Rational Design of Conjugated Polymers for <italic style="font-style: italic">d</italic>-Limonene Processed All-polymer Solar Cells with Small Energy Loss

Mei-Jing Li; Bao-Bing Fan; Wen-Kai Zhong; Zhao-Mi-Yi Zeng; Jing-Kun Xu; Lei Ying

doi:10.1007/s10118-020-2429-3

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Rational Design of Conjugated Polymers for d-Limonene Processed All-polymer Solar Cells with Small Energy Loss

RAPID COMMUNICATION | Updated：2020-05-18

- Rational Design of Conjugated Polymers for d-Limonene Processed All-polymer Solar Cells with Small Energy Loss
- Rational Design of Conjugated Polymers for d-Limonene Processed All-polymer Solar Cells with Small Energy Loss
- Chinese Journal of Polymer Science 2020年38卷第8期页码：791-796
- Affiliations：
  
  a.Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China
  b.School of Pharmacy, Jiangxi Science & Technology Normal University, Nanchang 330013, China
  c.South China Institute of Collaborative Innovation, Dongguan 523808, China
- Author bio：
  
  msleiying@scut.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21822505 and 21905103), Dongguan Science and Technology Bureau (Nos. 2018607201002 and 2019622163009), and the Basic and Applied Basic Research Major Program of Guangdong Province (No. 2019B030302007).
- DOI：10.1007/s10118-020-2429-3
  中图分类号：
- 收稿：2020-02-26，
  
  修回：2020-3-13，
  
  录用：2020-3-17，
  
  网络首发：2020-05-18，
  
  纸质出版：2020-08
- Accepted：
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Li, M. J.; Fan, B. B.; Zhong, W. K.; Zeng, Z. M. Y.; Xu, J. K.; Ying, L. Rational design of conjugated polymers for , d,-limonene processed all-polymer solar cells with small energy loss. Chinese J. Polym. Sci. 2020, 38, 791–796

Mei-Jing Li, Bao-Bing Fan, Wen-Kai Zhong, et al. Rational Design of Conjugated Polymers for d-Limonene Processed All-polymer Solar Cells with Small Energy Loss[J]. Chinese Journal of Polymer Science, 2020, 38(8): 791-796. DOI: 10.1007/s10118-020-2429-3.
Li, M. J.; Fan, B. B.; Zhong, W. K.; Zeng, Z. M. Y.; Xu, J. K.; Ying, L. Rational design of conjugated polymers for , d,-limonene processed all-polymer solar cells with small energy loss. Chinese J. Polym. Sci. 2020, 38, 791–796 DOI： 10.1007/s10118-020-2429-3.

Mei-Jing Li, Bao-Bing Fan, Wen-Kai Zhong, et al. Rational Design of Conjugated Polymers for d-Limonene Processed All-polymer Solar Cells with Small Energy Loss[J]. Chinese Journal of Polymer Science, 2020, 38(8): 791-796. DOI: 10.1007/s10118-020-2429-3. DOI：

摘要

Abstract

In this work

we designed and synthesized a novel naphthalenediimide-based n-type conjugated polymer

PNDICl

which bears asymmetric backbone containing a 3-chlorothiophene unit. The asymmetric structure associated with steric effects of the chlorine atom imparts remarkable solubility to

PNDICl

in various organic solvents

enabling the fabrication of all-polymer solar cells (all-PSCs) by using an environmentally friendly solvent of

-limonene. Combined with a novel pyrrolo[3

]benzotriazole-5

7(6

)-dione based p-type conjugated polymer

P2F-Si

with deep highest occupied molecular orbital energy level

the resulting

-limonene-processed all-PSCs presents an impressively high open-circuit voltage of approaching 1.0 V

corresponding to a very small energy loss of 0.49 eV. Through further morphology optimization by using

-valerolactone

we demonstrated an impressive device efficiency of 4.2%

which is among the best photovoltaic performance of devices processed using

-limonene and comparable to that processed by conventional solvent

suggesting the great promise of using greener solvent for fabricating high-performance all-PSCs.

关键词

Keywords

references

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DOI：10.1007/s10118-020-2429-3

摘要

Abstract

关键词

Keywords

references