a.Shanghai Collaborative Innovation Center for High Performance Fiber Composites, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
b.Sinochem International Corporation, Shanghai 200126, China
yjr@dhu.edu.cn
收稿:2020-05-09,
修回:2020-8-21,
录用:2020-9-9,
网络首发:2020-10-16,
纸质出版:2021-01-02
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Fan, L. L.; Quan, J. Y.; Zhang, H.; Yu, J. R.; Hu, Z. M.; Wang, Y. Preparation of hydrophilic UHMWPE hollow fiber membranes by chemically bounding silica nanoparticles. Chinese J. Polym. Sci. 2021, 39, 189–200
Lian-Lian Fan, Jia-You Quan, Hao Zhang, et al. Preparation of Hydrophilic UHMWPE Hollow Fiber Membranes by Chemically Bounding Silica Nanoparticles[J]. Chinese Journal of Polymer Science, 2021, 39(2): 189-200.
Fan, L. L.; Quan, J. Y.; Zhang, H.; Yu, J. R.; Hu, Z. M.; Wang, Y. Preparation of hydrophilic UHMWPE hollow fiber membranes by chemically bounding silica nanoparticles. Chinese J. Polym. Sci. 2021, 39, 189–200 DOI: 10.1007/s10118-021-2507-1.
Lian-Lian Fan, Jia-You Quan, Hao Zhang, et al. Preparation of Hydrophilic UHMWPE Hollow Fiber Membranes by Chemically Bounding Silica Nanoparticles[J]. Chinese Journal of Polymer Science, 2021, 39(2): 189-200. DOI: 10.1007/s10118-021-2507-1.
In this work
ultra-high molecular weight polyethylene (UHMWPE) microfiltration hollow fiber membranes prepared
via
the thermally induced phase separation (TIPS) method were modified by chemically bounding hydrophilic silica (SiO
2
) nanoparticles onto the surface to improve anti-fouling performance. A range of testing techniques including attenuated total reflection Flourier transformed infrared spectroscopy (ATR-FTIR)
X-ray photoelectron spectroscopy (XPS)
field emission scanning electron microscopy (FE-SEM)
water contact angle
mechanical test
filtration and anti-fouling performance were carried out to discuss the influence of different modification conditions on the properties of the membranes. The prepared hollow fiber membranes display the significantly excellent performance when the vinyl trimethoxy silane (VTMS) concentration was 13%
the pH value of the hydrolyzate was 4 and the hydrolysis reaction time was 6 h. In particular
the hydrophilicity of modified membranes was improved effectively
resulting in the enhancement of membrane anti-fouling properties. The results of this work can be consulted for improving the anti-fouling performance of the UHMWPE microfiltration hollow fiber membrane applied in the field of water purification.
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