Cellulose Acetate Thermoplastics with High Modulus, Dimensional Stability and Anti-migration Properties by Using CA-<italic style="font-style: italic">g</italic>-PLA as Macromolecular Plasticizer

Ru-Meng Xu; Tian-Tian Yang; Elvira Vidović; Ruo-Nan Jia; Jin-Ming Zhang; Qin-Yong Mi; Jun Zhang

doi:10.1007/s10118-020-2470-2

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Cellulose Acetate Thermoplastics with High Modulus, Dimensional Stability and Anti-migration Properties by Using CA-g-PLA as Macromolecular Plasticizer

ARTICLE | Updated：2020-07-29

- Cellulose Acetate Thermoplastics with High Modulus, Dimensional Stability and Anti-migration Properties by Using CA-g-PLA as Macromolecular Plasticizer
- Cellulose Acetate Thermoplastics with High Modulus, Dimensional Stability and Anti-migration Properties by Using CA-g-PLA as Macromolecular Plasticizer
- Chinese Journal of Polymer Science 2020年38卷第10期页码：1141-1148
- Affiliations：
  
  a.CAS Key Laboratory of Engineering Plastics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
  c.Faculty of Chemical Engineering and Technology, University of Zagreb, Zagreb 10000, Croatia
- Author bio：
  
  † The authors contributed equally to this work
  evidov@fkit.hr (E.V.)
  zhjm@iccas.ac.cn (J.M.Z.)
  jzhang@iccas.ac.cn (J.Z.)
- Funds：
  
  This work was finacially supported by the National Key Research and Development Program of China (No. 2017YFA0403103), the Key Programs of the Chinese Academy of Sciences (No. ZDRW-CN-2018-2), and the Youth Innovation Promotion Association CAS (No. 2018040).
- DOI：10.1007/s10118-020-2470-2
  中图分类号： M
- 收稿：2020-05-18，
  
  修回：2020-6-14，
  
  录用：2020-6-15，
  
  网络首发：2020-07-29，
  
  纸质出版：2020-06-16
- Accepted：
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Xu, R. M.; Yang, T. T.; Vidović, E.; Jia, R. N.; Zhang, J. M.; Mi, Q. Y.; Zhang, J. Cellulose acetate thermoplastics with high modulus, dimensional stability and anti-migration properties by using CA-, g,-PLA as macromolecular plasticizer. Chinese J. Polym. Sci. 2020, 38, 1141–1148

Ru-Meng Xu, Tian-Tian Yang, Elvira Vidović, et al. Cellulose Acetate Thermoplastics with High Modulus, Dimensional Stability and Anti-migration Properties by Using CA-g-PLA as Macromolecular Plasticizer[J]. Chinese Journal of Polymer Science, 2020, 38(10): 1141-1148. DOI: 10.1007/s10118-020-2470-2.
Xu, R. M.; Yang, T. T.; Vidović, E.; Jia, R. N.; Zhang, J. M.; Mi, Q. Y.; Zhang, J. Cellulose acetate thermoplastics with high modulus, dimensional stability and anti-migration properties by using CA-, g,-PLA as macromolecular plasticizer. Chinese J. Polym. Sci. 2020, 38, 1141–1148 DOI： 10.1007/s10118-020-2470-2.

Ru-Meng Xu, Tian-Tian Yang, Elvira Vidović, et al. Cellulose Acetate Thermoplastics with High Modulus, Dimensional Stability and Anti-migration Properties by Using CA-g-PLA as Macromolecular Plasticizer[J]. Chinese Journal of Polymer Science, 2020, 38(10): 1141-1148. DOI: 10.1007/s10118-020-2470-2. DOI：

摘要

Abstract

Cellulose diacetate (CDA) can be melt-processed to produce numerous and widely-used plastic products. However

due to the high glass transition temperature (

) of CDA

the addition of up to 30 wt% of micromolecular plasticizers is indispensable

which significantly reduces the dimensional stability and raises safety concerns from the migration of plasticizers. In this work

a series of CDA-graft-poly(lactic acid) (CDA-

-PLA) copolymers were synthesized by ring-opening polymerization of lactide onto the hydroxyl groups of CDA. The resultant CDA-

-PLA copolymers possess adjustable degrees of substitution (DS

PLA

) and side chain length (DP

PLA

) by controlling the reaction time and feed ratio. The

s and thermal flow temperatures (

s) of CDA-

-PLA strongly depend on DP

PLA

such as the

s decrease linearly with the increase of DP

PLA

. The CDA-

-PLA copolymers with the DP

PLA

of 3−9 can be directly processed to transparent plastics by melt processing without any external plasticizers

because of their low

s of 170−215 °C. More impressively

the CDA-

-PLA can act as the macromolecular plasticizer. The obtained CDA/CDA-

-PLA has higher storage modulus

flexural modulus and Young's modulus than the commercial CDA plasticized with triethyl citrate. In addition

the CDA/CDA-

-PLA exhibits high dimensional stability and anti-migration property. During a long-term treatment at 80 °C and 60% humidity

the CDA/CDA-

-PLA can retain the initial shape. Therefore

this work not only proposes a facile method for achieving a direct thermoplastic processing of CDA

but also provides a macromolecular plasticizer for CDA to make lightweight

stable and safer biobased thermoplastics.

关键词

Keywords

references

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Cellulose Acetate Thermoplastics with High Modulus, Dimensional Stability and Anti-migration Properties by Using CA-g-PLA as Macromolecular Plasticizer

Cellulose Acetate Thermoplastics with High Modulus, Dimensional Stability and Anti-migration Properties by Using CA-g-PLA as Macromolecular Plasticizer

DOI：10.1007/s10118-020-2470-2

摘要

Abstract

关键词

Keywords

references