Syntheses of Soluble Biopolyimides Using 4-Aminophenylalanine

Kenji Takada; Hiromasa Shinagawa; Yuki Morita; Manjit S. Grewal; Kazuya Taya; Amit Kumar; Tatsuo Kaneko

doi:10.1007/s10118-020-2450-6

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Syntheses of Soluble Biopolyimides Using 4-Aminophenylalanine

ARTICLE | Updated：2020-07-27

- Syntheses of Soluble Biopolyimides Using 4-Aminophenylalanine
- Syntheses of Soluble Biopolyimides Using 4-Aminophenylalanine
- Chinese Journal of Polymer Science 2020年38卷第10期页码：1117-1123
- Affiliations：
  
  a.Graduate School of Advanced Science and Technology, Energy and Environment Area, Japan Advanced Institute of Science and Technology (JAIST), 1-1 Asahidai, Nomi, Ishikawa, 923-1292, Japan
  b.Material/Organometallics Laboratory, Department of Chemistry, Atma Ram Sanatan Dharma College, University of Delhi, New Delhi- 110021, India
- Author bio：
  
  kaneko@jaist.ac.jp
- Funds：
  
  This work was financially supported by Japan Science and Technology Agency (JST)-Advanced Low Carbon Technology (ALCA) project (JPMJAL1010), Center of Innovation (COI) program “Construction of next-generation infrastructure using innovative materials–Realization of a safe and secure society that can coexist with the earth for centuries–, and Crossministerial Strategic Innovation Promotion Program (SIP2), “Smart-bio” (Bio-oriented Technology Research Advancement Institution, NARO).
- DOI：10.1007/s10118-020-2450-6
  中图分类号：
- 收稿：2020-03-30，
  
  修回：2020-4-24，
  
  录用：2020-4-29，
  
  网络首发：2020-07-27，
  
  纸质出版：2020-06-16
- Accepted：
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Takada, K.; Shinagawa, H.; Morita, Y.; Grewal, M. S.; Taya, K.; Kumar, A.; Kaneko, T. Syntheses of soluble biopolyimides using 4-aminophenylalanine. Chinese J. Polym. Sci. 2020, 38, 1117–1123

Kenji Takada, Hiromasa Shinagawa, Yuki Morita, et al. Syntheses of Soluble Biopolyimides Using 4-Aminophenylalanine[J]. Chinese Journal of Polymer Science, 2020, 38(10): 1117-1123.
Takada, K.; Shinagawa, H.; Morita, Y.; Grewal, M. S.; Taya, K.; Kumar, A.; Kaneko, T. Syntheses of soluble biopolyimides using 4-aminophenylalanine. Chinese J. Polym. Sci. 2020, 38, 1117–1123 DOI： 10.1007/s10118-020-2450-6.

Kenji Takada, Hiromasa Shinagawa, Yuki Morita, et al. Syntheses of Soluble Biopolyimides Using 4-Aminophenylalanine[J]. Chinese Journal of Polymer Science, 2020, 38(10): 1117-1123. DOI： 10.1007/s10118-020-2450-6.

摘要

Abstract

4-Aminophenylalanine (4APhe)

an exotic amino acid which is obtained as a microorganism metabolite of glucose

is polycondensed with various tetracarboxylic dianhydrides as a diamine monomer to obtain poly(amic acid)s. Subsequent thermal imidization of poly(amic acid)s is made at 220 °C with stepwise heating from 100 °C. Some of the obtained polyimides (PIs) exhibited good solubility in organic solvents such as

-dimethylformamide

-dimethylacetamide

and more. The progress of imidization was observed by proton nuclear magnetic resonance and infrared spectroscopy to confirm that the imidization ratio was up to 98%. Carboxylate group of the side-chains of PIs affected their solubilities despite the high imidization ratio

and the solubility was lost for any organic solvents by decarboxylation at 280 °C

confirmed from mass-loss of thermogravimetric analysis. Thus

a new series of PIs were obtained with abilities of solvent-molding in PI state and thermal resistivity enhancement by further heating after molding.

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Keywords

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