a.Laboratory of Advanced Polymer Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
yanghx@iccas.ac.cn (H.X.Y.)
shiyang@iccas.ac.cn (S.Y.Y.)
收稿:2020-03-10,
修回:2020-4-7,
录用:2020-4-17,
网络首发:2020-06-22,
纸质出版:2020-09-10
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Liu, F. L.; He, J. J.; Yang, H. X.; Yang, S. Y. Improved properties of aromatic polyamide tape-casting films. Chinese J. Polym. Sci. 2020, 38, 1345–1354
Fu-Lin Liu, Jian-Jun He, Hai-Xia Yang, et al. Improved Properties of Aromatic Polyamide Tape-casting Films[J]. Chinese Journal of Polymer Science, 2020, 38(12): 1345-1354.
Liu, F. L.; He, J. J.; Yang, H. X.; Yang, S. Y. Improved properties of aromatic polyamide tape-casting films. Chinese J. Polym. Sci. 2020, 38, 1345–1354 DOI: 10.1007/s10118-020-2445-3.
Fu-Lin Liu, Jian-Jun He, Hai-Xia Yang, et al. Improved Properties of Aromatic Polyamide Tape-casting Films[J]. Chinese Journal of Polymer Science, 2020, 38(12): 1345-1354. DOI: 10.1007/s10118-020-2445-3.
A convenient tape-casting method was applied to prepare high performance aromatic polyamide (PA) films based on Technora
®
. During the polycondensation
CaO was introduced to improve the solubility of the PA resin
and the generated halides were totally removed from the film
via
a simple water bath
without leaving any defects in PA films. The factors of processing temperature and immersion time had been systematically investigated
and the experimental results demonstrated that both of them had impressive impacts on aggregation state and comprehensive properties of the PA film. It was suggested that immersion in water for more than 1 min and baking below 300 °C for 10 min were the optimal conditions for the thermal
tensile
tear
and optical properties to be in the best equilibrium. The resultant PA films integrated outstanding film-forming ability and excellent general performance
especially the tensile property and tear resistance.
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