Transformation of Commodity Poly(hydroxyether of bisphenol A) into Vitrimers <italic style="font-style: italic">via</italic> Post Crosslinking with Hindered Urea Bonds

Hao Ding; Bingjie Zhao; Honggang Mei; Lei Li; Sixun Zheng

doi:10.1007/s10118-020-2457-z

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Transformation of Commodity Poly(hydroxyether of bisphenol A) into Vitrimers via Post Crosslinking with Hindered Urea Bonds

RAPID COMMUNICATION | Updated：2020-06-15

- Transformation of Commodity Poly(hydroxyether of bisphenol A) into Vitrimers via Post Crosslinking with Hindered Urea Bonds
- Transformation of Commodity Poly(hydroxyether of bisphenol A) into Vitrimers via Post Crosslinking with Hindered Urea Bonds
- Chinese Journal of Polymer Science 2020年38卷第9期页码：915-920
- Affiliations：
  
  Department of Polymer Science and Engineering and the State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
- Author bio：
  
  szheng@sjtu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51973113, 51133003, and 21774078).
- DOI：10.1007/s10118-020-2457-z
  中图分类号：
- 收稿：2020-03-22，
  
  修回：2020-5-5，
  
  录用：2020-5-15，
  
  网络首发：2020-06-15，
  
  纸质出版：2020-09
- Accepted：
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Ding, H.; Zhao, B.; Mei, H.; Li, L.; Zheng, S. Transformation of commodity poly(hydroxyether of bisphenol A) into vitrimers , via, post crosslinking with hindered urea bonds. Chinese J. Polym. Sci. 2020, 38, 915–920

Hao Ding, Bingjie Zhao, Honggang Mei, et al. Transformation of Commodity Poly(hydroxyether of bisphenol A) into Vitrimers via Post Crosslinking with Hindered Urea Bonds[J]. Chinese Journal of Polymer Science, 2020, 38(9): 915-920. DOI: 10.1007/s10118-020-2457-z.
Ding, H.; Zhao, B.; Mei, H.; Li, L.; Zheng, S. Transformation of commodity poly(hydroxyether of bisphenol A) into vitrimers , via, post crosslinking with hindered urea bonds. Chinese J. Polym. Sci. 2020, 38, 915–920 DOI： 10.1007/s10118-020-2457-z.

Hao Ding, Bingjie Zhao, Honggang Mei, et al. Transformation of Commodity Poly(hydroxyether of bisphenol A) into Vitrimers via Post Crosslinking with Hindered Urea Bonds[J]. Chinese Journal of Polymer Science, 2020, 38(9): 915-920. DOI: 10.1007/s10118-020-2457-z. DOI：

摘要

Abstract

In this contribution

we reported the preparation of vitrimers by using commodity thermoplastics

via

post crosslinking with hindered urea bonds (HUBs). First

three hindered urea diisocyanates (HUDIs) were synthesized

via

the reactions of

′-di-

tert

-butylethylenediamine

′-diethylethylenediamine

and piperazine with isophorone diisocyanate (IPDI). Thereafter

these HUDIs were used as the crosslinking agents to crosslink poly(hydroxyether of bisphenol A) (PH)

a commodity thermoplastics. Fourier transform infrared (FTIR) spectroscopy and dynamic mechanical thermal analyses (DMTA) indicated that the PH thermosets were successfully obtained. It was found that the thermosets displayed the behavior of vitrimers. The PH thermosets can be reprocessed at elevated temperature without using catalyst and the mechanical strengths of vitrimers were recovered as high as 95%. The reprocessing properties are attributable to dynamic exchange reaction of hindered urea bonds

contingent on types of hindered urea bonds.

关键词

Keywords

references

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Transformation of Commodity Poly(hydroxyether of bisphenol A) into Vitrimers via Post Crosslinking with Hindered Urea Bonds

Transformation of Commodity Poly(hydroxyether of bisphenol A) into Vitrimers via Post Crosslinking with Hindered Urea Bonds

DOI：10.1007/s10118-020-2457-z

摘要

Abstract

关键词

Keywords

references