Enhancement of <italic style="font-style: italic">β</italic>-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters

Lu Jin; Yan Zheng; Ze-Kun Liu; Jia-Shen Li; Yang-Pei-Qi Yi; Yang-Yang Fan; Lu-Lu Xu; Yi Li

doi:10.1007/s10118-020-2428-4

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Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters

ARTICLE | Updated：2020-06-18

- Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters
- Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters
- Chinese Journal of Polymer Science 2020年38卷第11期页码：1239-1247
- Affiliations：
  
  a.Department of Materials, School of Natural Sciences, The University of Manchester, Manchester M13 9PL, U.K.
  b.School of Fashion, Zhongyuan University of Technology, Zhengzhou 450007, China
- Author bio：
  
  henry.yili@manchester.ac.uk
- Funds：
  
  This work was financially supported by The Cotton Textiles Research Trust with the project “Protective Efficiency of Respiratory Protective Equipment against Byssinosis for Cotton Workers” and The University of Manchester through project AA14512 (UMRI project “Graphene-Smart Textiles E-Healthcare Network”). L.J. and Z.L. were funded by the China Scholarship Council (CSC).
- DOI：10.1007/s10118-020-2428-4
  中图分类号：
- 收稿：2020-01-02，
  
  修回：2020-3-13，
  
  录用：2020-3-17，
  
  网络首发：2020-06-18，
  
  纸质出版：2020-08-14
- Accepted：
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Jin, L.; Zheng, Y.; Liu, Z. K.; Li, J. S.; Yi, Y. P. Q.; Fan, Y. Y.; Xu, L. L.; Li, Y. Enhancement of , β,-phase crystal content of poly(vinylidene fluoride) nanofiber web by graphene and electrospinning parameters. Chinese J. Polym. Sci. 2020, 38, 1239–1247

Lu Jin, Yan Zheng, Ze-Kun Liu, et al. Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters[J]. Chinese Journal of Polymer Science, 2020, 38(11): 1239-1247. DOI: 10.1007/s10118-020-2428-4.
Jin, L.; Zheng, Y.; Liu, Z. K.; Li, J. S.; Yi, Y. P. Q.; Fan, Y. Y.; Xu, L. L.; Li, Y. Enhancement of , β,-phase crystal content of poly(vinylidene fluoride) nanofiber web by graphene and electrospinning parameters. Chinese J. Polym. Sci. 2020, 38, 1239–1247 DOI： 10.1007/s10118-020-2428-4.

Lu Jin, Yan Zheng, Ze-Kun Liu, et al. Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters[J]. Chinese Journal of Polymer Science, 2020, 38(11): 1239-1247. DOI: 10.1007/s10118-020-2428-4. DOI：

摘要

Abstract

Electrospun poly(vinylidene fluoride) (PVDF) nanofiber web has been widely utilized as a functional material in various flexible sensors and generators due to its high piezoelectricity

ease processability

and low cost. Among all the crystalline phases of PVDF

-phase is a key property for PVDF nanofiber web

because the content of

-phase is directly proportional to piezoelectric performance of PVDF nanofiber web. Herein

the impact of graphene content (GC)

tip-to-collector distance (TCD)

and rotational speed of collector (RSC)

as well as their interactions on the

-phase formation of PVDF nanofiber web is systematically investigated

via

design of experimental method. The fraction of each crystalline phase of PVDF nanofiber web is calculated by FTIR spectra

and the crystallinity is determined by XRD patterns. The influences of GC

TCD

and RSC on both

-phase fraction and crystallinity of PVDF nanofiber are analyzed using Minitab program. The results show that GC

TCD

and RSC all have significant effect on the

-phase content of PVDF nanofiber web

and GC is the most significant one. In addition

an optimal electrospinning condition (GC = 1 wt%

TCD = 4 cm

and RSC = 2000 r·min

–1

) to fabricate high

-phase crystallinity of PVDF nanofiber web is drawn

under which the crystallinity can reach 41.7%. The contributions in this study could provide guidance for future research on fabricating high performance PVDF nanofiber web based sensors or generators.

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Keywords

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DOI：10.1007/s10118-020-2428-4

摘要

Abstract

关键词

Keywords

references