Nanofiltration Membranes <italic style="font-style: italic">via</italic> Layer-by-layer Assembly and Cross-linking of Polyethyleneimine/Sodium Lignosulfonate for Heavy Metal Removal

Meng-Yun Xie; Jiang Wang; Qing-Yun Wu

doi:10.1007/s10118-020-2422-x

Your Location：

Home >

Browse articles >

Nanofiltration Membranes via Layer-by-layer Assembly and Cross-linking of Polyethyleneimine/Sodium Lignosulfonate for Heavy Metal Removal

ARTICLE | Updated：2020-05-27

- Nanofiltration Membranes via Layer-by-layer Assembly and Cross-linking of Polyethyleneimine/Sodium Lignosulfonate for Heavy Metal Removal
- Nanofiltration Membranes via Layer-by-layer Assembly and Cross-linking of Polyethyleneimine/Sodium Lignosulfonate for Heavy Metal Removal
- Chinese Journal of Polymer Science 2020年38卷第9期页码：965-972
- Affiliations：
  
  a.Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
  b.School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, China
- Author bio：
  
  wuqingyun@nbu.edu.cn
- Funds：
  
  This work was financially supported by Zhejiang Provincial Natural Science Foundation of China (No. LY18E030002), Natural Science Foundation of Ningbo (No. 2018A610111), and K.C. Wong Magna Fund in Ningbo University. We acknowledge Dr. Lijing Zhu, Dr. Linghui Wang, and Dr. Lin Gu for their experimental support and advice.
- DOI：10.1007/s10118-020-2422-x
  中图分类号：
- 收稿：2019-12-23，
  
  修回：2020-3-11，
  
  录用：2020-3-13，
  
  网络首发：2020-05-27，
  
  纸质出版：2020-09
- Accepted：
Scan QR Code
Xie, M. Y.; Wang, J.; Wu, Q. Y. Nanofiltration membranes , via, layer-by-layer assembly and cross-linking of polyethyleneimine/sodium lignosulfonate for heavy metal removal. Chinese J. Polym. Sci. 2020, 38, 965–972

Meng-Yun Xie, Jiang Wang, Qing-Yun Wu. Nanofiltration Membranes via Layer-by-layer Assembly and Cross-linking of Polyethyleneimine/Sodium Lignosulfonate for Heavy Metal Removal[J]. Chinese Journal of Polymer Science, 2020, 38(9): 965-972. DOI: 10.1007/s10118-020-2422-x.
Xie, M. Y.; Wang, J.; Wu, Q. Y. Nanofiltration membranes , via, layer-by-layer assembly and cross-linking of polyethyleneimine/sodium lignosulfonate for heavy metal removal. Chinese J. Polym. Sci. 2020, 38, 965–972 DOI： 10.1007/s10118-020-2422-x.

Meng-Yun Xie, Jiang Wang, Qing-Yun Wu. Nanofiltration Membranes via Layer-by-layer Assembly and Cross-linking of Polyethyleneimine/Sodium Lignosulfonate for Heavy Metal Removal[J]. Chinese Journal of Polymer Science, 2020, 38(9): 965-972. DOI: 10.1007/s10118-020-2422-x. DOI：

摘要

Abstract

Layer-by-layer (LbL) assembly technology is a facile method for constructing thin film composite membrane. Herein

a novel nanofiltration (NF) membrane was prepared by LbL assembly of polyethyleneimine (PEI) and sodium lignosulfonate (LS) followed by cross-linking. The surface composition

morphology

and property of PEI/LS bilayer were detailedly investigated by FTIR/ATR

XPS

SEM

AFM

and water contact angle test. The PEI/LS bilayer full of amino and hydroxyl groups presents increased roughness and improved hydrophilicity. Moreover

the NF performance of PEI/LS LbL assembly membranes can be modulated by bilayer number

polyelectrolyte concentration

and salt content. The water flux reduced while the salt rejection greatly improved as increasing the bilayer numbers

PEI concentration

or NaCl content. More than 95% MgSO

and MgCl

as well as 80% NaCl can be rejected by a NF membrane prepared by 6 PEI/LS bilayers

1 wt% PEI

0.5 wt% LS

and 1 mol/L NaCl. Furthermore

this NF membrane can be used to remove more than 95% heavy metal ions (Cd

and Ni

). This work proposed a promising NF membrane by using PEI/LS as low cost polyelectrolytes and facile LbL assembly method

which should receive much attention in water purification.

关键词

Keywords

references

Ahmed, F. E.; Hashaikeh, R.; Diabat, A.; Hilal, N. . Mathematical and optimization modelling in desalination: state-of-the-art and future direction . Desalination , 2019 . 469 114092 DOI: 10.1016/j.desal.2019.114092 http://doi.org/10.1016/j.desal.2019.114092 .

Abdel-Fatah, M. A. . Nanofiltration systems and applications in wastewater treatment: review article . Ain Shams Eng. J. , 2018 . 9 3077 - 3092 . DOI: 10.1016/j.asej.2018.08.001 http://doi.org/10.1016/j.asej.2018.08.001 .

Oatley-Radcliffe, D. L.; Walters, M.; Ainscough, T. J.; Williams, P. M.; Mohammad, A. W.; Hilal, N. . Nanofiltration membranes and processes: a review of research trends over the past decade . J. Water Process Eng. , 2017 . 19 164 - 171 . DOI: 10.1016/j.jwpe.2017.07.026 http://doi.org/10.1016/j.jwpe.2017.07.026 .

Liu, Y.; Lin, B.; Liu, W.; Li, J.; Gao, C.; Pan, Q. . Preparation and characterization of a novel nanofiltration membrane with chlorine-tolerant property and good separation performance . RSC Adv. , 2018 . 8 36430 - 36440 . DOI: 10.1039/C8RA06755D http://doi.org/10.1039/C8RA06755D .

Li, X. L.; Zhu, L. P.; Jiang, J. H.; Yi, Z.; Zhu, B. K.; Xu, Y. Y. . Hydrophilic nanofiltration membranes with self-polymerized and strongly-adhered polydopamine as separating layer . Chinese J. Polym. Sci. , 2012 . 30 152 - 163 . DOI: 10.1007/s10118-012-1107-5 http://doi.org/10.1007/s10118-012-1107-5 .

Qi, Y.; Zhu, L.; Shen, X.; Sotto, A.; Gao, C.; Shen, J. . Polythyleneimine-modified original positive charged nanofiltration membrane: removal of heavy metal ions and dyes . Sep. Purif. Technol. , 2019 . 222 117 - 124 . DOI: 10.1016/j.seppur.2019.03.083 http://doi.org/10.1016/j.seppur.2019.03.083 .

Lin, C. E.; Fang, L. F.; Du, S. Y.; Yao, Z. K.; Zhu, B. K. . A novel positively charged nanofiltration membrane formed via simultaneous cross-linking/quaternization of poly( m -phenylene isophthalamide)/polyethyleneimine blend membrane . Sep. Purif. Technol. , 2019 . 212 101 - 109 . DOI: 10.1016/j.seppur.2018.11.026 http://doi.org/10.1016/j.seppur.2018.11.026 .

Peydayesh, M.; Mohammadi, T.; Bakhtiari, O. . Water desalination via novel positively charged hybrid nanofiltration membranes filled with hyperbranched polyethyleneimine modified MWCNT . J. Ind. Eng. Chem. , 2019 . 69 127 - 140 . DOI: 10.1016/j.jiec.2018.09.007 http://doi.org/10.1016/j.jiec.2018.09.007 .

Hendrix, K.; Vaneynde, M.; Koeckelberghs, G.; Vankelecom, I. F. J. . Synthesis of modified poly(ether ether ketone) polymer for the preparation of ultrafiltration and nanofiltration membranes via phase inversion . J. Membr. Sci. , 2013 . 447 96 - 106 . DOI: 10.1016/j.memsci.2013.07.006 http://doi.org/10.1016/j.memsci.2013.07.006 .

Li, H.; Shi, W.; Zhang, H.; Zhou, R.; Qin, X. . Preparation of internally pressurized polyamide thin-film composite hollow fiber nanofiltration membrane with high ions selectivity by a facile coating method . Prog. Org. Coat. , 2019 . 105456 .

Wang, J. H.; Wu, Y. L.; Zhang, Y. H.; Zhu, B. K.; Xu, Y. Y. . Fabrication and performance of a low operating pressure nanofiltration poly(vinyl chloride) hollow fiber membrane . Chinese J. Polym. Sci. , 2014 . 32 377 - 384 . DOI: 10.1007/s10118-014-1374-4 http://doi.org/10.1007/s10118-014-1374-4 .

Cheng, J.; Shi, W.; Zhang, L.; Zhang, R. . A novel polyester composite nanofiltration membrane formed by interfacial polymerization of pentaerythritol (PE) and trimesoyl chloride (TMC) . Appl. Surf. Sci. , 2017 . 416 152 - 159 . DOI: 10.1016/j.apsusc.2017.04.173 http://doi.org/10.1016/j.apsusc.2017.04.173 .

Wang, J.; Wang, Z.; Liu, Y.; Wang, J.; Wang, S. . Surface modification of NF membrane with zwitterionic polymer to improve anti-biofouling property . J. Membr. Sci. , 2016 . 514 407 - 417 . DOI: 10.1016/j.memsci.2016.05.014 http://doi.org/10.1016/j.memsci.2016.05.014 .

Hu, L.; Zhang, S.; Han, R.; Jian, X. . Preparation and performance of novel thermally stable polyamide/PPENK composite nanofiltration membranes . Appl. Surf. Sci. , 2012 . 258 9047 - 9053 . DOI: 10.1016/j.apsusc.2012.05.153 http://doi.org/10.1016/j.apsusc.2012.05.153 .

Shen, K.; Cheng, C.; Zhang, T.; Wang, X. . High performance polyamide composite nanofiltration membranes via reverse interfacial polymerization with the synergistic interaction of gelatin interlayer and trimesoyl chloride . J. Membr. Sci. , 2019 . 588 117192 DOI: 10.1016/j.memsci.2019.117192 http://doi.org/10.1016/j.memsci.2019.117192 .

Huang, Y.; Sun, J.; Wu, D.; Feng, X. . Layer-by-layer self-assembled chitosan/PAA nanofiltration membranes . Sep. Purif. Technol. , 2018 . 207 142 - 150 . DOI: 10.1016/j.seppur.2018.06.032 http://doi.org/10.1016/j.seppur.2018.06.032 .

Su, C.; Ma, S. M.; Liu, G. X.; Yang, S. G. . Dewetting behavior of hydrogen bonded polymer complex film under hydrothermal condition . Chinese J. Polym. Sci. , 2018 . 36 1036 - 1042 . DOI: 10.1007/s10118-018-2109-8 http://doi.org/10.1007/s10118-018-2109-8 .

Liu, K.; Yang, C. M.; Yang, B. M.; Zhang, L.; Huang, W. C.; Ouyang, X. P.; Qi, F. G.; Zhao, N.; Bian, F. G. . Directed self-assembly of vertical PS- b -PMMA nanodomains grown on multilayered polyelectrolyte films . Chinese J. Polym. Sci. , 2020 . 38 92 - 99 . DOI: 10.1007/s10118-019-2315-z http://doi.org/10.1007/s10118-019-2315-z .

Zhang, X.; Xu, Y.; Zhang, X.; Wu, H.; Shen, J.; Chen, R.; Xiong, Y.; Li, J.; Guo, S. . Progress on the layer-by-layer assembly of multilayered polymer composites: strategy, structural control and applications . Prog. Polym. Sci. , 2019 . 89 76 - 107 . DOI: 10.1016/j.progpolymsci.2018.10.002 http://doi.org/10.1016/j.progpolymsci.2018.10.002 .

Guo, D.; Xiao, Y.; Li, T.; Zhou, Q.; Shen, L.; Li, R.; Xu, Y.; Lin, H. . Fabrication of high-performance composite nanofiltration membranes for dye wastewater treatment: mussel-inspired layer-by-layer self-assembly . J. Colloid Interf. Sci. , 2020 . 560 273 - 283 . DOI: 10.1016/j.jcis.2019.10.078 http://doi.org/10.1016/j.jcis.2019.10.078 .

Zheng, M.; Long, T. J.; Chen, X. L.; Sun, J. Q. . Humidity-responsive bilayer actuators comprised of porous and nonporous poly(acrylic acid)/poly(allylamine hydrochloride) films . Chinese J. Polym. Sci. , 2018 . 37 52 - 58 . .

Silva, V.; Martín, Á.; Martínez, F.; Malfeito, J.; Prádanos, P.; Palacio, L.; Hernández, A. . Electrical characterization of NF membranes a modified model with charge variation along the pores . Chem. Eng. Sci. , 2011 . 66 2898 - 2911 . .

Lv, Y.; Du, Y.; Chen, Z. X.; Qiu, W. Z.; Xu, Z. K. . Nanocomposite membranes of polydopamine/electropositive nanoparticles/polyethyleneimine for nanofiltration . J. Membr. Sci. , 2018 . 545 99 - 106 . DOI: 10.1016/j.memsci.2017.09.066 http://doi.org/10.1016/j.memsci.2017.09.066 .

Arı, G. A.; Özcan, Z. . A novel approach for stable anion exchange membrane: self-assembled multilayer formation on the membrane via LbL method . Synth. Met. , 2016 . 220 269 - 275 . DOI: 10.1016/j.synthmet.2016.06.022 http://doi.org/10.1016/j.synthmet.2016.06.022 .

Ilyas, S.; Abtahi, S. M.; Akkilic, N.; Roesink, H. D. W.; de Vos, W. M. . Weak polyelectrolyte multilayers as tunable separation layers for micro-pollutant removal by hollow fiber nanofiltration membranes . J. Membr. Sci. , 2017 . 537 220 - 228 . DOI: 10.1016/j.memsci.2017.05.027 http://doi.org/10.1016/j.memsci.2017.05.027 .

Naseem, A.; Tabasum, S.; Zia, K. M.; Zuber, M.; Ali, M.; Noreen, A. . Lignin-derivatives based polymers, blends and composites: a review . Int. J. Biol. Macromol. , 2016 . 93 296 - 313 . DOI: 10.1016/j.ijbiomac.2016.08.030 http://doi.org/10.1016/j.ijbiomac.2016.08.030 .

Zhang, W.; Yang, P.; Li, X.; Zhu, Z.; Chen, M.; Zhou, X. . Electrospun lignin-based composite nanofiber membrane as high-performance absorbent for water purification . Int. J. Biol. Macromol. , 2019 . 141 747 - 755 . DOI: 10.1016/j.ijbiomac.2019.08.221 http://doi.org/10.1016/j.ijbiomac.2019.08.221 .

Ma, J.; Khan, M. A.; Xia, M.; Fu, C.; Zhu, S.; Chu, Y.; Lei, W.; Wang, F. . Effective adsorption of heavy metal ions by sodium lignosulfonate reformed montmorillonite . Int. J. Biol. Macromol. , 2019 . 138 188 - 197 . DOI: 10.1016/j.ijbiomac.2019.07.075 http://doi.org/10.1016/j.ijbiomac.2019.07.075 .

Guo, X.; Zhang, S.; Shan, X. Q. . Adsorption of metal ions on lignin . J. Hazard Mater. , 2008 . 151 134 - 42 . DOI: 10.1016/j.jhazmat.2007.05.065 http://doi.org/10.1016/j.jhazmat.2007.05.065 .

Yang, H. C.; Liao, K. J.; Huang, H.; Wu, Q. Y.; Wan, L. S.; Xu, Z. K. . Mussel-inspired modification of a polymer membrane for ultra-high water permeability and oil-in-water emulsion separation . J. Mater. Chem. A , 2014 . 2 10225 - 10230 . DOI: 10.1039/C4TA00143E http://doi.org/10.1039/C4TA00143E .

Sun, Q.; Tong, Z.; Wang, C.; Ren, B.; Liu, X.; Zeng, F. . Charge density threshold for LbL self-assembly and small molecule diffusion in polyelectrolyte multilayer films . Polymer , 2005 . 46 4958 - 4966 . DOI: 10.1016/j.polymer.2005.03.091 http://doi.org/10.1016/j.polymer.2005.03.091 .

Rojas, O. J.; Claesson, P, M.; Muller, D.; Neuman, R. D. . The effect of salt concentration on adsorption of low-charge-density polyelectrolytes and interactions between polyelectrolyte-coated surfaces . J. Colloid. Interf. Sci. , 1998 . 205 77 - 88 . DOI: 10.1006/jcis.1998.5596 http://doi.org/10.1006/jcis.1998.5596 .

Zhang, L.; Guo, H.; Sun, J. . Salt effects on the structural tailoring of layer-by-layer assembled polyelectrolyte complexes and salt-containing polyelectrolyte films . Thin Solid Films , 2018 . 653 258 - 266 . DOI: 10.1016/j.tsf.2018.03.048 http://doi.org/10.1016/j.tsf.2018.03.048 .

Samanta, T.; Mukherjee, M. . Effect of added salt on morphology of ultrathin polyelectrolyte films . Polymer , 2012 . 53 5393 - 5403 . DOI: 10.1016/j.polymer.2012.09.038 http://doi.org/10.1016/j.polymer.2012.09.038 .

Gong, X.; Gao, C. . Influence of salt on assembly and compression of PDADMAC/PSSMA polyelectrolyte multilayers . Phys. Chem. Chem. Phys. , 2009 . 11 11577 - 11586 . DOI: 10.1039/b915335g http://doi.org/10.1039/b915335g .

McAloney, R. A.; Sinyor, M.; Dudnik, V.; Goh, M. C. . Atomic force microscopy studies of salt effects on polyelectrolyte multilayer film morphology . Langmuir , 2001 . 17 6655 - 6663 . DOI: 10.1021/la010136q http://doi.org/10.1021/la010136q .

Zhang, L.; Zheng, M.; Liu, X.; Sun, J. . Layer-by-layer assembly of salt-containing polyelectrolyte complexes for the fabrication of dewetting-induced porous coatings . Langmuir , 2011 . 27 1346 - 1352 . DOI: 10.1021/la103953n http://doi.org/10.1021/la103953n .

Zarei, F.; Moattari, R. M.; Rajabzadeh, S.; Bagheri, M.; Taghizadeh, A.; Mohammadi, T.; Matsuyama, H. . Preparation of thin film composite nano-filtration membranes for brackish water softening based on the reaction between functionalized UF membranes and polyethyleneimine . J. Membr. Sci. , 2019 . 588 117207 DOI: 10.1016/j.memsci.2019.117207 http://doi.org/10.1016/j.memsci.2019.117207 .

Yang, Y.; Lan, Q.; Wang, Y. . Gradient nanoporous phenolics as substrates for high-flux nanofiltration membranes by layer-by-layer assembly of polyelectrolytes . Chinese J. Chem. Eng. , 2020 . 28 114 - 124 . DOI: 10.1016/j.cjche.2019.04.011 http://doi.org/10.1016/j.cjche.2019.04.011 .

Menne, D.; Kamp, J.; Wong, J. E.; Wessling, M. . Precise tuning of salt retention of backwashable polyelectrolyte multilayer hollow fiber nanofiltration membranes . J. Membr. Sci. , 2016 . 499 396 - 405 . DOI: 10.1016/j.memsci.2015.10.058 http://doi.org/10.1016/j.memsci.2015.10.058 .

Cheng, W.; Liu, C.; Tong, T.; Epsztein, R.; Sun, M.; Verduzco, R.; Ma, J.; Elimelech, M. . Selective removal of divalent cations by polyelectrolyte multilayer nanofiltration membrane: role of polyelectrolyte charge, ion size, and ionic strength . J. Membr. Sci. , 2018 . 559 98 - 106 . DOI: 10.1016/j.memsci.2018.04.052 http://doi.org/10.1016/j.memsci.2018.04.052 .

Zhao, S.; Wang, Z. . A loose nano-filtration membrane prepared by coating HPAN UF membrane with modified PEI for dye reuse and desalination . J. Membr. Sci. , 2017 . 524 214 - 224 . DOI: 10.1016/j.memsci.2016.11.035 http://doi.org/10.1016/j.memsci.2016.11.035 .

DuChanois, R. M.; Epsztein, R.; Trivedi, J. A.; Elimelech, M. . Controlling pore structure of polyelectrolyte multilayer nanofiltration membranes by tuning polyelectrolyte-salt interactions . J. Membr. Sci. , 2019 . 581 413 - 420 . DOI: 10.1016/j.memsci.2019.03.077 http://doi.org/10.1016/j.memsci.2019.03.077 .

Liu, H.; Fu, S.; Li, H.; Zhan, H. . Layer-by-layer assembly of lignosulfonates for hydrophilic surface modification . Ind. Crop. Prod. , 2009 . 30 287 - 291 . DOI: 10.1016/j.indcrop.2009.05.006 http://doi.org/10.1016/j.indcrop.2009.05.006 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

High-performance Layer-by-Layer Processed Polymer Solar Cell via Solid Additive of Thermally-activated Delay Fluorescence

Biomimetic Design of Porous Polymerized High Internal Phase Emulsion (PolyHIPE)/Hydrogel Solar Evaporator for Salt-resistant Desalination and Energy Generation

Fe3+-coordinated Dual-crosslinked Conjugated Polymer Hydrogels with Ultrahigh Evaporation Rate for Efficient Desalination and Sustainable Agriculture

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

Nanofiltration Membranes via Layer-by-layer Assembly and Cross-linking of Polyethyleneimine/Sodium Lignosulfonate for Heavy Metal Removal

Nanofiltration Membranes via Layer-by-layer Assembly and Cross-linking of Polyethyleneimine/Sodium Lignosulfonate for Heavy Metal Removal

DOI：10.1007/s10118-020-2422-x

摘要

Abstract

关键词

Keywords

references