Flame-retardant and Self-healing Biomass Aerogels Based on Electrostatic Assembly

Ji-Yu Yang; Yu Xia; Jin Zhao; Long-Fei Yi; Yong-Jiao Song; Hong Wu; Shao-Yun Guo; Li-Juan Zhao; Jin-Rong Wu

doi:10.1007/s10118-020-2444-4

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Flame-retardant and Self-healing Biomass Aerogels Based on Electrostatic Assembly

ARTICLE | Updated：2020-06-09

- Flame-retardant and Self-healing Biomass Aerogels Based on Electrostatic Assembly
- Flame-retardant and Self-healing Biomass Aerogels Based on Electrostatic Assembly
- Chinese Journal of Polymer Science 2020年38卷第12期页码：1294-1304
- Affiliations：
  
  a.College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066, China
  b.State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute, Sichuan University, Chengdu 610065, China
  c.State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  lijuan_zhao@sicnu.edu.cn (L.J.Z.)
  wujinrong@scu.edu.cn (J.R.W.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51873133 and 51873110), the Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University) (No. sklpme2018-4-33 and sklpme2019-4-32) and Chengdu Science and Technology Bureau (No. 2019-YF05-01319-SN).
- DOI：10.1007/s10118-020-2444-4
  中图分类号：
- 收稿：2020-03-17，
  
  修回：2020-4-13，
  
  录用：2020-4-15，
  
  网络首发：2020-06-09，
  
  纸质出版：2020-09-10
- Accepted：
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Yang, J. Y.; Xia, Y.; Zhao, J.; Yi, L. F.; Song, Y. J.; Wu, H.; Guo, S. Y.; Zhao, L. J.; Wu, J. R. Flame-retardant and self-healing biomass aerogels based on electrostatic assembly. Chinese J. Polym. Sci. 2020, 38, 1294–1304

Ji-Yu Yang, Yu Xia, Jin Zhao, et al. Flame-retardant and Self-healing Biomass Aerogels Based on Electrostatic Assembly[J]. Chinese Journal of Polymer Science, 2020, 38(12): 1294-1304.
Yang, J. Y.; Xia, Y.; Zhao, J.; Yi, L. F.; Song, Y. J.; Wu, H.; Guo, S. Y.; Zhao, L. J.; Wu, J. R. Flame-retardant and self-healing biomass aerogels based on electrostatic assembly. Chinese J. Polym. Sci. 2020, 38, 1294–1304 DOI： 10.1007/s10118-020-2444-4.

Ji-Yu Yang, Yu Xia, Jin Zhao, et al. Flame-retardant and Self-healing Biomass Aerogels Based on Electrostatic Assembly[J]. Chinese Journal of Polymer Science, 2020, 38(12): 1294-1304. DOI： 10.1007/s10118-020-2444-4.

摘要

Abstract

It remains a significant challenge to fabricate self-healing aerogels with excellent flame retardancy. Herein

we develop a class of biomass aerogels by electrostatically assembling chitosan (CS)

phytic acid (PA)

and itaconic acid (IA). The electrostatic interaction between CS and IA is weak and dynamic

so freeze-drying the solution of CS and IA enables the formation of continuous aerogel skeleton with self-healing ability and re-programmability; in comparison

the electrostatic interaction between CS and PA is strong and less dynamic

and thus mixing PA with CS in aqueous solution leads to fine precipitates of high flame retardancy due to the synergistic phosphorus-nitrogen effect. Integrating the continuous skeleton and the fine precipitates results in self-healing aerogles with UL-4 V-0 rating of flame retardancy aerogels and auto-extinguishable feature. Interestingly

the aerogels after burning in flame for 30 s form a skin-core structure

and the carbonized skin protects the integrity of the aerogels and the self-healing ability of the internal parts. Therefore

this work provides a facile strategy to develop multi-functional aerogels which hold great promise for advanced applications.

关键词

Keywords

references

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