Green Monomer of CO<sub>2</sub> and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s

Bo Song; An-Jun Qin; Ben Zhong Tang

doi:10.1007/s10118-020-2454-2

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Green Monomer of CO₂ and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s

ARTICLE | Updated：2020-07-13

- Green Monomer of CO₂ and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s
- Green Monomer of CO₂ and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s
- Chinese Journal of Polymer Science 2021年39卷第1期页码：51-59
- Affiliations：
  
  a.State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, Center for Aggregation-Induced Emission, South China University of Technology, Guangzhou 510640, China
  b.Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Centre for Tissue Restoration and Reconstruction, Institute for Advanced Study, Department of Chemical and Biological Engineering, The Hong Kong University of Science & Technology, Hong Kong, China
- Author bio：
  
  msqinaj@scut.edu.cn (A.J.Q.)
  tangbenz@ust.hk (B.Z.T.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21788102, 21525417, and 21490571), the Natural Science Foundation of Guangdong Province (Nos. 2016A030312002 and 2019B030301003), and the Innovation and Technology Commission of Hong Kong (ITC-CNERC14S01).
- DOI：10.1007/s10118-020-2454-2
  中图分类号：
- 收稿：2020-04-03，
  
  修回：2020-4-30，
  
  录用：2020-5-6，
  
  网络首发：2020-07-13，
  
  纸质出版：2021-01-01
- Accepted：
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Song, B.; Qin, A. J.; Tang, B. Z. Green monomer of CO₂ and alkyne-based four-component tandem polymerization toward regio- and stereoregular poly(aminoacrylate)s. Chinese J. Polym. Sci. 2021, 39, 51–59 DOI: 10.1007/s10118-020-2454-2.

Bo Song, An-Jun Qin, Ben Zhong Tang. Green Monomer of CO₂ and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s[J]. Chinese Journal of Polymer Science, 2021, 39(1): 51-59. DOI: 10.1007/s10118-020-2454-2.
Song, B.; Qin, A. J.; Tang, B. Z. Green monomer of CO₂ and alkyne-based four-component tandem polymerization toward regio- and stereoregular poly(aminoacrylate)s. Chinese J. Polym. Sci. 2021, 39, 51–59 DOI: 10.1007/s10118-020-2454-2. DOI：

Bo Song, An-Jun Qin, Ben Zhong Tang. Green Monomer of CO₂ and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s[J]. Chinese Journal of Polymer Science, 2021, 39(1): 51-59. DOI: 10.1007/s10118-020-2454-2. DOI：

摘要

Abstract

Green monomers

such as carbon dioxide (CO

)

are closely related to our daily life and highly desirable to be transferred to functional polymers with diverse structures and versatile properties because they are abundant

cheap

nontoxic

renewable

and sustainable. However

the polymerizations based on these green monomers are to be further developed. In this work

a facile CO

and alkyne-based one-pot

two-step

four-component tandem polymerization was successfully established. The polymerization of CO

diynes

alkyl dihalides

and primary/secondary amines can proceed under mild reaction conditions and regio- and stereoregular poly(aminoacrylate)s with good solubility and thermal stability were obtained in high yields (up to 95%). Notably

distinctly different stereoregularity of resultant poly(aminoacrylate)s was realized

via

using primary or secondary amines. Using the former would readily generate polymers with 100%

-isomers

whereas the latter furnished products with over 95%

-isomers. Through different monomer combination

the polymers with tunable structures and properties were obtained. Moreover

the tetraphenylethene units containing poly(aminoacrylate)s

showing the unique aggregation-induced emission characteristics

could function as a fluorescent probe for sensitive explosive detection. Thus

this work not only develops a facile CO

and alkyne-based multicomponent tandem polymerization but also provides a valuable strategy to fine-tune the polymer structures and properties

which could be potentially applied in diverse areas.

关键词

Keywords

references

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Green Monomer of CO2 and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s

Green Monomer of CO2 and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s

DOI：10.1007/s10118-020-2454-2

摘要

Abstract

关键词

Keywords

references

Green Monomer of CO₂ and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s

Green Monomer of CO₂ and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s