon.2018.03.023 http://doi.org/10.1016/j.carbon.2018.03.023 .

Xu, J.; Yuan, G.; Zhu, Q.; Wang, J.; Tang, S.; Gao, L. . Enhancing the strength of graphene by a denser grain boundary . ACS Nano , 2018 . 12 4529 - 4535 . DOI: 10.1021/acsnano.8b00869 http://doi.org/10.1021/acsnano.8b00869 .

Liu, R. Y.; Xu, A. W. . Byssal threads inspired ionic cross-linked narce-like graphene oxide paper with superior mechanical strength . RSC Adv. , 2014 . 4 40390 - 40395 . DOI: 10.1039/C4RA08319A http://doi.org/10.1039/C4RA08319A .

Li, P.; Yang, M.; Liu, Y.; Qin, H.; Liu, J.; Xu, Z.; Liu, Y.; Meng, F.; Lin, J.; Wang, F.; Gao, C. . Continuous crystalline graphene papers with gigapascal strength by intercalation modulated plasticization . Nat. Commun. , 2020 . 11 2645 DOI: 10.1038/s41467-020-16494-0 http://doi.org/10.1038/s41467-020-16494-0 .

Ranjbartoreh, A. R.; Wang, B.; Shen, X.; Wang, G. . Advanced mechanical properties of graphene paper . J. Appl. Phys. , 2011 . 109 014306 DOI: 10.1063/1.3528213 http://doi.org/10.1063/1.3528213 .

Gibson, L. J.; Ashby, M. F. Cellular solids: structure and properties . 2 Ed., Cambridge University Press, Cambridge, 1997 .

Sheng, L.; Liang, Y.; Jiang, L.; Wang, Q.; Wei, T.; Qu, L.; Fan, Z. . Bubble-decorated honeycomb-like graphene film as ultrahigh sensitivity pressure sensors . Adv. Funct. Mater. , 2015 . 25 6545 - 6551 . DOI: 10.1002/adfm.201502960 http://doi.org/10.1002/adfm.201502960 .

Huang, R.; Huang, M.; Li, X.; An, F.; Koratkar, N.; Yu, Z. Z. . Porous graphene films with unprecedented elastomeric scaffold-like folding behavior for foldable energy storage devices . Adv. Mater. , 2018 . 30 1707025 DOI: 10.1002/adma.201707025 http://doi.org/10.1002/adma.201707025 .

Qiu, L.; Liu, J. Z.; Chang, S. L. Y.; Wu, Y.; Li, D. . Biomimetic superelastic graphene-based cellular monoliths . Nat. Commun. , 2012 . 3 1241 DOI: 10.1038/ncomms2251 http://doi.org/10.1038/ncomms2251 .

Gao, H. L.; Zhu, Y. B.; Mao, L. B.; Wang, F. C.; Luo, X. S.; Liu, Y. Y.; Lu, Y.; Pan, Z.; Ge, J.; Shen, W.; Zheng, Y. R.; Xu, L.; Wang, L. J.; Xu, W. H.; Wu, H. A.; Yu, S. H. . Super-elastic and fatigue resistant carbon material with lamellar multi-arch microstructure . Nat. Commun. , 2016 . 7 12920 DOI: 10.1038/ncomms12920 http://doi.org/10.1038/ncomms12920 .

Yang, M.; Xu, Z.; Li, P.; Guo, F.; Liu, Y.; Xiao, Y.; Gao, W.; Gao, C. . Interlayer crosslinking to conquer the stress relaxation of graphene laminated materials . Mater. Horiz. , 2018 . 5 1112 - 1119 . DOI: 10.1039/C8MH00817E http://doi.org/10.1039/C8MH00817E .

Xu, J.; Chen, J.; Zhang, M.; Hong, J. D.; Shi, G. . Highly conductive stretchable electrodes prepared by in situ reduction of wavy graphene oxide films coated on elastic tapes . Adv. Electron. Mater. , 2016 . 2 1600022 DOI: 10.1002/aelm.201600022 http://doi.org/10.1002/aelm.201600022 .

Jagannadham, K. . Thermal conductivity of copper-graphene composite films synthesized by electrochemical deposition with exfoliated graphene platelets . Metall. Mater. Trans. B , 2012 . 43 316 - 324 . .

Long, Y.; Zhang, C.; Wang, X.; Gao, J.; Wang, W.; Liu, Y. . Oxidation of SO 2 to SO 3 catalyzed by graphene oxide foams . J. Mater. Chem. , 2011 . 21 13934 - 13941 . DOI: 10.1039/c1jm12031j http://doi.org/10.1039/c1jm12031j .

Xue, Y.; Yu, D.; Dai, L.; Wang, R.; Li, D.; Roy, A.; Lu, F.; Chen, H.; Liu, Y.; Qu, J. . Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction . Phys. Chem. Chem. Phys. , 2013 . 15 12220 - 12226 . DOI: 10.1039/c3cp51942b http://doi.org/10.1039/c3cp51942b .

Han, A.; Jin, S.; Chen, H.; Ji, H.; Sun, Z.; Du, P. . A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14 . J. Mater. Chem. A , 2015 . 3 1941 - 1946 . DOI: 10.1039/C4TA06071G http://doi.org/10.1039/C4TA06071G .

Worsley, M. A.; Pauzauskie, P. J.; Olson, T. Y.; Biener, J.; Satcher, J. H.; Baumann, T. F. . Synthesis of graphene aerogel with high electrical conductivity . J. Am. Chem. Soc. , 2010 . 132 14067 - 14069 . DOI: 10.1021/ja1072299 http://doi.org/10.1021/ja1072299 .

Wang, Z. L.; Xu, D.; Xu, J. J.; Zhang, L. L.; Zhang, X. B. . Graphene oxide gel-derived, free-standing, hierarchically porous carbon for high-capacity and high-rate rechargeable Li-O 2 batteries . Adv. Funct. Mater. , 2012 . 22 3699 - 3705 . DOI: 10.1002/adfm.201200403 http://doi.org/10.1002/adfm.201200403 .

Chen, J.; Sheng, K.; Luo, P.; Li, C.; Shi, G. . Graphene hydrogels deposited in nickel foams for high-rate electrochemical capacitors . Adv. Mater. , 2012 . 24 4569 - 4573 . DOI: 10.1002/adma.201201978 http://doi.org/10.1002/adma.201201978 .

Hu, G.; Xu, C.; Sun, Z.; Wang, S.; Cheng, H. M.; Li, F.; Ren, W. . 3D graphene-foam-reduced-graphene-oxide hybrid nested hierarchical networks for high-performance Li-S batteries . Adv. Mater. , 2016 . 28 1603 - 1609 . DOI: 10.1002/adma.201504765 http://doi.org/10.1002/adma.201504765 .

Huang, Y.; Huang, X. L.; Lian, J. S.; Xu, D.; Wang, L. M.; Zhang, X. B. . Self-assembly of ultrathin porous NiO nanosheets/graphene hierarchical structure for high-capacity and high-rate lithium storage . J. Mater. Chem. , 2012 . 22 2844 - 2847 . DOI: 10.1039/c2jm15865e http://doi.org/10.1039/c2jm15865e .

He, Y.; Zhang, N.; Wu, F.; Xu, F.; Liu, Y.; Gao, J. . Graphene oxide foams and their excellent adsorption ability for acetone gas . Mater. Res. Bull. , 2013 . 48 3553 - 3558 . DOI: 10.1016/j.materresbull.2013.05.056 http://doi.org/10.1016/j.materresbull.2013.05.056 .

Lei, Y.; Chen, F.; Luo, Y.; Zhang, L. . Three-dimensional magnetic graphene oxide foam/Fe 3 O 4 nanocomposite as an efficient absorbent for Cr(VI) removal . J. Mater. Sci. , 2014 . 49 4236 - 4245 . DOI: 10.1007/s10853-014-8118-2 http://doi.org/10.1007/s10853-014-8118-2 .

Niu, Z.; Chen, J.; Hng, H. H.; Ma, J.; Chen, X. . A leavening strategy to prepare reduced graphene oxide foams . Adv. Mater. , 2012 . 24 4144 - 4150 . DOI: 10.1002/adma.201200197 http://doi.org/10.1002/adma.201200197 .

Dong, X. C.; Xu, H.; Wang, X. W.; Huang, Y. X.; Chan-Park, M. B.; Zhang, H.; Wang, L. H.; Huang, W.; Chen, P. . 3D graphene-cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection . ACS Nano , 2012 . 6 3206 - 3213 . DOI: 10.1021/nn300097q http://doi.org/10.1021/nn300097q .

Xi, J.; Liu, Y.; Wu, Y.; Hu, J.; Gao, W.; Zhou, E.; Chen, H.; Chen, Z.; Chen, Y.; Gao, C. . Multifunctional bicontinuous composite foams with ultralow percolation thresholds . ACS Appl. Mater. Interfaces , 2018 . 10 20806 - 20815 . DOI: 10.1021/acsami.8b06017 http://doi.org/10.1021/acsami.8b06017 .

Yao, H.; Zhang, P.; Huang, Y.; Cheng, H.; Li, C.; Qu, L. . Highly efficient clean water production from contaminated air with a wide humidity range . Adv. Mater. , 2020 . 32 1905875 DOI: 10.1002/adma.201905875 http://doi.org/10.1002/adma.201905875 .

Huang, Y.; Cheng, H.; Yang, C.; Zhang, P.; Liao, Q.; Yao, H.; Shi, G.; Qu, L. . Interface-mediated hygroelectric generator with an output voltage approaching 1.5 volts . Nat. Commun. , 2018 . 9 4166 DOI: 10.1038/s41467-018-06633-z http://doi.org/10.1038/s41467-018-06633-z .

Ren, H.; Tang, M.; Guan, B.; Wang, K.; Yang, J.; Wang, F.; Wang, M.; Shan, J.; Chen, Z.; Wei, D.; Peng, H.; Liu, Z. . Hierarchical graphene foam for efficient omnidirectional solar-thermal energy conversion . Adv. Mater. , 2017 . 29 1702590 DOI: 10.1002/adma.201702590 http://doi.org/10.1002/adma.201702590 .

Zhang, L.; Li, R.; Tang, B.; Wang, P. . Solar-thermal conversion and thermal energy storage of graphene foam-based composites . Nanoscale , 2016 . 8 14600 - 14607 . DOI: 10.1039/C6NR03921A http://doi.org/10.1039/C6NR03921A .

Qi, G.; Yang, J.; Bao, R.; Xia, D.; Cao, M.; Yang, W.; Yang, M.; Wei, D. . Hierarchical graphene foam-based phase change materials with enhanced thermal conductivity and shape stability for efficient solar-to-thermal energy conversion and storage . Nano Res. , 2017 . 10 802 - 813 . DOI: 10.1007/s12274-016-1333-1 http://doi.org/10.1007/s12274-016-1333-1 .

Chang, Q.; Ma, Z.; Wang, J.; Li, P.; Yan, Y.; Shi, W.; Chen, Q.; Huang, Y.; Huang, L. . Hybrid graphene quantum dots@graphene foam nanosheets for dye-sensitized solar cell electrodes . Energy Technol. , 2016 . 4 256 - 262 . DOI: 10.1002/ente.201500194 http://doi.org/10.1002/ente.201500194 .

Wang, Y.; Li, H.; Kong, J. . Facile preparation of mesocellular graphene foam for direct glucose oxidase electrochemistry and sensitive glucose sensing . Sens. Actuators B , 2014 . 193 708 - 714 . DOI: 10.1016/j.snb.2013.11.105 http://doi.org/10.1016/j.snb.2013.11.105 .

Kuang, J.; Liu, L.; Gao, Y.; Zhou, D.; Chen, Z.; Han, B.; Zhang, Z. . A hierarchically structured graphene foam and its potential as a large-scale strain-gauge sensor . Nanoscale , 2013 . 5 12171 - 12177 . DOI: 10.1039/c3nr03379a http://doi.org/10.1039/c3nr03379a .

Jeong, Y. R.; Park, H.; Jin, S. W.; Hong, S. Y.; Lee, S. S.; Ha, J. S. . Highly stretchable and sensitive strain sensors using fragmentized graphene foam . Adv. Funct. Mater. , 2015 . 25 4228 - 4236 . DOI: 10.1002/adfm.201501000 http://doi.org/10.1002/adfm.201501000 .

Peng, L.; Zheng, Y.; Li, J.; Jin, Y.; Gao, C. . Monolithic neat graphene oxide aerogel for efficient catalysis of S→O acetyl migration . ACS Catal. , 2015 . 5 3387 - 3392 . DOI: 10.1021/acscatal.5b00233 http://doi.org/10.1021/acscatal.5b00233 .

Chen, C.; Xi, J.; Zhou, E.; Peng, L.; Chen, Z.; Gao, C. . Porous graphene microflowers for high-performance microwave absorption . Nano-Micro Lett. , 2017 . 10 26 .

Chen, C.; Xi, J.; Han, Y.; Peng, L.; Gao, W.; Xu, Z.; Gao, C. . Ultralight graphene micro-popcorns for multifunctional composite applications . Carbon , 2018 . 139 545 - 555 . DOI: 10.1016/j.carbon.2018.07.020 http://doi.org/10.1016/j.carbon.2018.07.020 .

Xi, J.; Zhou, E.; Liu, Y.; Gao, W.; Ying, J.; Chen, Z.; Gao, C. . Wood-based straightway channel structure for high performance microwave absorption . Carbon , 2017 . 124 492 - 498 . DOI: 10.1016/j.carbon.2017.07.088 http://doi.org/10.1016/j.carbon.2017.07.088 .

Li, Z.; Xu, Z.; Liu, Y.; Wang, R.; Gao, C. . Multifunctional non-woven fabrics of interfused graphene fibres . Nat. Commun. , 2016 . 7 13684 DOI: 10.1038/ncomms13684 http://doi.org/10.1038/ncomms13684 .

Li, Z.; Huang, T.; Gao, W.; Xu, Z.; Chang, D.; Zhang, C.; Gao, C. . Hydrothermally activated graphene fiber fabrics for textile electrodes of supercapacitors . ACS Nano , 2017 . 11 11056 - 11065 . DOI: 10.1021/acsnano.7b05092 http://doi.org/10.1021/acsnano.7b05092 .

Kinloch, I. A.; Suhr, J.; Lou, J.; Young, R. J.; Ajayan, P. M. . Composites with carbon nanotubes and graphene: an outlook . Science , 2018 . 362 547 DOI: 10.1126/science.aat7439 http://doi.org/10.1126/science.aat7439 .

Li, K.; Liu, J.; Huang, Y.; Bu, F.; Xu, Y. . Integration of ultrathin graphene/polyaniline composite nanosheets with a robust 3D graphene framework for highly flexible all-solid-state supercapacitors with superior energy density and exceptional cycling stability . J. Mater. Chem. A , 2017 . 5 5466 - 5474 . DOI: 10.1039/C6TA11224B http://doi.org/10.1039/C6TA11224B .

Zhang, Q.; Zhou, A.; Wang, J.; Wu, J.; Bai, H. . Degradation-induced capacitance: a new insight into the superior capacitive performance of polyaniline/graphene composites . Energy Environ. Sci. , 2017 . 10 2372 - 2382 . DOI: 10.1039/C7EE02018J http://doi.org/10.1039/C7EE02018J .

Wu, J.; Zhang, Q.; Zhou, A.; Huang, Z.; Bai, H.; Li, L. . Phase-separated polyaniline/graphene composite electrodes for high-rate electrochemical supercapacitors . Adv. Mater. , 2016 . 28 10211 - 10216 . DOI: 10.1002/adma.201601153 http://doi.org/10.1002/adma.201601153 .

Wu, J.; Zhang, Q. E.; Wang, J.; Huang, X.; Bai, H. . A self-assembly route to porous polyaniline/reduced graphene oxide composite materials with molecular-level uniformity for high-performance supercapacitors . Energy Environ. Sci. , 2018 . 11 1280 - 1286 . DOI: 10.1039/C8EE00078F http://doi.org/10.1039/C8EE00078F .

Boland, C. S.; Khan, U.; Ryan, G.; Barwich, S.; Charifou, R.; Harvey, A.; Backes, C.; Li, Z.; Ferreira, M. S.; Möbius, M. E.; Young, R. J.; Coleman, J. N. . Sensitive electromechanical sensors using viscoelastic graphene-polymer nanocomposites . Science , 2016 . 354 1257 - 1260 . DOI: 10.1126/science.aag2879 http://doi.org/10.1126/science.aag2879 .

Zhang, M.; Yu, X.; Ma, H.; Du, W.; Qu, L.; Li, C.; Shi, G. . Robust graphene composite films for multifunctional electrochemical capacitors with an ultrawide range of areal mass loading toward high-rate frequency response and ultrahigh specific capacitance . Energy Environ. Sci. , 2018 . 11 559 - 565 . DOI: 10.1039/C7EE03349D http://doi.org/10.1039/C7EE03349D .

Zhao, J.; Zhu, Y.; Pan, F.; He, G.; Fang, C.; Cao, K.; Xing, R.; Jiang, Z. . Fabricating graphene oxide-based ultrathin hybrid membrane for pervaporation dehydration via layer-by-layer self-assembly driven by multiple interactions . J. Membr. Sci. , 2015 . 487 162 - 172 . DOI: 10.1016/j.memsci.2015.03.073 http://doi.org/10.1016/j.memsci.2015.03.073 .

He, G.; He, X.; Wang, X.; Chang, C.; Zhao, J.; Li, Z.; Wu, H.; Jiang, Z. . A highly proton-conducting, methanol-blocking Nafion composite membrane enabled by surface-coating crosslinked sulfonated graphene oxide . Chem. Commun. , 2016 . 52 2173 - 2176 . DOI: 10.1039/C5CC07406A http://doi.org/10.1039/C5CC07406A .

Stankovich, S.; Dikin, D. A.; Dommett, G. H. B.; Kohlhaas, K. M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff, R. S. . Graphene-based composite materials . Nature , 2006 . 442 282 - 286 . DOI: 10.1038/nature04969 http://doi.org/10.1038/nature04969 .

Li, D.; Kaner, R. B. . Graphene-based materials . Science , 2008 . 320 1170 DOI: 10.1126/science.1158180 http://doi.org/10.1126/science.1158180 .

Hu, M.; Mi, B. . Layer-by-layer assembly of graphene oxide membranes via electrostatic interaction . J. Membr. Sci. , 2014 . 469 80 - 87 . DOI: 10.1016/j.memsci.2014.06.036 http://doi.org/10.1016/j.memsci.2014.06.036 .

Yang, D.; Zhao, J.; Shi, J.; Wang, X.; Zhang, S.; Jiang, Z. . Combination of redox assembly and biomimetic mineralization to prepare graphene-based composite cellular foams for versatile catalysis . ACS Appl. Mater. Interfaces , 2017 . 9 43950 - 43958 . DOI: 10.1021/acsami.7b11601 http://doi.org/10.1021/acsami.7b11601 .

Vickery, J. L.; Patil, A. J.; Mann, S. . Fabrication of graphene-polymer nanocomposites with higher-order three-dimensional architectures . Adv. Mater. , 2009 . 21 2180 - 2184 . DOI: 10.1002/adma.200803606 http://doi.org/10.1002/adma.200803606 .

Yun, Y. J.; Hong, W. G.; Kim, W. J.; Jun, Y.; Kim, B. H. . A novel method for applying reduced graphene oxide directly to electronic textiles from yarns to fabrics . Adv. Mater. , 2013 . 25 5701 - 5705 . DOI: 10.1002/adma.201303225 http://doi.org/10.1002/adma.201303225 .

Hu, R.; He, Y.; Huang, M.; Zhao, G.; Zhu, H. . Strong adhesion of graphene oxide coating on polymer separation membranes . Langmuir , 2018 . 34 10569 - 10579 . DOI: 10.1021/acs.langmuir.8b02342 http://doi.org/10.1021/acs.langmuir.8b02342 .

Chen, T.; Wang, S.; Wu, Z.; Wang, X.; Peng, J.; Wu, B.; Cui, J.; Fang, X.; Xie, Y.; Zheng, N. . A cake making strategy to prepare reduced graphene oxide wrapped plant fiber sponges for high-efficiency solar steam generation . J. Mater. Chem. A , 2018 . 6 14571 - 14576 . DOI: 10.1039/C8TA04420A http://doi.org/10.1039/C8TA04420A .

Krishnamoorthy, K.; Navaneethaiyer, U.; Mohan, R.; Lee, J.; Kim, S. J. . Graphene oxide nanostructures modified multifunctional cotton fabrics . Appl. Nanosci. , 2012 . 2 119 - 126 . DOI: 10.1007/s13204-011-0045-9 http://doi.org/10.1007/s13204-011-0045-9 .

Fugetsu, B.; Sano, E.; Yu, H.; Mori, K.; Tanaka, T. . Graphene oxide as dyestuffs for the creation of electrically conductive fabrics . Carbon , 2010 . 48 3340 - 3345 . DOI: 10.1016/j.carbon.2010.05.016 http://doi.org/10.1016/j.carbon.2010.05.016 .

Niu, Z.; Liu, L.; Zhang, L.; Shao, Q.; Zhou, W.; Chen, X.; Xie, S. . A universal strategy to prepare functional porous graphene hybrid architectures . Adv. Mater. , 2014 . 26 3681 - 3687 . DOI: 10.1002/adma.201400143 http://doi.org/10.1002/adma.201400143 .

Yang, S.; Bachman, R. E.; Feng, X.; Müllen, K. . Use of organic precursors and graphenes in the controlled synthesis of carbon-containing nanomaterials for energy storage and conversion . Acc. Chem. Res. , 2013 . 46 116 - 128 . DOI: 10.1021/ar3001475 http://doi.org/10.1021/ar3001475 .

Chen, K.; Chen, L.; Chen, Y.; Bai, H.; Li, L. . Three-dimensional porous graphene-based composite materials: electrochemical synthesis and application . J. Mater. Chem. , 2012 . 22 20968 - 20976 . DOI: 10.1039/c2jm34816k http://doi.org/10.1039/c2jm34816k .

Qiu, B.; Xing, M.; Zhang, J. . Mesoporous TiO 2 nanocrystals grown in situ on graphene aerogels for high photocatalysis and lithium-ion batteries . J. Am. Chem. Soc. , 2014 . 136 5852 - 5855 . DOI: 10.1021/ja500873u http://doi.org/10.1021/ja500873u .

Dai, Y.; Jing, Y.; Zeng, J.; Qi, Q.; Wang, C.; Goldfeld, D.; Xu, C.; Zheng, Y.; Sun, Y. . Nanocables composed of anatase nanofibers wrapped in UV-light reduced graphene oxide and their enhancement of photoinduced electron transfer in photoanodes . J. Mater. Chem. , 2011 . 21 18174 - 18179 . DOI: 10.1039/c1jm13641k http://doi.org/10.1039/c1jm13641k .

Tong, Z.; Yang, D.; Shi, J.; Nan, Y.; Sun, Y.; Jiang, Z. . Three-dimensional porous aerogel constructed by g-C 3 N 4 and graphene oxide nanosheets with excellent visible-light photocatalytic performance . ACS Appl. Mater. Interfaces , 2015 . 7 25693 - 25701 . DOI: 10.1021/acsami.5b09503 http://doi.org/10.1021/acsami.5b09503 .

Kong, L.; Yin, X.; Zhang, Y.; Yuan, X.; Li, Q.; Ye, F.; Cheng, L.; Zhang, L. . Electromagnetic wave absorption properties of reduced graphene oxide modified by maghemite colloidal nanoparticle clusters . J. Phys. Chem. C , 2013 . 117 19701 - 19711 . DOI: 10.1021/jp4058498 http://doi.org/10.1021/jp4058498 .

Hu, C.; Mou, Z.; Lu, G.; Chen, N.; Dong, Z.; Hu, M.; Qu, L. . 3D graphene-Fe 3 O 4 nanocomposites with high-performance microwave absorption . Phys. Chem. Chem. Phys. , 2013 . 15 13038 - 13043 . DOI: 10.1039/c3cp51253c http://doi.org/10.1039/c3cp51253c .

Liu, P.; Huang, Y.; Yan, J.; Yang, Y.; Zhao, Y. . Construction of CuS nanoflakes vertically aligned on magnetically decorated graphene and their enhanced microwave absorption properties . ACS Appl. Mater. Interfaces , 2016 . 8 5536 - 5546 . DOI: 10.1021/acsami.5b10511 http://doi.org/10.1021/acsami.5b10511 .

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