Fabrication of Silver Yolk@Porous Janus Polymer Shell Nanospheres for Synergistic Catalysis

Shao-hong Liu; Yan-huan Lin; Wen-tai Guo; Shi-mei Li; Wei-cong Mai; Hui Wang; Ruo-wen Fu; Ding-cai Wu

doi:10.1007/s10118-020-2419-5

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Fabrication of Silver Yolk@Porous Janus Polymer Shell Nanospheres for Synergistic Catalysis

ARTICLE | Updated：2020-05-12

- Fabrication of Silver Yolk@Porous Janus Polymer Shell Nanospheres for Synergistic Catalysis
- Fabrication of Silver Yolk@Porous Janus Polymer Shell Nanospheres for Synergistic Catalysis
- Chinese Journal of Polymer Science 2020年38卷第8期页码：847-852
- Affiliations：
  
  a.Materials Science Institute, PCFM Lab and GDHPPC Lab, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
  b.Department of Colorectal Surgery, Guangdong Provincial Key Laboratory of Colorectal and Pelvic Floor Diseases, The Sixth Affiliated Hospital of Sun Yat-sen University, Guangzhou 510655, China
- Author bio：
  
  wang89@mail.sysu.edu.cn (H.W.)
  cesfrw@mail.sysu.edu.cn (R.W.F.)
  wudc@mail.sysu.edu.cn (D.C.W.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51925308, U1601206, 51672313, 51702370, and 51872336), National Program for Support of Top-notch Young Professionals, Leading Scientific, Technical and Innovation Talents of Guangdong Special Support Program (No. 2017TX04C248), Fundamental Research Funds for the Central Universities (Nos. 18lgzd10 and17lgpy83), and the Science and Technology Program of Guangzhou (No. 201704020059).
- DOI：10.1007/s10118-020-2419-5
  中图分类号： M
- 收稿：2019-11-23，
  
  修回：2020-2-28，
  
  录用：2020-3-9，
  
  网络首发：2020-05-12，
  
  纸质出版：2020-08
- Accepted：
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Liu, S. H.; Lin, Y. H.; Guo, W. T.; Li, S. M.; Mai, W. C.; Wang, H.; Fu, R. W.; Wu, D. C. Fabrication of silver yolk@porous Janus polymer shell nanospheres for synergistic catalysis. Chinese J. Polym. Sci. 2020, 38, 847–852

Shao-hong Liu, Yan-huan Lin, Wen-tai Guo, et al. Fabrication of Silver Yolk@Porous Janus Polymer Shell Nanospheres for Synergistic Catalysis[J]. Chinese Journal of Polymer Science, 2020, 38(8): 847-852.
Liu, S. H.; Lin, Y. H.; Guo, W. T.; Li, S. M.; Mai, W. C.; Wang, H.; Fu, R. W.; Wu, D. C. Fabrication of silver yolk@porous Janus polymer shell nanospheres for synergistic catalysis. Chinese J. Polym. Sci. 2020, 38, 847–852 DOI： 10.1007/s10118-020-2419-5.

Shao-hong Liu, Yan-huan Lin, Wen-tai Guo, et al. Fabrication of Silver Yolk@Porous Janus Polymer Shell Nanospheres for Synergistic Catalysis[J]. Chinese Journal of Polymer Science, 2020, 38(8): 847-852. DOI： 10.1007/s10118-020-2419-5.

摘要

Abstract

Yolk-shell nanostructures have recently attracted tremendous research interests in various areas because of their unique structural merits. Currently

there is an urgent need for developing porous shells with multifunctional features to enhance their performance in various applications. Herein

advanced yolk-shell nanospheres have been facilely prepared by encapsulating silver nanoparticles with porous Janus polymer shells that consist of a hypercrosslinked polystyrene (

PS) outer layer and a tethered poly(acrylic acid) (PAA) brush lining. The

PS outer layer possesses well-developed porosity as mass diffusion pathways. More importantly

the tethered PAA brushes with customized carboxyl groups exhibit great affinity toward specific species (

e.g.

cationic dyes)

leading to their enrichment from the bulk solution into the interior cavity. The unusual combination of highly porous outer layers with customizable inbuilt polymer linings in the porous Janus shells endows them with great promise for synergistically catalytic degradation of cationic dyes.

关键词

Keywords

references

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