Conductive Film with Flexible and Stretchable Capability for Sensor Application and Stealth Information Transmission

Yi-Fei Shan; Kun Yang; Zhi-Xi Li; Xiao-Xiao Wang; Hao Li; Yong-Yan Cui

doi:10.1007/s10118-020-2483-x

Your Location：

Home >

Browse articles >

Conductive Film with Flexible and Stretchable Capability for Sensor Application and Stealth Information Transmission

ARTICLE | Updated：2020-09-11

- Conductive Film with Flexible and Stretchable Capability for Sensor Application and Stealth Information Transmission
- Conductive Film with Flexible and Stretchable Capability for Sensor Application and Stealth Information Transmission
- Chinese Journal of Polymer Science 2021年39卷第2期页码：164-173
- Affiliations：
  
  a.College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, China
  b.Institute of Molecular Aggregation Science, Tianjin University, Tianjin 300072, China
- Author bio：
  
  yangkun1463@126.com (K.Y.)
  cyy@tust.edu.cn (Y.Y.C.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51403115). The authors would like to thank Mr. Ang Li and Prof. Huige Wei for the guidance of electrical signal tests of this study.
- DOI：10.1007/s10118-020-2483-x
  中图分类号：
- 收稿：2020-06-11，
  
  修回：2020-7-14，
  
  录用：2020-7-20，
  
  网络首发：2020-09-11，
  
  纸质出版：2021-01-02
- Accepted：
Scan QR Code
Shan, Y. F.; Yang, K.; Li, Z. X.; Wang, X. X.; Li, H.; Cui, Y. Y. Conductive film with flexible and stretchable capability for sensor application and stealth information transmission. Chinese J. Polym. Sci. 2021, 39, 164–173

Yi-Fei Shan, Kun Yang, Zhi-Xi Li, et al. Conductive Film with Flexible and Stretchable Capability for Sensor Application and Stealth Information Transmission[J]. Chinese Journal of Polymer Science, 2021, 39(2): 164-173.
Shan, Y. F.; Yang, K.; Li, Z. X.; Wang, X. X.; Li, H.; Cui, Y. Y. Conductive film with flexible and stretchable capability for sensor application and stealth information transmission. Chinese J. Polym. Sci. 2021, 39, 164–173 DOI： 10.1007/s10118-020-2483-x.

Yi-Fei Shan, Kun Yang, Zhi-Xi Li, et al. Conductive Film with Flexible and Stretchable Capability for Sensor Application and Stealth Information Transmission[J]. Chinese Journal of Polymer Science, 2021, 39(2): 164-173. DOI： 10.1007/s10118-020-2483-x.

摘要

Abstract

Flexible and wearable strain sensors for human-computer interaction

health monitoring

and soft robotics have drawn widespread attention to promising applications in the next generation of artificial intelligence devices. However

conventional semiconductor sensors are difficult to meet the requirements of flexibility and stretchability. Here

we reported a kind of novel and simple sensor based on layer-by-layer (LBL) method. Carbon nanotubes (CNTs) layer provides high ductility and stability in the process of tension sensing

while silver layer provides low initial resistance and fast reflecting in the process of tension sensing. LBL method ensures the uniformity of the conductive layer. The sensor has superior sheet resistance of 9.44 Ω/sq.

high elongation at break of 104%. For sensing capability

the sensor has wide reflecting range of 60%

high gauge factor (GF) of 1000 up to 60% strain

fast reflecting time of 165 ms. Excellent reliability and stability have also been verified. It is also worth mentioning that the entire process does not require any expensive equipments

complicated processes or harsh experimental conditions. The above features provide an idea for large-scale application of flexible stretchable sensors.

关键词

Keywords

references

Zhang, Z. F.; Yang, K.; Zhao, S. G.; Guo, L. N. . Self-healing behavior of ethylene propylene diene rubbers based on ionic association . Chinese J. Polym. Sci. , 2019 . 37 700 - 707 . DOI: 10.1007/s10118-019-2241-0 http://doi.org/10.1007/s10118-019-2241-0 .

Ryu, S.; Lee, P.; Chou, J. B.; Xu, R.; Zhao, R.; Hart, A. J.; Kim, S. G. . Extremely elastic wearable carbon nanotube fiber strain sensor for monitoring of human motion . ACS Nano , 2015 . 9 5929 DOI: 10.1021/acsnano.5b00599 http://doi.org/10.1021/acsnano.5b00599 .

Chen, X.; Sun, P.; Liu, H. . Hierarchically crosslinked gels containing hydrophobic ionic liquids towards reliable sensing applications . Chinese J. Polym. Sci. , 2020 . 38 332 - 341 . .

Lin, S.; Zhao, X.; Jiang, X.; Wu, A.; Ding, H.; Zhong, Y.; Li, J.; Pan, J.; Liu, B.; Zhu, H. . Highly stretchable, adaptable, and durable strain sensing based on a bioinspired dynamically cross-linked graphene/polymer composite . Small , 2019 . 15 e1900848 DOI: 10.1002/smll.201900848 http://doi.org/10.1002/smll.201900848 .

Ma, Y.; Zhang, Y.; Cai, S.; Han, Z.; Liu, X.; Wang, F.; Cao, Y.; Wang, Z.; Li, H.; Chen, Y.; Feng, X. . Flexible hybrid electronics for digital healthcare . Adv. Mater. , 2019 . 1902062 DOI: 10.1002/adma.201902062 http://doi.org/10.1002/adma.201902062 .

Han, Y.; Wu, X.; Zhang, X.; Lu, C. . Archimedean spiral inspired conductive supramolecular elastomer with rapid electrical and mechanical self-healing capability for sensor application . Adv. Mater. Technol. , 2019 . 4 1800424 DOI: 10.1002/admt.201800424 http://doi.org/10.1002/admt.201800424 .

Yu, G. H.; Han, Q.; Qu, L. T. . Graphene fibers: advancing applications in sensor, energy storage and conversion . Chinese J. Polym. Sci. , 2019 . 37 535 - 547 . DOI: 10.1007/s10118-019-2245-9 http://doi.org/10.1007/s10118-019-2245-9 .

Ma, W. L.; Cai, Z. H.; Zhang, Y.; Wang, Z. Y.; Xia, L.; Ma, S. P.; Li, G. H.; Huang, Y. . An overview of stretchable supercapacitors based on carbon nanotube and graphene . Chinese J. Polym. Sci. , 2020 . 38 491 - 505 . DOI: 10.1007/s10118-020-2386-x http://doi.org/10.1007/s10118-020-2386-x .

Yang, X.; Liu, J.; Fan, D.; Cao, J.; Huang, X.; Zheng, Z.; Zhang, X. . Scalable manufacturing of real-time self-healing strain sensors based on brominated natural rubber . Chem. Eng. J. , 2020 . 389 124448 DOI: 10.1016/j.cej.2020.124448 http://doi.org/10.1016/j.cej.2020.124448 .

Jian, M.; Zhang, Y.; Liu, Z. . Natural biopolymers for flexible sensing and energy devices . Chinese J. Polym. Sci. , 2020 . 38 459 - 490 . DOI: 10.1007/s10118-020-2379-9 http://doi.org/10.1007/s10118-020-2379-9 .

Wang, C.; Xia, K.; Wang, H.; Liang, X.; Yin, Z.; Zhang, Y. . Advanced carbon for flexible and wearable electronics . Adv. Mater. , 2019 . 31 1801072 DOI: 10.1002/adma.201801072 http://doi.org/10.1002/adma.201801072 .

Liao, X.; Song, W.; Zhang, X.; Yan, C.; Li, T.; Ren, H.; Liu, C.; Wang, Y.; Zheng, Y. . A bioinspired analogous nerve towards artificial intelligence . Nat. Commun. , 2020 . 11 268 DOI: 10.1038/s41467-019-14214-x http://doi.org/10.1038/s41467-019-14214-x .

Zhang, M.; Wang, C.; Wang, Q.; Jian, M.; Zhang, Y. . Sheath-core graphite/silk fiber made by dry-meyer-rod-coating for wearable strain sensors . ACS Appl. Mater. Interfaces , 2016 . 8 20894 DOI: 10.1021/acsami.6b06984 http://doi.org/10.1021/acsami.6b06984 .

Li, Z.; Shan, Y.; Wang, X.; Li, H.; Yang, K.; Cui, Y. . Self-healing flexible sensor based on metal-ligand coordination . Chem. Eng. J. , 2020 . 394 124932 DOI: 10.1016/j.cej.2020.124932 http://doi.org/10.1016/j.cej.2020.124932 .

Wan, Y.; Qiu, Z.; Huang, J.; Yang, J.; Wang, Q.; Lu, P.; Yang, J.; Zhang, J.; Huang, S.; Wu, Z.; Guo, C. F. . Natural plant materials as dielectric layer for highly sensitive flexible electronic skin . Small , 2018 . 14 e1801657 DOI: 10.1002/smll.201801657 http://doi.org/10.1002/smll.201801657 .

Liu, Q.; Liu, Z.; Li, C.; Xie, K.; Zhu, P.; Shao, B.; Zhang, J.; Yang, J.; Zhang, J.; Wang, Q.; Guo, C. F. . Highly transparent and flexible iontronic pressure sensors based on an opaque to transparent transition . Adv. Sci. , 2020 . 2000348 .

Mo, Y. L.; Tian, Y. X.; Liu, Y. H.; Chen, F.; Fu, Q. . Preparation and properties of ultrathin flexible expanded graphite film via adding natural rubber . Chinese J. Polym. Sci. , 2019 . 37 806 - 814 . DOI: 10.1007/s10118-019-2264-6 http://doi.org/10.1007/s10118-019-2264-6 .

Xu, J.; Wu, H. C.; Zhu, C.; Ehrlich, A.; Shaw, L.; Nikolka, M.; Wang, S.; Molina-Lopez, F.; Gu, X.; Luo, S.; Zhou, D.; Kim, Y. H.; Wang, G. N.; Gu, K.; Feig, V. R.; Chen, S.; Kim, Y.; Katsumata, T.; Zheng, Y. Q.; Yan, H.; Chung, J. W.; Lopez, J.; Murmann, B.; Bao, Z. . Multi-scale ordering in highly stretchable polymer semiconducting films . Nat. Mater. , 2019 . 18 594 DOI: 10.1038/s41563-019-0340-5 http://doi.org/10.1038/s41563-019-0340-5 .

Lei, T.; Shao, L. L.; Zheng, Y. Q.; Pitner, G.; Fang, G.; Zhu, C.; Li, S.; Beausoleil, R.; Wong, H. P.; Huang, T. C.; Cheng, K. T.; Bao, Z. . Low-voltage high-performance flexible digital and analog circuits based on ultrahigh-purity semiconducting carbon nanotubes . Nat. Commun. , 2019 . 10 2161 DOI: 10.1038/s41467-019-10145-9 http://doi.org/10.1038/s41467-019-10145-9 .

Liu, X.; Su, G.; Guo, Q.; Lu, C.; Zhou, T.; Zhou, C.; Zhang, X. . Hierarchically structured self-healing sensors with tunable positive/negative piezoresistivity . Adv. Funct. Mater. , 2018 . 28 1706658 DOI: 10.1002/adfm.201706658 http://doi.org/10.1002/adfm.201706658 .

Liang, Y.; Xiao, P.; Wang, S.; Shi, J.; He, J.; Zhang, J.; Huang, Y.; Chen, T. . Scalable fabrication of free-standing, stretchable CNT/TPE ultrathin composite films for skin adhesive epidermal electronics . J. Mater. Chem. C , 2018 . 6 6666 DOI: 10.1039/C8TC00711J http://doi.org/10.1039/C8TC00711J .

Zhu, G. J.; Ren, P. G.; Guo, H.; Jin, Y. L.; Yan, D. X.; Li, Z. M. . Highly sensitive and stretchable polyurethane fiber strain sensors with embedded silver nanowires . ACS Appl. Mater. Interfaces , 2019 . 11 23649 DOI: 10.1021/acsami.9b08611 http://doi.org/10.1021/acsami.9b08611 .

Jheng, L. C.; Hsiao, C. H.; Ko, W. C.; Hsu, S. L.; Huang, Y. L. . Conductive films based on sandwich structures of carbon nanotubes/silver nanowires for stretchable interconnects . Nanotechnology , 2019 . 30 235201 DOI: 10.1088/1361-6528/ab0483 http://doi.org/10.1088/1361-6528/ab0483 .

Guo, C. F.; Chen, Y.; Tang, L.; Wang, F.; Ren, Z. . Enhancing the scratch resistance by introducing chemical bonding in highly stretchable and transparent electrodes . Nano Lett. , 2016 . 16 594 DOI: 10.1021/acs.nanolett.5b04290 http://doi.org/10.1021/acs.nanolett.5b04290 .

Guo, C. F.; Sun, T.; Liu, Q.; Suo, Z.; Ren, Z. . Highly stretchable and transparent nanomesh electrodes made by grain boundary lithography . Nat. Commun. , 2014 . 5 3121 DOI: 10.1038/ncomms4121 http://doi.org/10.1038/ncomms4121 .

Liu, B.; Tang, H.; Luo, Z.; Zhang, W.; Tu, Q.; Jin, X. . Wearable carbon nanotubes-based polymer electrodes for ambulatory electrocardiographic measurements . Sens. Actuators A , 2017 . 265 79 DOI: 10.1016/j.sna.2017.08.036 http://doi.org/10.1016/j.sna.2017.08.036 .

Qin, R.; Liu, Y.; Tao, F.; Li, C.; Cao, W.; Yang, P. . Protein-bound freestanding 2D metal film for stealth information transmission . Adv. Mater. , 2019 . 31 1803377 DOI: 10.1002/adma.201803377 http://doi.org/10.1002/adma.201803377 .

浏览量

113

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Highly Stretchable and Conductive Hybrid Fibers for High-performance Fibrous Electrodes and All-solid-state Supercapacitors

Sodium Carboxymethyl Cellulose/Polypyrrole Nanoparticle-doped Conductive Hydrogel for Self-powered Flexible Strain Sensors and Signal Transmission

Ultralong Sodium Alginate-based Room/High-temperature Phosphorescence Materials with Color-tunability and Flexibility

Multifunctional Property Enhancement of 2-Acrylamido-2-methyl-1-propanesulfonic Acid/Acrylic Acid Hydrogels with Dual-ionic Liquid Functionalized Carbon Nanotubes

Silk Sericin-inspired Poly-β-homoserine for Protein Protection