Highly Stretchable, Compressible, Adhesive, Conductive Self-healing Composite Hydrogels with Sensor Capacity

Ji-Jun Wang; Qiang Zhang; Xing-Xiang Ji; Li-Bin Liu

doi:10.1007/s10118-020-2472-0

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Highly Stretchable, Compressible, Adhesive, Conductive Self-healing Composite Hydrogels with Sensor Capacity

ARTICLE | Updated：2020-08-27

- Highly Stretchable, Compressible, Adhesive, Conductive Self-healing Composite Hydrogels with Sensor Capacity
- Highly Stretchable, Compressible, Adhesive, Conductive Self-healing Composite Hydrogels with Sensor Capacity
- Chinese Journal of Polymer Science 2020年38卷第11期页码：1221-1229
- Affiliations：
  
  State Key Laboratory of Biobased Material and Green Papermaking, School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China
- Author bio：
  
  lbliu@qlu.edu.cn
- Funds：
  
  This work was financially supported by the Introduction and Cultivation Plan of Young Innovative Talents in Colleges and Universities of Shandong Province, the Shandong Key R&D Program (No. 2019GSF109050), Research Leader Foundation of “20 Policies of Colleges and Universities” of Jinan City (No. 2018GXRC027), and the National Natural Science Foundation of China (No. 31670590).
- DOI：10.1007/s10118-020-2472-0
  中图分类号：
- 收稿：2020-03-03，
  
  修回：2020-6-4，
  
  录用：2020-6-23，
  
  网络首发：2020-08-27，
  
  纸质出版：2020-08-14
- Accepted：
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Wang, J. J.; Zhang, Q.; Ji, X. X.; Liu, L. B. Highly stretchable, compressible, adhesive, conductive self-healing composite hydrogels with sensor capacity. Chinese J. Polym. Sci. 2020, 38, 1221–1229

Ji-Jun Wang, Qiang Zhang, Xing-Xiang Ji, et al. Highly Stretchable, Compressible, Adhesive, Conductive Self-healing Composite Hydrogels with Sensor Capacity[J]. Chinese Journal of Polymer Science, 2020, 38(11): 1221-1229.
Wang, J. J.; Zhang, Q.; Ji, X. X.; Liu, L. B. Highly stretchable, compressible, adhesive, conductive self-healing composite hydrogels with sensor capacity. Chinese J. Polym. Sci. 2020, 38, 1221–1229 DOI： 10.1007/s10118-020-2472-0.

Ji-Jun Wang, Qiang Zhang, Xing-Xiang Ji, et al. Highly Stretchable, Compressible, Adhesive, Conductive Self-healing Composite Hydrogels with Sensor Capacity[J]. Chinese Journal of Polymer Science, 2020, 38(11): 1221-1229. DOI： 10.1007/s10118-020-2472-0.

摘要

Abstract

The design and fabrication of conductive hydrogels with high stretchability

compressibility

self-healing properties and good adhesion remains a significant challenge. We have fabricated composite hydrogels by random polymerization of acrylic acid (AA) and dopamine (DA) in the presence of multi-walled carbon nanotubes (MWCNTs). The

interaction between DA and MWCNTs makes MWCNTs stably and homogenously dispersed in water. The fabricated PAA-PDA/CNT composite hydrogels possess relatively high mechanical strength (maximum Young’s modulus: 800 kPa) and can be stretched to 1280% strain and compressed to 80% strain. The multiple hydrogen bonding formed between functional groups of PAA-PDA and MWCNTs can effectively dissipate energy and quickly achieve self-healing. The composite hydrogels also show good adhesion and can easily adhere to various inorganic or organic surfaces. In addition

the hydrogel reveals stable strain sensitivity and can be used as skin sensors.

关键词

Keywords

references

Li, L.; Gu, L.; Lou, Z.; Fan, Z. . ZnO quantum dot decorated Zn 2 SnO 4 nanowire heterojunction photodetectors with drastic performance enhancement and flexible ultraviolet image sensors . ACS Nano , 2017 . 11 4067 - 4076 . DOI: 10.1021/acsnano.7b00749 http://doi.org/10.1021/acsnano.7b00749 .

Wang, C.; Sim, K.; Chen, J.; Kim, H. . Soft ultrathin electronics innervated adaptive fully soft robots . Adv. Mater. , 2018 . 30 1706695 DOI: 10.1002/adma.201706695 http://doi.org/10.1002/adma.201706695 .

Yang, T.; Xie, D.; Li, Z.; Zhu, H. . Recent advances in wearable tactile sensors: materials, sensing mechanisms, and device performance . Mater. Sci. Eng. R Rep. , 2017 . 115 1 - 37 . DOI: 10.1016/j.mser.2017.02.001 http://doi.org/10.1016/j.mser.2017.02.001 .

Wu, Z.; Zhang, B.; Zou, H.; Lin, Z. . Multifunctional sensor based on translational-rotary triboelectric nanogenerator . Adv. Energy Mater. , 2019 . 9 1901124 DOI: 10.1002/aenm.201901124 http://doi.org/10.1002/aenm.201901124 .

Shao, C.; Wang, M.; Meng, L.; Chang, H. . Mussel-inspired cellulose nanocomposite tough hydrogels with synergistic self-healing, adhesive, and strain-sensitive properties . Chem. Mater. , 2018 . 30 3110 - 3121 . DOI: 10.1021/acs.chemmater.8b01172 http://doi.org/10.1021/acs.chemmater.8b01172 .

Han, L.; Liu, K.; Wang, M.; Wang, K. . Mussel-inspired adhesive and conductive hydrogel with long-lasting moisture and extreme temperature tolerance . Adv. Funct. Mater. , 2018 . 28 1704195 DOI: 10.1002/adfm.201704195 http://doi.org/10.1002/adfm.201704195 .

Yang, B.; Yuan, W. . Highly stretchable and transparent double-network hydrogel ionic conductors as flexible thermal-mechanical dual sensors and electroluminescent devices . ACS Appl. Mater. Interfaces , 2019 . 11 16765 - 16775 . DOI: 10.1021/acsami.9b01989 http://doi.org/10.1021/acsami.9b01989 .

Zhang, S.; Zhang, Y.; Li, B.; Zhang, P. . One-step preparation of a highly stretchable, conductive, and transparent poly(vinyl alcohol)-phytic acid hydrogel for casual writing circuits . ACS Appl. Mater. Interfaces , 2019 . 11 32441 - 32448 . DOI: 10.1021/acsami.9b12626 http://doi.org/10.1021/acsami.9b12626 .

Zhou, Y.; Wan, C.; Yang, Y.; Yang, H. . Highly stretchable, elastic, and ionic conductive hydrogel for artificial soft electronics . Adv. Funct. Mater. , 2019 . 29 1806220 DOI: 10.1002/adfm.201806220 http://doi.org/10.1002/adfm.201806220 .

Wang, L.; Gao, G.; Zhou, Y.; Xu, T. . Tough, adhesive, self-healable, and transparent ionically conductive zwitterionic nanocomposite hydrogels as skin strain sensors . ACS Appl. Mater. Interfaces , 2018 . 11 3506 - 3515 . DOI: 10.1021/acsami.8b20755 http://doi.org/10.1021/acsami.8b20755 .

Ryplida, B.; Lee, K. D.; In, I.; Park, S. Y. . Light-induced swelling-responsive conductive, adhesive, and stretchable wireless film hydrogel as electronic artificial skin . Adv. Funct. Mater. , 2019 . 29 1903209 DOI: 10.1002/adfm.201903209 http://doi.org/10.1002/adfm.201903209 .

Liu, Y. J.; Cao, W. T.; Ma, M. G.; Wan, P. . Ultrasensitive wearable soft strain sensors of conductive, self-healing, and elastic hydrogels with synergistic “soft and hard” hybrid networks . ACS Appl. Mater. Interfaces , 2017 . 9 25559 - 25570 . DOI: 10.1021/acsami.7b07639 http://doi.org/10.1021/acsami.7b07639 .

Tong, R.; Chen, G.; Pan, D.; Qi, H. . Highly stretchable and compressible cellulose ionic hydrogels for flexible strain sensors . Biomacromolecules , 2019 . 20 2096 - 2104 . DOI: 10.1021/acs.biomac.9b00322 http://doi.org/10.1021/acs.biomac.9b00322 .

Liu, S.; Li, K.; Hussain, I.; Oderinde, O. . A conductive self-healing double network hydrogel with toughness and force sensitivity . Chem. Eur. J. , 2018 . 24 6632 - 6638 . DOI: 10.1002/chem.201800259 http://doi.org/10.1002/chem.201800259 .

Zhang, Q.; Liu, L.; Pan, C.; Li, D. . Thermally sensitive, adhesive, injectable, multiwalled carbon nanotube covalently reinforced polymer conductors with self-healing capabilities . J. Mater. Chem. C , 2018 . 6 1746 - 1752 . DOI: 10.1039/C7TC05432G http://doi.org/10.1039/C7TC05432G .

Kang, T. H.; Chang, H.; Choi, D.; Kim, S. . Hydrogel-templated transfer-printing of conductive nanonetworks for wearable sensors on topographic flexible substrates . Nano Lett. , 2019 . 19 3684 - 3691 . DOI: 10.1021/acs.nanolett.9b00764 http://doi.org/10.1021/acs.nanolett.9b00764 .

Ren, K.; Cheng, Y.; Huang, C.; Chen, R. . Self-healing conductive hydrogels based on alginate, gelatin and polypyrrole serve as a repairable circuit and a mechanical sensor . J. Mater. Chem. B , 2019 . 7 5704 - 5712 . DOI: 10.1039/C9TB01214A http://doi.org/10.1039/C9TB01214A .

Liao, M.; Wan, P.; Wen, J.; Gong, M. . Wearable, healable, and adhesive epidermal sensors assembled from mussel-inspired conductive hybrid hydrogel framework . Adv. Funct. Mater. , 2017 . 27 1703852 DOI: 10.1002/adfm.201703852 http://doi.org/10.1002/adfm.201703852 .

Ge, G.; Cai, Y.; Dong, Q.; Zhang, Y. . A flexible pressure sensor based on rGO/polyaniline wrapped sponge with tunable sensitivity for human motion detection . Nanoscale , 2018 . 10 10033 - 10040 . DOI: 10.1039/C8NR02813C http://doi.org/10.1039/C8NR02813C .

Jiang, D.; Liang, H.; Liu, Y.; Zheng, Y.; Li, C.; Yang, W.; Barrow, C. J.; Liu, J. . In situ generation of CoS 1.097 nanoparticles on S/N co-doped graphene/carbonized foam for mechanically tough and flexible all solid-state supercapacitors . J. Mater. Chem. A , 2018 . 6 11966 - 11977 . DOI: 10.1039/c8ta04307h http://doi.org/10.1039/c8ta04307h .

Chun, S.; Son, W.; Choi, C. . Flexible pressure sensors using highly-oriented and free-standing carbon nanotube sheets . Carbon , 2018 . 139 586 - 592 . DOI: 10.1016/j.carbon.2018.07.005 http://doi.org/10.1016/j.carbon.2018.07.005 .

Tong, L.; Wang, X. X.; He, X. X.; Nie, G. D. . Electrically conductive TPU nanofibrous composite with high stretchability for flexible strain sensor . Nanoscale Res. Lett. , 2018 . 13 1 - 8 . DOI: 10.1186/s11671-017-2411-3 http://doi.org/10.1186/s11671-017-2411-3 .

Dong, B.; Wang, Y.; Fang, G.; Han, N. . Smart releasing behavior of a chemical self-healing microcapsule in the stimulated concrete pore solution . Cem. Concr. Compos. , 2015 . 56 46 - 50 . DOI: 10.1016/j.cemconcomp.2014.10.006 http://doi.org/10.1016/j.cemconcomp.2014.10.006 .

Lai, G.; Chang, S.; Lee, J.; Liu, H. . Conductive microcapsules for self-healing electric circuits . RSC Adv. , 2015 . 5 104145 - 104148 . DOI: 10.1039/C5RA22021A http://doi.org/10.1039/C5RA22021A .

Casuso, P.; Odriozola, I.; Perez-San Vicente, A.; Loinaz, I.; Cabanero, G.; Grande, H. J.; Dupin, D. . Injectable and self-healing dynamic hydrogels based on metal (I)-thiolate/disulfide exchange as biomaterials with tunable mechanical properties . Biomacromolecules , 2015 . 16 3552 - 3561 . DOI: 10.1021/acs.biomac.5b00980 http://doi.org/10.1021/acs.biomac.5b00980 .

Haldar, U.; Bauri, K.; Li, R.; Faust, R. . Polyisobutylene-based pH-responsive self-healing polymeric gels . ACS Appl. Mater. Interfaces , 2015 . 7 8779 - 8788 . DOI: 10.1021/acsami.5b01272 http://doi.org/10.1021/acsami.5b01272 .

Taylor, D. L.; in het Panhuis, M. . Self-healing hydrogels . Adv. Mater. , 2016 . 28 9060 - 9093 . DOI: 10.1002/adma.201601613 http://doi.org/10.1002/adma.201601613 .

Pan, C.; Liu, L.; Chen, Q.; Zhang, Q. . Tough, stretchable, compressive novel polymer/graphene oxide nanocomposite hydrogels with excellent self-healing performance . ACS Appl. Mater. Interfaces , 2017 . 9 38052 - 38061 . DOI: 10.1021/acsami.7b12932 http://doi.org/10.1021/acsami.7b12932 .

Pan, C.; Wang, J.; Ji, X.; Liu, L. . Stretchable, compressible, self-healable carbon nanotube mechanically enhanced composite hydrogels with high strain sensitivity . J. Mater. Chem. C , 2020 . 8 1933 - 1942 . DOI: 10.1039/C9TC04853G http://doi.org/10.1039/C9TC04853G .

Zhou, B.; He, D.; Hu, J.; Ye, Y. . A flexible, self-healing and highly stretchable polymer electrolyte via quadruple hydrogen bonding for lithium-ion batteries . J. Mater. Chem. A , 2018 . 6 11725 - 11733 . DOI: 10.1039/C8TA01907J http://doi.org/10.1039/C8TA01907J .

Harada, A.; Takashima, Y.; Nakahata, M. . Supramolecular polymeric materials via cyclodextrin-guest interactions . Acc. Chem. Res. , 2014 . 47 2128 - 2140 . DOI: 10.1021/ar500109h http://doi.org/10.1021/ar500109h .

Chen, Q.; Yan, X.; Zhu, L.; Chen, H. . Improvement of mechanical strength and fatigue resistance of double network hydrogels by ionic coordination interactions . Chem. Mater. , 2016 . 28 5710 - 5720 . DOI: 10.1021/acs.chemmater.6b01920 http://doi.org/10.1021/acs.chemmater.6b01920 .

Tee, B. C.; Wang, C.; Allen, R.; Bao, Z. . An electrically and mechanically self-healing composite with pressure- and flexion-sensitive properties for electronic skin applications . Nat. Nanotechnol. , 2012 . 7 825 DOI: 10.1038/nnano.2012.192 http://doi.org/10.1038/nnano.2012.192 .

Han, L.; Yan, L.; Wang, K.; Fang, L. . Tough, self-healable and tissue-adhesive hydrogel with tunable multifunctionality . NPG Asia Mater. , 2017 . 9 e372 DOI: 10.1038/am.2017.33 http://doi.org/10.1038/am.2017.33 .

Shi, C.; Deng, C.; Zhang, X.; Yang, P. . Synthesis of highly water-dispersible polydopamine-modified multiwalled carbon nanotubes for matrix-assisted laser desorption/ionization mass spectrometry analysis . ACS Appl. Mater. Interfaces , 2013 . 5 7770 - 7776 . DOI: 10.1021/am4024143 http://doi.org/10.1021/am4024143 .

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