Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling

William Imamura; Érik Oda Usuda; Lucas Soares Paixão; Nicolau Molina Bom; Angelo Marcio Gomes; Alexandre Magnus Gomes Carvalho

doi:10.1007/s10118-020-2423-9

Your Location：

Home >

Browse articles >

Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling

ARTICLE | Updated：2020-05-22

- Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling
- Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling
- Chinese Journal of Polymer Science 2020年38卷第9期页码：999-1005
- Affiliations：
  
  a.Faculdade de Engenharia Mecânica, UNICAMP, CEP 13083-860, Campinas, SP, Brazil
  b.Universidade Federal de São Paulo, UNIFESP, CEP 09913-030, Diadema, SP, Brazil
  c.Instituto de Física Gleb Wataghin, UNICAMP, CEP 13083-859, Campinas, SP, Brazil
  d.Catalan Institute of Nanoscience and Nanotechnology, ICN2, 08860 Belaterra, Barcelona, Spain
  e.The Institute of Photonic Sciences, ICFO, 08193 Castelldefels, Barcelona, Spain
  f.Instituto de Física, UFRJ, CEP 21941-972, Rio de Janeiro, RJ, Brazil
  g.Departamento de Engenharia Mecânica, UEM, CEP 87020-900, Maringá, PR, Brazil
- Author bio：
  
  amgcarvalho.pem.uem@gmail.com
- Funds：
  
  This work was financially supported by FAPESP (No. 2016/22934-3), CNPq, CAPES, and CNPEM.
- DOI：10.1007/s10118-020-2423-9
  中图分类号：
- 收稿：2020-01-07，
  
  修回：2020-3-7，
  
  录用：2020-3-13，
  
  网络首发：2020-05-22，
  
  纸质出版：2020-09
- Accepted：
Scan QR Code
Imamura, W.; Usuda, É. O.; Paixão, L. S.; Bom, N. M.; Gomes, A. M.; Carvalho, A. M. G. Supergiant barocaloric effects in acetoxy silicone rubber over a wide temperature range: great potential for solid-state cooling. Chinese J. Polym. Sci. 2020, 38, 999–1005

William Imamura, Érik Oda Usuda, Lucas Soares Paixão, et al. Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling[J]. Chinese Journal of Polymer Science, 2020, 38(9): 999-1005.
Imamura, W.; Usuda, É. O.; Paixão, L. S.; Bom, N. M.; Gomes, A. M.; Carvalho, A. M. G. Supergiant barocaloric effects in acetoxy silicone rubber over a wide temperature range: great potential for solid-state cooling. Chinese J. Polym. Sci. 2020, 38, 999–1005 DOI： 10.1007/s10118-020-2423-9.

William Imamura, Érik Oda Usuda, Lucas Soares Paixão, et al. Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling[J]. Chinese Journal of Polymer Science, 2020, 38(9): 999-1005. DOI： 10.1007/s10118-020-2423-9.

摘要

Abstract

Solid-state cooling based on caloric effects is considered a viable alternative to replace the conventional vapor-compression refrigeration systems. Regarding barocaloric materials

recent results show that elastomers are promising candidates for cooling applications around room-temperature. In the present paper

we report supergiant barocaloric effects observed in acetoxy silicone rubber—a very popular

low-cost and environmentally friendly elastomer. Huge values of adiabatic temperature change and reversible isothermal entropy change were obtained upon moderate applied pressures and relatively low strains. These huge barocaloric changes are associated both to the polymer chain rearrangements induced by confined compression and to the first-order structural transition. The results are comparable to the best barocaloric materials reported so far

opening encouraging prospects for the application of elastomers in near future solid-state cooling devices.

关键词

Keywords

references

Imamura, W.; Paixão, L. S.; Usuda, E. O.; Bom, N. M.; Gama, S.; Lopes, E. S. N.; Carvalho, A. M. G. i -Caloric effects: a proposal for normalization. 2018 , arXiv: 1806.07959.

Gough, J. . A description of a property of caoutchouc, or indian rubber . Memories Lit. Philos. Soc. Manchester , 1805 . 1 288 - 295 . .

Pecharsky, V. K.; Gschneidner, Jr., K. A . Giant magnetocaloric effect in Gd 5 Si 2 Ge 2 . Phys. Rev. Lett. , 1997 . 78 4494 - 4497 . DOI: 10.1103/PhysRevLett.78.4494 http://doi.org/10.1103/PhysRevLett.78.4494 .

Mischenko, A. S.; Zhang, Q.; Scott, J. F.; Whatmore, R. W.; Mathur, N. D. . Giant electrocaloric effect in thin-film PbZr 0.95 Ti 0.05 O 3 . Science , 2006 . 3011 1270 - 1271 . .

Dart, S. L.; Anthony, R. L.; Guth, E. . Rise of temperature on fast stretching if synthetics and natural rubbers . Ind. Eng. Chem. , 1942 . 34 1340 - 1342 . DOI: 10.1021/ie50395a020 http://doi.org/10.1021/ie50395a020 .

Dart, S. L.; Guth, E. . Rise of temperature on fast stretching of butyl rubber . J. Chem. Phys. , 1945 . 13 28 - 36 . DOI: 10.1063/1.1723964 http://doi.org/10.1063/1.1723964 .

Shaw, J. A.; Kyriakides, S. . Thermomechanical aspects of NiTi . J. Mech. Phys. Solids , 1995 . 43 1243 - 1281 . DOI: 10.1016/0022-5096(95)00024-D http://doi.org/10.1016/0022-5096(95)00024-D .

Bonnot, E.; Romero, R.; Mañosa, L.; Vives, E.; Planes, A. . Elastocaloric effect associated with the martensitic transition in shape-memory alloys . Phys. Rev. Lett. , 2008 . 100 1 - 4 . .

Mañosa, L.; González-Alonso, D.; Planes, A.; Bonnot, E.; Barrio, M.; Tamarit, J. L.; Aksoy, S.; Acet, M. . Giant solid-state barocaloric effect in the Ni-Mn-In magnetic shape-memory alloy . Nat. Mater. , 2010 . 9 478 - 481 . DOI: 10.1038/nmat2731 http://doi.org/10.1038/nmat2731 .

Millán-Solsona, R.; Stern-Taulats, E.; Vives, E.; Planes, A.; Sharma, J.; Nayak, A. K.; Suresh, K. G.; Mañosa, L. . Large entropy change associated with the elastocaloric effect in polycrystalline Ni-Mn-Sb-Co magnetic shape memory alloys . Appl. Phys. Lett. , 2014 . 105 241901 DOI: 10.1063/1.4904419 http://doi.org/10.1063/1.4904419 .

Wu, R. R.; Bao, L. F.; Hu, F. X.; Wu, H.; Huang, Q. Z.; Wang, J.; Dong, X. L.; Li, G. N.; Sun, J. R.; Shen, F. R.; Zhao, T. Y.; Zheng, X. Q.; Wang, L. C.; Liu, Y.; Zuo, W. L.; Zhao, Y. Y.; Zhang, M.; Wang, X. C.; Jin, C. Q.; Rao, G. H.; Han, X. F.; Shen, B. G. . Giant barocaloric effect in hexagonal Ni 2 In-Type Mn-Co-Ge-In compounds around room temperature . Sci. Rep. , 2015 . 5 18027 DOI: 10.1038/srep18027 http://doi.org/10.1038/srep18027 .

Lloveras, P.; Stern-Taulats, E.; Barrio, M.; Tamarit, J. L.; Crossley, S.; Li, W.; Pomjakushin, V.; Planes, A.; Mañosa, L.; Mathur, N. D.; Moya, X. . Giant barocaloric effects at low pressure in ferrielectric ammonium sulphate . Nat. Commun. , 2015 . 6 8801 DOI: 10.1038/ncomms9801 http://doi.org/10.1038/ncomms9801 .

Vallone, S. P.; Tantillo, A. N.; dos Santos, A. M.; Molaison, J. J.; Kulmaczewski, R.; Chapoy, A.; Ahmadi, P.; Halcrow, M. A.; Sandeman, K. G. . Giant barocaloric effect at the spin crossover transition of a molecular crystal . Adv. Mater. , 2019 . 31 1807334 DOI: 10.1002/adma.201807334 http://doi.org/10.1002/adma.201807334 .

Li, B.; Kawakita, Y.; Ohira-Kawamura, S.; Sugahara, T.; Wang, H.; Wang, J.; Chen, Y.; Kawaguchi, S. I.; Kawaguchi, S.; Ohara, K.; Li, K.; Yu, D.; Mole, R.; Hattori, T.; Kikuchi, T.; Yano, S.; Zhang, Z.; Zhang, Z.; Ren, W.; Lin, S.; Sakata, O.; Nakajima, K.; Zhang, Z. . Colossal barocaloric effects in plastic crystals . Nature , 2019 . 567 506 - 510 . DOI: 10.1038/s41586-019-1042-5 http://doi.org/10.1038/s41586-019-1042-5 .

Lloveras, P.; Aznar, A.; Barrio, M.; Negrier, P.; Popescu, C.; Planes, A.; Mañosa, L.; Stern-Taulats, E.; Avramenko, A.; Mathur, N. D.; Moya, X.; Tamarit, J. L. . Colossal barocaloric effects near room temperature in plastic crystals of neopentylglycol . Nat. Commun. , 2019 . 10 1803 DOI: 10.1038/s41467-019-09730-9 http://doi.org/10.1038/s41467-019-09730-9 .

Guyomar, D.; Li, Y.; Sebald, G.; Cottinet, P. J.; Ducharne, B.; Capsal, J. F. . Elastocaloric modeling of natural rubber . Appl. Therm. Eng. , 2013 . 57 33 - 38 . DOI: 10.1016/j.applthermaleng.2013.03.032 http://doi.org/10.1016/j.applthermaleng.2013.03.032 .

Xie, Z.; Sebald, G.; Guyomar, D. . Comparison of direct and indirect measurement of the elastocaloric effect in natural rubber . Appl. Phys. Lett. , 2016 . 108 041901 DOI: 10.1063/1.4940378 http://doi.org/10.1063/1.4940378 .

Patel, S.; Chauhan, A.; Vaish, R.; Thomas, P. . Elastocaloric and barocaloric effects in polyvinylidene di-fluoride-based polymers . Appl. Phys. Lett. , 2016 . 108 072903 DOI: 10.1063/1.4942000 http://doi.org/10.1063/1.4942000 .

Usuda, E. O.; Bom, N. M.; Carvalho, A. M. G. . Large barocaloric effects at low pressures in natural rubber . Eur. Polym. J. , 2017 . 92 287 - 293 . DOI: 10.1016/j.eurpolymj.2017.05.017 http://doi.org/10.1016/j.eurpolymj.2017.05.017 .

Carvalho, A. M. G.; Imamura, W.; Usuda, E. O.; Bom, N. M. . Giant room-temperature barocaloric effects in PDMS rubber at low pressures . Eur. Polym. J. , 2018 . 99 212 - 221 . DOI: 10.1016/j.eurpolymj.2017.12.007 http://doi.org/10.1016/j.eurpolymj.2017.12.007 .

Bom, N. M.; Imamura, W.; Usuda, E. O.; Paixao, L. S.; Carvalho, A. M. G. . Giant barocaloric effects in natural rubber: a relevant step toward solid-state cooling . ACS Macro Lett. , 2018 . 7 31 - 36 . DOI: 10.1021/acsmacrolett.7b00744 http://doi.org/10.1021/acsmacrolett.7b00744 .

Yoshida, Y.; Yuse, K.; Guyomar, D.; Capsal, J. F.; Sebald, G. . Elastocaloric effect in poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene) terpolymer . Appl. Phys. Lett. , 2016 . 108 242904 DOI: 10.1063/1.4953770 http://doi.org/10.1063/1.4953770 .

Usuda, E. O.; Imamura, W.; Bom, N. M.; Paixão, L. S.; Carvalho, A. M. G. . Giant reversible barocaloric effects in nitrile butadiene rubber around room temperature . ACS Appl. Polym. Mater. , 2019 . 1 1991 - 1997 . DOI: 10.1021/acsapm.9b00235 http://doi.org/10.1021/acsapm.9b00235 .

Smith, J. C. B. . Analysis of organo-silicon compounds, with special reference to silanes and siloxanes. A review . Analyst , 1960 . 85 465 DOI: 10.1039/an9608500465 http://doi.org/10.1039/an9608500465 .

Imamura, W.; Usuda, E. O.; Paixão, L. S.; Bom, N. M.; Carvalho, A. M. G. Supergiant barocaloric effects in acetoxy silicone rubber around room temperature. 2017 , arXiv: 1710.01761.

Aprea, C.; Greco, A.; Maiorino, A.; Masselli, C. . Enhancing the heat transfer in an active barocaloric cooling system using ethylene-glycol based nanofluids as secondary medium . Energies , 2019 . 12 2902 DOI: 10.3390/en12152902 http://doi.org/10.3390/en12152902 .

Aprea, C.; Greco, A.; Maiorino, A.; Masselli, C. . The employment of caloric-effect materials for solid-state heat pumping . Int. J. Refrig. , 2020 . 109 1 - 11 . DOI: 10.1016/j.ijrefrig.2019.09.011 http://doi.org/10.1016/j.ijrefrig.2019.09.011 .

Aprea, C.; Greco, A.; Maiorino, A.; Masselli, C. . The use of barocaloric effect for energy saving in a domestic refrigerator with ethylene-glycol based nanofluids: a numerical analysis and a comparison with a vapor compression cooler . Energy , 2020 . 190 116404 DOI: 10.1016/j.energy.2019.116404 http://doi.org/10.1016/j.energy.2019.116404 .

Bom, N. M.; Usuda, E. O.; Guimarães, G. M.; Coelho, A. A.; Carvalho, A. M. G. . Note: experimental setup for measuring the barocaloric effect in polymers: application to natural rubber . Rev. Sci. Instrum. , 2017 . 88 046103 - 046105 . DOI: 10.1063/1.4979464 http://doi.org/10.1063/1.4979464 .

Carvalho, A. M. G.; Araújo, D. H. C.; Canova, H. F.; Rodella, C. B.; Barrett, D. H.; Cuffini, S. L.; Costa, R. N.; Nunes, R. S. . X-ray powder diffraction at the XRD1 beamline at LNLS . J. Synchrotron Radiat. , 2016 . 23 1501 - 1506 . DOI: 10.1107/S1600577516012686 http://doi.org/10.1107/S1600577516012686 .

Carvalho, A. M. G.; Nunes, R. S.; Coelho, A. A. . X-ray powder diffraction of high-absorption materials at the XRD1 beamline off the best conditions: application to (Gd,Nd) 5 Si 4 compounds . Powder Diffr. , 2017 . 32 10 - 14 . DOI: 10.1017/S0885715616000646 http://doi.org/10.1017/S0885715616000646 .

Matsunami, D.; Fujita, A.; Takenaka, K.; Kano, M. . Giant barocaloric effect enhanced by the frustration of the antiferromagnetic phase in Mn 3 GaN . Nat. Mater. , 2015 . 14 73 - 78 . DOI: 10.1038/nmat4117 http://doi.org/10.1038/nmat4117 .

Yuce, S.; Barrio, M.; Emre, B.; Stern-Taulats, E.; Planes, A.; Tamarit, J. L.; Mudryk, Y.; Gschneidner, K. A.; Pecharsky, V. K.; Mañosa, L. . Barocaloric effect in the magnetocaloric prototype Gd 5 Si 2 Ge 2 . Appl. Phys. Lett. , 2012 . 101 71906 DOI: 10.1063/1.4745920 http://doi.org/10.1063/1.4745920 .

Mañosa, L.; González-Alonso, D.; Planes, A.; Barrio, M.; Tamarit, J.-L.; Titov, I. S.; Acet, M.; Bhattacharyya, A.; Majumdar, S. . Inverse barocaloric effect in the giant magnetocaloric La-Fe-Si-Co Compound . Nat. Commun. , 2011 . 2 595 DOI: 10.1038/ncomms1606 http://doi.org/10.1038/ncomms1606 .

Samanta, T.; Lloveras, P.; Saleheen, A. U.; Lepkowski, D. L.; Kramer, E.; Dubenko, I.; Philip, W.; Young, D. P.; Barrio, M.; Tamarit, J. L.; Ali, N.; Stadler, S.; Samanta, T.; Lloveras, P.; Saleheen, A. U.; Lepkowski, D. L.; Kramer, E.; Dubenko, I.; Adams, P. W.; Young, D. P.; Barrio, M.; Tamarit, J. L.; Ali, N.; Stadler, S. . Barocaloric and magnetocaloric effects in (MnNiSi) 1- x (FeCoGe) x . Appl. Phys. Lett. , 2018 . 112 021907 DOI: 10.1063/1.5011743 http://doi.org/10.1063/1.5011743 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Waste Tire Rubber-based Refrigerants for Solid-state Cooling Devices

A Terbium Coordination Cross-linked Tough Metallo-elastomer Showing Fluorochromism in Response to Multistimuli

Stretchable All-Small-Molecule Organic Solar Cells Enabled by Polymer Elastomer Confinement

Recyclable and Self-healable Polydimethylsiloxane Elastomers Based on Knoevenagel Condensation

Enhanced Segment Mobility Promotes Stereocomplex Crystallization in Polymer Blends via Elevated Segmental Miscibility