Enhanced Reproducibility of Positive Temperature Coefficient Effect of CB/HDPE/PVDF Composites with the Addition of Ionic Liquid

Long Chen; Xiao Wu; Xiao-Fang Zhang; Jian-Ming Zhang

doi:10.1007/s10118-020-2475-x

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Enhanced Reproducibility of Positive Temperature Coefficient Effect of CB/HDPE/PVDF Composites with the Addition of Ionic Liquid

ARTICLE | Updated：2020-09-01

- Enhanced Reproducibility of Positive Temperature Coefficient Effect of CB/HDPE/PVDF Composites with the Addition of Ionic Liquid
- Enhanced Reproducibility of Positive Temperature Coefficient Effect of CB/HDPE/PVDF Composites with the Addition of Ionic Liquid
- Chinese Journal of Polymer Science 2021年39卷第2期页码：228-236
- Affiliations：
  
  Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-plastics, Qingdao University of Science & Technology, Qingdao 266042, China
- Author bio：
  
  zjm@qust.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51803103 and 21873059) and Taishan Mountain Scholar Foundation (Nos. TS20081120 and tshw20110510).
- DOI：10.1007/s10118-020-2475-x
  中图分类号：
- 收稿：2020-04-28，
  
  修回：2020-6-4，
  
  录用：2020-6-29，
  
  网络首发：2020-09-01，
  
  纸质出版：2021-01-02
- Accepted：
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Chen, L.; Wu, X.; Zhang, X. F.; Zhang, J. M. Enhanced reproducibility of positive temperature coefficient effect of CB/HDPE/PVDF composites with the addition of ionic liquid. Chinese J. Polym. Sci. 2021, 39, 228–236

Long Chen, Xiao Wu, Xiao-Fang Zhang, et al. Enhanced Reproducibility of Positive Temperature Coefficient Effect of CB/HDPE/PVDF Composites with the Addition of Ionic Liquid[J]. Chinese Journal of Polymer Science, 2021, 39(2): 228-236.
Chen, L.; Wu, X.; Zhang, X. F.; Zhang, J. M. Enhanced reproducibility of positive temperature coefficient effect of CB/HDPE/PVDF composites with the addition of ionic liquid. Chinese J. Polym. Sci. 2021, 39, 228–236 DOI： 10.1007/s10118-020-2475-x.

Long Chen, Xiao Wu, Xiao-Fang Zhang, et al. Enhanced Reproducibility of Positive Temperature Coefficient Effect of CB/HDPE/PVDF Composites with the Addition of Ionic Liquid[J]. Chinese Journal of Polymer Science, 2021, 39(2): 228-236. DOI： 10.1007/s10118-020-2475-x.

摘要

Abstract

Developing an effective method for improving the reproducibility of positive temperature coefficient (PTC) effect is of great significance for large-scale application of polymer based PTC composites

owing to its contribution to the security and reliability. Herein

we developed a carbon black (CB)/high density polyethylene (HDPE)/poly(vinylidene fluoride) (PVDF) composite with outstanding PTC reproducibility

by incorporating 1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([OMIm][NTf

]) into the composite. After multiple repeated temperature cycles

the PTC performance of as-prepared material keeps almost unchanged and the varition of resistance at room temperature is less than 7%. Our studies revealed that [OMIm]

[NTf

] contributes to the improvement of PTC reproducibility in two ways: (i) it acts as an efficient plasticizer for refining the co-continuous phase morphology of HDPE/PVDE blends; (ii) it inhibits the crystallization of PVDF through the dilution effect

leading to more overlaps of the volume shrinkage process of HDPE and PVDF melt which results in the decrease of interface gap between HDPE and PVDF. This study demonstrated that ionic liquids as the multifunctional agents have great potential for improving the reproducibility in the application of the binary polymer based PTC composites.

关键词

Keywords

references

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