a.Research Branch of Advanced Functional Materials, School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 610054, China
b.School of Chemical Engineering, Northwest University, Xi’an 710069, China
weirb10@uestc.edu.cn (R.B.W.)
liuxb@uestc.edu.cn (X.B.L)
收稿:2020-05-10,
修回:2020-7-5,
录用:2020-7-13,
网络首发:2020-09-02,
纸质出版:2021-01-02
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Wei, R. B.; Zhan, C. H.; Yang, Y.; He, P. L.; Liu, X. B. Polyarylene ether nitrile and titanium dioxide hybrids as thermal resistant dielectrics. Chinese J. Polym. Sci. 2021, 39, 211–218
Ren-Bo Wei, Chen-Hao Zhan, Yang Yang, et al. Polyarylene Ether Nitrile and Titanium Dioxide Hybrids as Thermal Resistant Dielectrics[J]. Chinese Journal of Polymer Science, 2021, 39(2): 211-218.
Wei, R. B.; Zhan, C. H.; Yang, Y.; He, P. L.; Liu, X. B. Polyarylene ether nitrile and titanium dioxide hybrids as thermal resistant dielectrics. Chinese J. Polym. Sci. 2021, 39, 211–218 DOI: 10.1007/s10118-020-2481-z.
Ren-Bo Wei, Chen-Hao Zhan, Yang Yang, et al. Polyarylene Ether Nitrile and Titanium Dioxide Hybrids as Thermal Resistant Dielectrics[J]. Chinese Journal of Polymer Science, 2021, 39(2): 211-218. DOI: 10.1007/s10118-020-2481-z.
With the expanding application of capacitors
thermal resistant dielectric materials are in high demand due to the increasing harsh environments where the capacitors are needed and the heat generated by the capacitors. Herein
we present polyarylene ether nitrile and titanium dioxide hybrids which can be used as thermal resistant dielectrics for these capacitors. Phthalonitrile modified titanium dioxide (TiO
2
-CN) and phthalonitrile end-capped polyarylene ether nitrile (PEN-Ph) are firstly prepared. After being cast into TiO
2
-CN/PEN nanocomposite films
these composites self-crosslink upon heating at 320 °C for 4 h
forming the polyarylene ether nitrile and titanium dioxide hybrids (TiO
2
-PEN). Improved dielectric constants which are stable from room temperature to 200 °C of these hybrids are observed
indicating the potential application of the hybrids as thermal resistant dielectrics.
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