Scalable Reaction-spinning of Rigid-rod Upilex-S<sup>®</sup> Type Polyimide Fiber with an Ultrahigh <italic style="font-style: italic">T</italic><sub>g</sub>

Sen-Sen Zheng; Han Dong; Shi-Hua Wang; Jie Dong; Tao Guo; Xin Zhao; Qing-Hua Zhang

doi:10.1007/s10118-021-2508-0

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Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g

ARTICLE | Updated：2020-10-13

- Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g
- Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g
- Chinese Journal of Polymer Science 2021年39卷第5期页码：592-600
- Affiliations：
  
  a.Shanghai Collaborative Innovation Center for High Performance Fiber Composites, Engineering Research Center of Technical Textiles, Ministry of Education, Donghua University, Shanghai 201620, China
  b.Jiangsu Aoshen Hi-Tech Materials Co., Ltd., Lianyungang 222000, China
- Author bio：
  
  dj01@dhu.edu.cn (J.D.)
  qhzhang@dhu.edu.cn (Q.H.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51903038, 21774019, and 21975040), the Program of Shanghai Academic Research Leader (No. 18XD1400100) and the Scientific Research Innovation Plan of Shanghai Education Commission (No. 2019-01-07-00-03-E00001).
- DOI：10.1007/s10118-021-2508-0
  中图分类号：
- 收稿：2020-08-26，
  
  修回：2020-9-8，
  
  录用：2020-9-14，
  
  网络首发：2020-10-13，
  
  纸质出版：2021-01-01
- Accepted：
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Zheng, S. S.; Dong, H.; Wang, S. H.; Dong, J.; Guo, T.; Zhao, X.; Zhang, Q. H. Scalable reaction-spinning of rigid-rod Upilex-S^® type polyimide fiber with an ultrahigh , T,_g. Chinese J. Polym. Sci. 2021, 39, 592–600 DOI: 10.1007/s10118-021-2508-0.

Sen-Sen Zheng, Han Dong, Shi-Hua Wang, et al. Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g[J]. Chinese Journal of Polymer Science, 2021, 39(5): 592-600. DOI: 10.1007/s10118-021-2508-0.
Zheng, S. S.; Dong, H.; Wang, S. H.; Dong, J.; Guo, T.; Zhao, X.; Zhang, Q. H. Scalable reaction-spinning of rigid-rod Upilex-S^® type polyimide fiber with an ultrahigh , T,_g. Chinese J. Polym. Sci. 2021, 39, 592–600 DOI: 10.1007/s10118-021-2508-0. DOI：

Sen-Sen Zheng, Han Dong, Shi-Hua Wang, et al. Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g[J]. Chinese Journal of Polymer Science, 2021, 39(5): 592-600. DOI: 10.1007/s10118-021-2508-0. DOI：

摘要

Abstract

In the family of polyimide (PI) materials

Upilex-S

film has been a shining star through the research PI materials due to its appealing merits. Unfortunately

the wholly rigid-rod backbone and easily formed skin-core micromorphology and microvoids of Upilex-S

type PI lead to the high difficulty in melt- and wet-spinning fabrication. Herein

we propose a facile and scalable method

reaction-spinning

to fabricate the Upilex-S

type PI fiber

in which the rapid solidification of spinning dope and partial imidization take place simultaneously. Thus

the stability and mechanical strength of as-spun fibers can be improved

and the microvoids in fibers can be greatly reduced in relative to the wet-spun fibers. The resultant Upilex-S

type PI fiber shows higher tensile strength and modulus than most commercial thermal-oxidative polymeric fibers with an ultrahigh glass transition temperature

of 478 °C. Moreover

the WAXS and SAXS results indicate that orthorhombic crystals are formed for Upilex-S

type PI fiber in the post hot-drawing process. Increasing the hot-drawing temperature results in a continuous crystallization and high orientation of PI chains in amorphous phase and perfects the existing lamellar structure

which make a great contribution to the improved mechanical property.

关键词

Keywords

references

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Scalable Reaction-spinning of Rigid-rod Upilex-S® Type Polyimide Fiber with an Ultrahigh Tg

Scalable Reaction-spinning of Rigid-rod Upilex-S® Type Polyimide Fiber with an Ultrahigh Tg

DOI：10.1007/s10118-021-2508-0

摘要

Abstract

关键词

Keywords

references

Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g

Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g