Mechanical Properties, Crystallization and Biodegradation Behavior of the Polylactide/Poly(3-hydroxybutyrate-<italic style="font-style: italic">co</italic>-4-hydroxybutyrate)/Poly(butylene adipate-<italic style="font-style: italic">co</italic>-terephthalate) Blown Films

Xiang-Yu Wang; Hong-Wei Pan; Shi-Ling Jia; Zeng-Wen Cao; Li-Jing Han; Hui-Liang Zhang; Li-Song Dong

doi:10.1007/s10118-020-2418-6

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Mechanical Properties, Crystallization and Biodegradation Behavior of the Polylactide/Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)/Poly(butylene adipate-co-terephthalate) Blown Films

ARTICLE | Updated：2020-05-19

- Mechanical Properties, Crystallization and Biodegradation Behavior of the Polylactide/Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)/Poly(butylene adipate-co-terephthalate) Blown Films
- Mechanical Properties, Crystallization and Biodegradation Behavior of the Polylactide/Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)/Poly(butylene adipate-co-terephthalate) Blown Films
- Chinese Journal of Polymer Science 2020年38卷第10期页码：1072-1081
- Affiliations：
  
  a.Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
  b.University of Science and Technology of China, Hefei 230026, China
  c.Zhejiang Zhongke Applied Chemistry Technology Co., Ltd., Hangzhou 310000, China
- Author bio：
  
  ljhan@ciac.ac.cn
- Funds：
  
  This work was financially supported by the fund of Science and Technology Bureau of Jilin Province of China (No. 20170204012SF), Chinese Academy of Sciences (Changchun Branch) (No. 2020SYHZ0002), Science and Technology Services Network Program of Chinese Academy of Sciences (STS Project) (No. KFJ-STS-ZDTP-082), and the National Science Foundation of Zhejiang Province of China (No. LQY19B040001).
- DOI：10.1007/s10118-020-2418-6
  中图分类号：
- 收稿：2020-01-14，
  
  修回：2020-3-4，
  
  录用：2020-3-5，
  
  网络首发：2020-05-19，
  
  纸质出版：2020-06-16
- Accepted：
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Wang, X. Y.; Pan, H. W.; Jia, S. L.; Cao, Z. W.; Han, L. J.; Zhang, H. L.; Dong, L. S. Mechanical properties, crystallization and biodegradation behavior of the polylactide/poly(3-hydroxybutyrate-, co,-4-hydroxybutyrate)/poly(butylene adipate-, co,-terephthalate) blown films. Chinese J. Polym. Sci. 2020, 38, 1072–1081

Xiang-Yu Wang, Hong-Wei Pan, Shi-Ling Jia, et al. Mechanical Properties, Crystallization and Biodegradation Behavior of the Polylactide/Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)/Poly(butylene adipate-co-terephthalate) Blown Films[J]. Chinese Journal of Polymer Science, 2020, 38(10): 1072-1081. DOI: 10.1007/s10118-020-2418-6.
Wang, X. Y.; Pan, H. W.; Jia, S. L.; Cao, Z. W.; Han, L. J.; Zhang, H. L.; Dong, L. S. Mechanical properties, crystallization and biodegradation behavior of the polylactide/poly(3-hydroxybutyrate-, co,-4-hydroxybutyrate)/poly(butylene adipate-, co,-terephthalate) blown films. Chinese J. Polym. Sci. 2020, 38, 1072–1081 DOI： 10.1007/s10118-020-2418-6.

Xiang-Yu Wang, Hong-Wei Pan, Shi-Ling Jia, et al. Mechanical Properties, Crystallization and Biodegradation Behavior of the Polylactide/Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)/Poly(butylene adipate-co-terephthalate) Blown Films[J]. Chinese Journal of Polymer Science, 2020, 38(10): 1072-1081. DOI: 10.1007/s10118-020-2418-6. DOI：

摘要

Abstract

Polylactide (PLA)

poly(3-hydroxybutyrate-

-4-hydroxybutyrate) (P(3HB-

-4HB))

and poly(butylene adipate-

-terephthalate) (PBAT) ternary blends were prepared by extrusion blending. The biodegradable PLA/P(3HB-

-4HB)/PBAT films were successfully obtained by using blown films technique. Excellent stiffness-toughness balance was achieved for 55/10/35 PLA/P(3HB-

-4HB)/PBAT film. The tensile strength reached 33.0 MPa (MD) and 23.5 MPa (TD)

the elongation at break exceeded 130 %

and tear strength exceeded 110 kN/m. The Young′s modulus as low as about 1800 MPa also met packaging applications. SEM observations revealed rough and long ligaments

indicating that the tear specimens were broken yieldingly. The addition of PBAT elastomers was the main reason for the improved toughness of the film. From DMA and SEM analysis

it was demonstrated that PLA

P(3HB-

-4HB)

and PBAT were partially compatible. With increasing P(3HB-

-4HB) content

the melt and cold crystallization of PLA was promoted. The enzymatic degradation experiments indicated that the films had good biodegradability. These findings gave important implications for designing and manufacturing biodegradation package of high biological carbon content.

关键词

Keywords

references

Bartczak, Z.; Galeski, A.; Kowalczuk, M.; Sobota, M.; Malinovoski, R. . Tough blends of poly(lactide) and amorphous poly([ R , S ]-3-hydroxy butyrate)-morphology and properties . Eur. Polym. J. , 2013 . 49 3630 - 3641 . DOI: 10.1016/j.eurpolymj.2013.07.033 http://doi.org/10.1016/j.eurpolymj.2013.07.033 .

Liu, Y. T.; Cao, L. M.; Yuan, D. S.; Chen, Y. K. . Design of super-tough co-continuous PLA/NR/SiO 2 TPVs with balanced stiffness-toughness based on reinforced rubber and interfacial compatibilization . Compos. Sci. Technol. , 2018 . 165 231 - 239 . DOI: 10.1016/j.compscitech.2018.07.005 http://doi.org/10.1016/j.compscitech.2018.07.005 .

Koh, J. J.; Zhang, X. W.; Kong, J. H.; He, C. B. . Compatibilization of multicomponent composites through a transitioning phase: interfacial tensions considerations . Compos. Sci. Technol. , 2018 . 164 34 - 43 . DOI: 10.1016/j.compscitech.2018.05.030 http://doi.org/10.1016/j.compscitech.2018.05.030 .

Mazidi, M. M.; Edalat, A.; Berahman, R.; Hosseini, F. S. . Highly-toughened polylactide- (PLA-) based ternary blends with significantly enhanced glass transition and melt strength: tailoring the interfacial interactions, phase morphology, and performance . Macromolecules , 2018 . 51 4298 - 4314 . DOI: 10.1021/acs.macromol.8b00557 http://doi.org/10.1021/acs.macromol.8b00557 .

Pagano, N.; Campana, G.; Fiorini, M.; Morelli, R. . Laser transmission welding of polylactide to aluminium thin films for applications in the food-packaging industry . Opt. Laser Technol. , 2017 . 91 80 - 84 . DOI: 10.1016/j.optlastec.2016.12.014 http://doi.org/10.1016/j.optlastec.2016.12.014 .

Cerqueira, B. B. S.; Lasham, A.; Shelling, A. N.; Al-Kassas, R. . Development of biodegradable PLGA nanoparticles surface engineered with hyaluronic acid for targeted delivery of paclitaxel to triple negative breast cancer cells . Mater. Sci. Eng. C , 2017 . 76 593 - 600 . DOI: 10.1016/j.msec.2017.03.121 http://doi.org/10.1016/j.msec.2017.03.121 .

Jaimes-Aguirre, L.; Morales-Avila, E.; Ocampo-García, B. E.; Medina, L. A.; López-Téllez, G.; Gibbens-Bandala, B. V.; Izquierdo-Sánchez, V. . Biodegradable poly(D,L-lactide- co -glycolide)/poly(L-gamma-glutamic acid) nanoparticles conjugated to folic acid for targeted delivery of doxorubicin . Mater. Sci. Eng. C , 2017 . 76 743 - 751 . DOI: 10.1016/j.msec.2017.03.145 http://doi.org/10.1016/j.msec.2017.03.145 .

Arraiza, A. L.; Sarasua, J. R.; Verdu. J.; Colin, X. . Rheological behavior and modeling of thermal degradation of poly(epsilon-caprolactone) and poly(L-lactide) . Int. Polym. Process. , 2007 . 22 389 - 394 . DOI: 10.3139/217.2067 http://doi.org/10.3139/217.2067 .

Al-Itry, R.; Lamnawar, K.; Maazouz. A. . Improvement of thermal stability, rheological and mechanical properties of PLA, PBAT and their blends by reactive extrusion with functionalized epoxy . Polym. Degrad. Stab. , 2012 . 97 1898 - 1914 . DOI: 10.1016/j.polymdegradstab.2012.06.028 http://doi.org/10.1016/j.polymdegradstab.2012.06.028 .

Jia, S. L.; Chen, Y. J.; Yu, Y. L.; Han, L. J.; Zhang, H. L.; Dong. L. S. . Effect of ethylene/butyl methacrylate/glycidyl methacrylate terpolymer on toughness and biodegradation of poly(L-lactic acid) . Int. J. Biol. Macromol. , 2019 . 127 415 - 424 . DOI: 10.1016/j.ijbiomac.2019.01.068 http://doi.org/10.1016/j.ijbiomac.2019.01.068 .

Dong, W.; Zou, B.; Yan, Y.; Ma, P.; Chen. M. . Effect of chain-extenders on the properties and hydrolytic degradation behavior of the poly(lactide)/poly(butylene adipate- co -terephthalate) blends . Int. J. Mol. Sci. , 2013 . 14 20189 - 20203 . DOI: 10.3390/ijms141020189 http://doi.org/10.3390/ijms141020189 .

Kulinski, Z.; Piorkowska, E. . Crystallization, structure and properties of plasticized poly(L-lactide) . Polymer , 2005 . 46 10290 - 10300 . DOI: 10.1016/j.polymer.2005.07.101 http://doi.org/10.1016/j.polymer.2005.07.101 .

Ljungberg, N.; Wesslen, B. . The effects of plasticizers on the dynamic mechanical and thermal properties of poly(lactic acid) . J. Appl. Polym. Sci. , 2002 . 86 1227 - 1234 . DOI: 10.1002/app.11077 http://doi.org/10.1002/app.11077 .

Zhang, H. L.; Fang, J. Y.; Ge, H. H.; Han, L. J.; Wang, X. M.; Hao, Y. P.; Han, C. Y.; Dong, L. S. . Thermal, mechanical, and rheological properties of polylactide/poly(1,2-propylene glycol adipate) . Polym. Eng. Sci. , 2013 . 53 112 - 118 . DOI: 10.1002/pen.23238 http://doi.org/10.1002/pen.23238 .

Zhang, H. L.; Liang, H. Y.; Bian, J. J.; Hao, Y. P.; Han, L. J.; Wang, X. M.; Zhang, G. B.; Liu, S. R.; Dong, L. S. . Influence of acrylic impact modifier on plasticized polylactide blown films . Polym. Int. , 2014 . 63 1076 - 1084 . DOI: 10.1002/pi.4615 http://doi.org/10.1002/pi.4615 .

Ge, H. H.; Yang, F.; Hao, Y. P.; Wu, G. F.; Zhang, H. L.; Dong, L. S. . Thermal, mechanical, and rheological properties of plasticized poly(L-lactic acid) . J. Appl. Polym. Sci. , 2013 . 127 2832 - 2839 . DOI: 10.1002/app.37620 http://doi.org/10.1002/app.37620 .

Wang, L.; Ma, W.; Gross, R. A.; McCarthy, S. P. . Reactive compatibilization of biodegradable blends of poly(lactic acid) and poly(epsilon-caprolactone) . Polym. Degrad. Stab. , 1998 . 59 161 - 168 . DOI: 10.1016/S0141-3910(97)00196-1 http://doi.org/10.1016/S0141-3910(97)00196-1 .

Sun, S. L.; Zhang, M. Y.; Zhang, H. X.; Zhang, X. M. . Polylactide toughening with epoxy-functionalized grafted acrylonitrile-butadiene-styrene particles . J. Appl. Polym. Sci. , 2011 . 122 2992 - 2999 . DOI: 10.1002/app.34111 http://doi.org/10.1002/app.34111 .

Abdelwahab, M. A.; Taylor, S.; Misra, M.; Mohanty, A. K. . Thermo-mechanical characterization of bioblends from polylactide and poly(butylene adipate- co -terephthalate) and lignin . Macromol. Mater. Eng. , 2015 . 300 299 - 311 . DOI: 10.1002/mame.201400241 http://doi.org/10.1002/mame.201400241 .

Zolali, A. M.; Favis, B. D. . Compatibilization and toughening of co-continuous ternary blends via partially wet droplets at the interface . Polymer , 2017 . 114 277 - 288 . DOI: 10.1016/j.polymer.2017.02.093 http://doi.org/10.1016/j.polymer.2017.02.093 .

Ma, P.; Cai, X.; Zhang, Y.; Wang, S.; Dong, W.; Chen, M.; Lemstra, P. J. . In - situ compatibilization of poly(lactic acid) and poly(butylene adipate- co -terephthalate) blends by using dicumyl peroxide as a free-radical initiator . Polym. Degrad. Stab. , 2014 . 102 145 - 151 . DOI: 10.1016/j.polymdegradstab.2014.01.025 http://doi.org/10.1016/j.polymdegradstab.2014.01.025 .

Yeh, J. T.; Tsou, C. H.; Huang, C. Y.; Chen, K. N.; Wu, C. S.; Chai, W. L. . Compatible and crystallization properties of poly(lactic acid)/poly(butylene adipate- co -terephthalate) blends . J. Appl. Polym. Sci. , 2010 . 116 680 - 687 . .

Li, K.; Peng, J.; Turng, L. S.; Huang, H. X. . Dynamic rheological behavior and morphology of polylactide/poly(butylenes adipate- co -terephthalate) blends with various composition ratios . Adv. Polym. Technol. , 2011 . 30 150 - 157 . DOI: 10.1002/adv.20212 http://doi.org/10.1002/adv.20212 .

Zhang, N. W.; Wang, Q. F.; Ren, J.; Wang, L. . Preparation and properties of biodegradable poly(lactic acid)/poly(butylene adipate- co -terephthalate) blend with glycidyl methacrylate as reactive processing agent . J. Mater. Sci. , 2009 . 44 250 - 256 . DOI: 10.1007/s10853-008-3049-4 http://doi.org/10.1007/s10853-008-3049-4 .

Nitschke, M.; Costa, S. G. V. A. O.; Contiero, J. . Rhamnolipids and PHAs: recent reports on pseudomonas-derived molecules of increasing industrial interest . Process Biochem. , 2011 . 46 621 - 630 . DOI: 10.1016/j.procbio.2010.12.012 http://doi.org/10.1016/j.procbio.2010.12.012 .

Saito, Y.; Doi, Y. . Microbial synthesis and properties of poly(3-hydroxybutyrate- co -4-hydroxybutyrate) in Comamonas-acidovorans . Int. J. Biol. Macromol. , 1994 . 16 99 - 104 . DOI: 10.1016/0141-8130(94)90022-1 http://doi.org/10.1016/0141-8130(94)90022-1 .

Chen, G. Q.; Wu, Q.; Zhao, K.; Yu, P. H. . Functional polyhydroxyalkanoates synthesized by microorganisms . Chinese J. Polym. Sci. , 2000 . 18 389 - 396 . .

Ou, W. F.; Qiu, H. D.; Chen, Z. F.; Xu, K. T. . Biodegradable block poly(ester-urethane)s based on poly(3-hydroxybutyrate- co -4-hydroxybutyrate) copolymers . Biomaterials , 2011 . 32 3178 - 3188 . DOI: 10.1016/j.biomaterials.2011.01.031 http://doi.org/10.1016/j.biomaterials.2011.01.031 .

Weng, Y. X.; Wang, L.; Zhang, M.; Wang, X. L.; Wang, Y. Z. . Biodegradation behavior of P(3HB, 4HB)/PLA blends in real soil environments . Polym. Test. , 2013 . 32 60 - 70 . DOI: 10.1016/j.polymertesting.2012.09.014 http://doi.org/10.1016/j.polymertesting.2012.09.014 .

Han, L. J.; Han, C. Y.; Zhang, H. L.; Chen, S.; Dong, L. S. . Morphology and properties of biodegradable and biosourced polylactide blends with poly(3-hydroxybutyrate- co -4-hydroxybutyrate) . Polym. Compos. , 2012 . 33 850 - 859 . DOI: 10.1002/pc.22213 http://doi.org/10.1002/pc.22213 .

Zhang, K. Y.; Mohanty, A. K.; Misra, M. . Fully Biodegradable and biorenewable ternary blends from polylactide, poly(3-hydroxybutyrate- co -hydroxyvalerate) and poly(butylene succinate) with balanced properties . ACS Appl. Mater. Interfaces , 2012 . 4 3091 - 3101 . DOI: 10.1021/am3004522 http://doi.org/10.1021/am3004522 .

Su, Z. Z.; Li, Q. Y.; Liu, Y. J.; Hu, G. H.; Wu, C. F. . Compatibility and phase structure of binary blends of poly(lactic acid) and glycidyl methacrylate grafted poly(ethylene octane) . Eur. Polym. J. , 2009 . 45 2428 - 2433 . DOI: 10.1016/j.eurpolymj.2009.04.028 http://doi.org/10.1016/j.eurpolymj.2009.04.028 .

Finkenstadt, V. L.; Liu, C. K.; Cooke, P. H.; Liu, L. S.; Willett, J. L. J. . Mechanical property characterization of plasticized sugar beet pulp and poly(lactic acid) green composites using acoustic emission and confocal microscopy . Polym. Environ. , 2008 . 16 19 - 26 . DOI: 10.1007/s10924-008-0085-8 http://doi.org/10.1007/s10924-008-0085-8 .

Lazzeri, A.; Bucknall, C. B. . Dilatational bands in rubber-toughened polymers . J. Mater. Sci. , 1993 . 28 6799 - 6808 . DOI: 10.1007/BF00356433 http://doi.org/10.1007/BF00356433 .

Jiang, L.; Wolcott, M. P.; Zhang, J. W. . Study of biodegradable polyactide/poly(butylene adipate- co -terephthalate) blends . Biomacromolecules , 2006 . 7 199 - 207 . DOI: 10.1021/bm050581q http://doi.org/10.1021/bm050581q .

Lu, J. M.; Qiu, Z. B.; Yang, W. T. . Fully biodegradable blends of poly(L-lactide) and poly(ethylene succinate): miscibility, crystallization, and mechanical properties . Polymer , 2007 . 48 4196 - 4204 . DOI: 10.1016/j.polymer.2007.05.035 http://doi.org/10.1016/j.polymer.2007.05.035 .

Dollase, T.; Wilhelm. M.; Spiess H. W.; Yagen, Y.; Yerushalmi-Rozen, R. . Effect of interfaces on the crystallization behavior of PDMS . Interface Sci. , 2003 . 11 199 - 209 . DOI: 10.1023/A:1022174712707 http://doi.org/10.1023/A:1022174712707 .

Mayes, A. M. . Glass-transition of amorphous polymer surfaces . Macromolecules , 1994 . 27 3114 - 3115 . DOI: 10.1021/ma00089a033 http://doi.org/10.1021/ma00089a033 .

Roth, C. B.; McNerny, K. L.; Jager, W. F.; Torkelson, J. M. . Eliminating the enhanced mobility at the free surface of polystyrene: fluorescence studies of the glass transition temperature in thin bilayer films of immiscible polymers . Macromolecules , 2007 . 40 2568 - 2574 . DOI: 10.1021/ma062864w http://doi.org/10.1021/ma062864w .

Factor, B. J.; Russell, T. P.; Toney, M. F. . Surface-induced ordering of an aromatic polyimide . Phys. Rev. Lett. , 1991 . 66 1181 - 1184 . DOI: 10.1103/PhysRevLett.66.1181 http://doi.org/10.1103/PhysRevLett.66.1181 .

Sakai, F.; Nishikawa, K.; Inoue, Y.; Yazawa, K. . Nucleation enhancement effect in poly(L-lactide) (PLLA)/poly(epsilon-caprolactone) (PCL) blend induced by locally activated chain mobility resulting from limited miscibility . Macromolecules , 2009 . 42 8335 - 8342 . DOI: 10.1021/ma901547a http://doi.org/10.1021/ma901547a .

Lee, D. H.; Park, K. H.; Kim, Y. H.; Lee, H. S. . Surface chain orientation during crystallization induction period of poly(pentamethylene 2,6-naphthalate) studied with polarized FTIR-ATR . Macromolecules , 2007 . 40 6277 - 6282 . DOI: 10.1021/ma070044t http://doi.org/10.1021/ma070044t .

Kunioka, M.; Tamaki, A.; Doi, Y. . Crystalline and thermal-properties of bacterial copolyesters-poly(3-hydroxybutyrate- co -3-hydroxyvalerate) and poly(3-hydroxybutyrate- co -4-hydroxybutyrate) . Macromolecules , 1989 . 22 694 - 697 . DOI: 10.1021/ma00192a031 http://doi.org/10.1021/ma00192a031 .

Barham, P. J.; Keller, A.; Otun, E. L.; Holmes, P. A. . Crystallization and morphology of a bacterial thermoplastic-poly-3-hydroxybutyrate . J. Membr. Sci. , 1984 . 19 2781 - 2794 . .

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DOI：10.1007/s10118-020-2418-6

摘要

Abstract

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Keywords

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