Platinum Atoms Dispersed in Single-chain Polymer Nanoparticles

Zhi-Yu Hu; Hong-Ting Pu; Jian-Guo Wu

doi:10.1007/s10118-021-2499-x

Your Location：

Home >

Browse articles >

Platinum Atoms Dispersed in Single-chain Polymer Nanoparticles

ARTICLE | Updated：2020-09-18

- Platinum Atoms Dispersed in Single-chain Polymer Nanoparticles
- Platinum Atoms Dispersed in Single-chain Polymer Nanoparticles
- Chinese Journal of Polymer Science 2021年39卷第4期页码：441-446
- Affiliations：
  
  a.Department of Polymeric Materials, School of Materials Science & Engineering, Tongji University, Shanghai 201804, China
  b.Key Laboratory of Advanced Civil Engineering Materials, School of Materials Science & Engineering, Tongji University, Shanghai 201804, China
- Author bio：
  
  puhongting@tongji.edu.cn
- Funds：
  
  This work was financially supported by the Fundamental Research Funds for the Central Universities (China) (No. 0500219216) and the National Natural Science Foundation of China (No. 21144006).
- DOI：10.1007/s10118-021-2499-x
  中图分类号：
- 收稿：2020-08-03，
  
  修回：2020-8-22，
  
  录用：2020-8-31，
  
  网络首发：2020-09-18，
  
  纸质出版：2021-01-01
- Accepted：
Scan QR Code
Hu, Z. Y.; Pu, H. T.; Wu, J. G. Platinum atoms dispersed in single-chain polymer nanoparticles. Chinese J. Polym. Sci. 2021, 39, 441–446

Zhi-Yu Hu, Hong-Ting Pu, Jian-Guo Wu. Platinum Atoms Dispersed in Single-chain Polymer Nanoparticles[J]. Chinese Journal of Polymer Science, 2021, 39(4): 441-446.
Hu, Z. Y.; Pu, H. T.; Wu, J. G. Platinum atoms dispersed in single-chain polymer nanoparticles. Chinese J. Polym. Sci. 2021, 39, 441–446 DOI： 10.1007/s10118-021-2499-x.

Zhi-Yu Hu, Hong-Ting Pu, Jian-Guo Wu. Platinum Atoms Dispersed in Single-chain Polymer Nanoparticles[J]. Chinese Journal of Polymer Science, 2021, 39(4): 441-446. DOI： 10.1007/s10118-021-2499-x.

摘要

Abstract

The intramolecular cross-linking of single polymer chains can form single-chain nanoparticles (SCNPs)

which have many applications. In this study

styrenic copolymers with pendent triphenylphosphine as the coordination site for platinum ions (Pt(II)) and benzocyclobutene as the latent reactive groups are synthesized. Triphenylphosphine groups in the chains can coordinate Pt(II) and aid slight single-chain folding in dilute solution. The intramolecular cross-linking caused by the ring-open reaction of benzocyclobutene completes the single-chain collapse and forms stable SCNPs in dilute solution. Pt(II) embedded in SCNPs can be further reduced to platinum atoms (Pt(0)). Pt(0) steadily and atomically dispersed in SCNPs exhibits better catalytic properties than normal polymer carried platinum particles do for the reduction of

-nitrophenol to

-aminophenol.

关键词

Keywords

references

Zhang, O.; Yu, H. M.; Lu, L. M.; Wen, Y. P.; Duan, X. M. . Poly(thiophene-3-acetic acid)-palladium nanoparticle composite modified electrodes for supersensitive determination of hydrazine . Chinese J. Polym. Sci. , 2013 . 31 419 - 426 . DOI: 10.1007/s10118-013-1230-y http://doi.org/10.1007/s10118-013-1230-y .

Xu, Q. L.; Li, H. X.; Wang, G. C. . Preparation of polyalkylcyanoacrylate nanoparticles with various morphologies . Chinese J. Polym. Sci. , 2011 . 29 336 - 341 . DOI: 10.1007/s10118-011-1033-y http://doi.org/10.1007/s10118-011-1033-y .

Li, Q. L.; Li, L.; Wang, H. S.; Wang, R.; Wang, W.; Jiang, Y. J.; Tian, Q.; Liu, J. P. . The doubly thermo-responsive triblock copolymer nanoparticles prepared through seeded RAFT polymerization . Chinese J. Polym. Sci. , 2017 . 35 66 - 77 . DOI: 10.1007/s10118-016-1859-4 http://doi.org/10.1007/s10118-016-1859-4 .

Ormategui, N.; Zhang, S. W.; Loinaz, I.; Brydson, R.; Nelson, A.; Vakurov, A. . Interaction of poly( N -isopropylacrylamide) (pNIPAM) based nanoparticles and their linear polymer precursor with phospholipid membrane models . Bioelectrochemistry , 2012 . 87 211 - 219 . DOI: 10.1016/j.bioelechem.2011.12.006 http://doi.org/10.1016/j.bioelechem.2011.12.006 .

Knoefel, N. D.; Rothfuss, H.; Barner-Kowollik, C.; Roesky, P. W. . $$ {{\rm{M}}_{2}^{4+}} $$ http://notExist.jpg paddlewheel clusters as junction points in single-chain nanoparticles . Polym. Chem. , 2019 . 10 86 - 93 . DOI: 10.1039/C8PY01486H http://doi.org/10.1039/C8PY01486H .

Willenbacher, J.; Altintas, O.; Trouillet, V.; Knöfel, N.; Monteiro, M. J.; Roesky, P. W.; Barner-Kowollik, C. . Pd-complex driven formation of single-chain nanoparticles . Polym. Chem. , 2015 . 6 4358 - 4365 . DOI: 10.1039/C5PY00389J http://doi.org/10.1039/C5PY00389J .

Rubio-Cervilla, J.; Gonzalez, E.; Pomposo, J. A. . Advances in single-chain nanoparticles for catalysis applications . Nanomaterials , 2017 . 7 341 DOI: 10.3390/nano7100341 http://doi.org/10.3390/nano7100341 .

Kroger, A. P. P.; Paulusse, J. M. J. . Single-chain polymer nanoparticles in controlled drug delivery and targeted imaging . J. Control. Release , 2018 . 286 326 - 347 . DOI: 10.1016/j.jconrel.2018.07.041 http://doi.org/10.1016/j.jconrel.2018.07.041 .

Kroger, A. P. P.; Hamelmann, N. M.; Juan, A.; Lindhoud, S.; Paulusse, J. M. J. . Biocompatible single-chain polymer nanoparticles for drug delivery a dual approach . ACS Appl. Mater. Interfaces , 2018 . 10 30946 - 30951 . DOI: 10.1021/acsami.8b07450 http://doi.org/10.1021/acsami.8b07450 .

Kilic, D.; Pamukcu, C.; Balta, D. K.; Temel, B. A.; Temel, G. . Rapid synthesis of fluorescent single-chain nanoparticles via photoinduced step-growth polymerization of pendant carbazole units . Eur. Polym. J. , 2020 . 125 109469 DOI: 10.1016/j.eurpolymj.2019.109469 http://doi.org/10.1016/j.eurpolymj.2019.109469 .

Fu, C. L.; Sun, Z. Y.; An, L. J. . The properties of a single polymer chain in solvent confined in a slit: a molecular dynamics simulation . Chinese J. Polym. Sci. , 2012 . 31 388 - 398 . .

Tuten, B. T.; Chao, D. M.; Lyon, C. K.; Berda, E. B. . Single-chain polymer nanoparticles via reversible disulfide bridges . Polym. Chem. , 2012 . 3 3068 - 3071 . DOI: 10.1039/c2py20308a http://doi.org/10.1039/c2py20308a .

Ana, S. S.; Fulton, D. A.; Pomposo, J. A. . pH-responsive single-chain polymer nanoparticles utilising dynamic covalent enamine bonds . Chem. Commun. , 2014 . 50 1871 - 1874 . DOI: 10.1039/C3CC48733D http://doi.org/10.1039/C3CC48733D .

Wang, F.; Pu, H. T.; Che, X. . Voltage-responsive single-chain polymer nanoparticles via host-guest interaction . Chem. Commun. , 2016 . 52 3516 - 3519 . DOI: 10.1039/C5CC09984F http://doi.org/10.1039/C5CC09984F .

Zhu, Z. G.; Xu, N.; Yu, Q. P.; Guo, L.; Cao, H.; Lu, X. H.; Cai, Y. L. . Construction and self-assembly of single-chain polymer nanoparticles via coordination association and electrostatic repulsion in water . Macromol. Rapid Commun. , 2015 . 36 1521 - 1527 . DOI: 10.1002/marc.201500281 http://doi.org/10.1002/marc.201500281 .

Wang, F.; Zhang, J. Q.; Ding, X.; Dong, S. Y.; Liu, M.; Zheng, B.; Li, S. J.; Wu, L.; Yu, Y. H. ; Gibson, W.; Huang, F. H. . Metal coordination mediated reversible conversion between linear and cross-linked supramolecular polymers . Angew. Chem. Int. Ed. , 2010 . 49 1090 - 1094 . DOI: 10.1002/anie.200906389 http://doi.org/10.1002/anie.200906389 .

Fischer, T. S.; Spann, S.; An, Q.; Luy, B.; Tsotsalas, M.; Blinco, J. P.; Mutlu, H.; Barner-Kowollik, C. . Self-reporting and refoldable profluorescent single-chain nanoparticles . Chem. Sci. , 2018 . 9 4696 - 4702 . DOI: 10.1039/C8SC01009A http://doi.org/10.1039/C8SC01009A .

Willenbacher, J.; Wuest, K. N. R.; Mueller, J. O.; Kaupp, M.; Wagenknech, H. A.; Barner-Kowollik, C. . Photochemical design of functional fluorescent single-chain nanoparticles . ACS Macro Lett. , 2014 . 3 574 - 579 . DOI: 10.1021/mz500292e http://doi.org/10.1021/mz500292e .

Rubio-Cervilla, J.; M. De Molina, P.; Robles-Hernandez, B.; Arbe, A.; Moreno, A.; Alegria, A.; Colmenero, J.; Pomposo, J. A. . Facile access to completely deuterated single-chain nanoparticles enabled by intramolecular azide photodecomposition . Macromol. Rapid Commun. , 2019 . 40 e1900046 DOI: 10.1002/marc.201900046 http://doi.org/10.1002/marc.201900046 .

Saha, R.; Sekar, G. . Selective oxidation of alkylarenes to aromatic acids/ketone in water by using reusable binaphthyl stabilized Pt nanoparticles (Pt-BNP) as catalyst . Appl. Catal. B-Environ. , 2019 . 250 325 - 336 . DOI: 10.1016/j.apcatb.2019.03.052 http://doi.org/10.1016/j.apcatb.2019.03.052 .

De-La-Cuesta, J.; Gonzalez, E.; Pomposo, J. A. . Advances in fluorescent single-chain nanoparticles . Molecules , 2017 . 22 1819 DOI: 10.3390/molecules22111819 http://doi.org/10.3390/molecules22111819 .

Croce, T. A.; Hamilton, S. K.; Chen, M. L.; Muchalski, H.; Harth, E. . Alternative o -quinodimethane cross-linking precursors for intramolecular chain collapse nanoparticles . Macromolecules , 2007 . 40 6028 - 6031 . DOI: 10.1021/ma071111m http://doi.org/10.1021/ma071111m .

Prasher, A.; Loynd, C. M.; Tuten, B. T.; Frank, P. G.; Chao, D. M.; Berda, E. B. . Efficient fabrication of polymer nanoparticles via sonogashira cross-linking of linear polymers in dilute solution . J. Polym. Sci., Part A: Polym. Chem. , 2016 . 54 209 - 217 . DOI: 10.1002/pola.27942 http://doi.org/10.1002/pola.27942 .

Asenjo-Sanz, I.; Verde-Sesto, E.; Pomposo, J. A. . Valuable structure-size relationships for tadpole-shaped single-chain nanoparticles with long and short flexible tails unveiled . Phys. Chem. Chem. Phys. , 2019 . 21 10884 - 10887 . DOI: 10.1039/C9CP01318K http://doi.org/10.1039/C9CP01318K .

Wang, P.; Pu, H. T.; Jin, M. . Single-chain nanoparticles with well-defined structure via intramolecular crosslinking of linear polymers with pendant benzoxazine groups . J. Polym. Sci., Part A: Polym. Chem. , 2011 . 49 5133 - 5141 . DOI: 10.1002/pola.25003 http://doi.org/10.1002/pola.25003 .

Knofel, N. D.; Rothfuss, H.; Willenbacher, J.; Barner-Kowollik, C.; Roesky, P. W. . Platinum(II)-crosslinked single-chain nanoparticles: an approach towards recyclable homogeneous catalysts . Angew. Chem. Int. Ed. , 2017 . 56 4950 - 4954 . DOI: 10.1002/anie.201700718 http://doi.org/10.1002/anie.201700718 .

Wang, F.; Pu, H. T.; Jin, M.; Wan, D. C. . Supramolecular nanoparticles via single-chain folding driven by ferrous ions . Macromol. Rapid Commun. , 2016 . 37 330 - 336 . DOI: 10.1002/marc.201500616 http://doi.org/10.1002/marc.201500616 .

Pomposo, J. A. . Bioinspired single-chain polymer nanoparticles . Polym. Int. , 2014 . 63 589 - 592 . DOI: 10.1002/pi.4671 http://doi.org/10.1002/pi.4671 .

Liu, Y. L.; Turunen, P.; De Waal, B. F. M.; Blank, K. G.; Rowan, A. E.; Palmans, A. R. A.; Meijer, E. W. . Catalytic single-chain polymeric nanoparticles at work: from ensemble towards single-particle kinetics . Mol. Syst. Des. Eng. , 2018 . 3 609 - 618 . DOI: 10.1039/C8ME00017D http://doi.org/10.1039/C8ME00017D .

Harth, E.; Van Horn, B.; Lee, V. Y.; Germack, D. S.; Gonzales, C. P.; Miller, R. D.; Hawker, C. J. . A facile approach to architecturally defined nanoparticles via intramolecular chain collapse . J. Am. Chem. Soc. , 2002 . 124 8653 - 8660 . DOI: 10.1021/ja026208x http://doi.org/10.1021/ja026208x .

Zhu, L. P.; Yi, Z.; Liu, F.; Wei, X. Z.; Zhu, B. K.; Xu, Y. Y. . Amphiphilic graft copolymers based on ultrahigh molecular weight poly(styrene- alt -maleic anhydride) with poly(ethylene glycol) side chains for surface modification of polyethersulfone membranes . Eur. Polym. J. , 2008 . 44 1907 - 1914 . DOI: 10.1016/j.eurpolymj.2008.03.015 http://doi.org/10.1016/j.eurpolymj.2008.03.015 .

Harrisson, S.; Wooley, K. L. . Shell-crosslinked nanostructures from amphiphilic AB and ABA block copolymers of styrene- alt -(maleic anhydride) and styrene: polymerization, assembly and stabilization in one pot . Chem. Commun. , 2005 . 26 3259 - 3261 . .

Tuteja, A.; Mackay, M. E.; Hawker, C. J.; van Horn, B.; Ho, D. L. . Molecular architecture and rheological characterization of novel intramolecularly crosslinked polystyrene nanoparticles . J. Polym. Sci., Part B: Polym. Phys. , 2010 . 44 1930 - 1947 . .

Kim, Y.; Pyun, J.; Frechet, J. M. J.; Hawker, C. J.; Frank, C. W. . The dramatic effect of architecture on the self-assembly of block copolymers at interfaces . Langmuir , 2005 . 21 10444 - 10458 . DOI: 10.1021/la047122f http://doi.org/10.1021/la047122f .

Dirlam, P. T.; Kim, H. J.; Arrington, K. J.; Chung, W. J.; Sahoo, R.; Hill, L. J.; Costanzo, P. J.; Theato, P.; Char, K.; Pyun, J. . Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization . Polym. Chem. , 2013 . 4 3765 - 3773 . DOI: 10.1039/c3py00321c http://doi.org/10.1039/c3py00321c .

Mei, Y.; Sharma, G.; Lu, Y.; Ballauff, M.; Drechsler, M.; Irrgang, T.; Kempe, R. . High catalytic activity of platinum nanoparticles immobilized on spherical polyelectrolyte brushes . Langmuir , 2005 . 21 12229 - 12234 . DOI: 10.1021/la052120w http://doi.org/10.1021/la052120w .

Nie, R. F.; Liang, D.; Shen, L.; Gao, J.; Chen, P.; Hou, Z. Y. . Selective oxidation of glycerol with oxygen in base-free solution over MWCNTs supported PtSb alloy nanoparticles . Appl. Catal. B-Environ. , 2012 . 127 212 - 220 . DOI: 10.1016/j.apcatb.2012.08.026 http://doi.org/10.1016/j.apcatb.2012.08.026 .

Wunder, S.; Polzer, F.; Lu, Y.; Mei, Y.; Ballauff, M. . Kinetic analysis of catalytic reduction of 4-nitrophenol by metallic nanoparticles immobilized in spherical polyelectrolyte brushes . J. Phys. Chem. C , 2010 . 114 8814 - 8820 . DOI: 10.1021/jp101125j http://doi.org/10.1021/jp101125j .

浏览量

103

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination

Enhanced Electron Transfer Ability via Coordination in Block Copolymer/Porphyrin/Fullerene Micelle

The Influence of Rare Earth Ions on the Rheological Behavior of Polyamide

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast