Antistatic Structural Color and Photoluminescent Membranes from Co-assembling Cellulose Nanocrystals and Carbon Nanomaterials for Anti-counterfeiting

Si-Yuan Liu; Yan-Bin Gong; Shan Ma; Yu-Huan Wang; Lin Gan; Jin Huang

doi:10.1007/s10118-020-2414-x

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Antistatic Structural Color and Photoluminescent Membranes from Co-assembling Cellulose Nanocrystals and Carbon Nanomaterials for Anti-counterfeiting

ARTICLE | Updated：2020-05-13

- Antistatic Structural Color and Photoluminescent Membranes from Co-assembling Cellulose Nanocrystals and Carbon Nanomaterials for Anti-counterfeiting
- Antistatic Structural Color and Photoluminescent Membranes from Co-assembling Cellulose Nanocrystals and Carbon Nanomaterials for Anti-counterfeiting
- Chinese Journal of Polymer Science 2020年38卷第10期页码：1061-1071
- Affiliations：
  
  a.School of Chemistry and Chemical Engineering, Chongqing Key Laboratory of Soft-Matter Material Chemistry and Function Manufacturing, and “the Belt and Road (B&R)” International Joint Research Laboratory of Sustainable Materials, Southwest University, Chongqing 400715, China
  b.College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China
- Author bio：
  
  swucgl@swu.edu.cn (L.G.)
  huangjin2015@swu.edu.cn or huangjin@iccas.ac.cn (J.H.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51973175 and 51603171), the Project for Chongqing University Innovation Research Group (No. CXQT19008), the Chongqing Talent Plan for Innovation and Entrepreneurship Demonstration Team (No. CQYC201903243), and the Key Laboratory of Polymeric Composite & Functional Materials of Ministry of Education (No. PCFM201605).
- DOI：10.1007/s10118-020-2414-x
  中图分类号：
- 收稿：2020-01-06，
  
  修回：2020-2-26，
  
  录用：2020-2-28，
  
  网络首发：2020-05-13，
  
  纸质出版：2020-06-16
- Accepted：
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Liu, S. Y.; Gong, Y. B.; Ma, S.; Wang, Y. H.; Gan, L.; Huang, J. Antistatic structural color and photoluminescent membranes from co-assembling cellulose nanocrystals and carbon nanomaterials for anti-counterfeiting. Chinese J. Polym. Sci. 2020, 38, 1061–1071

Si-Yuan Liu, Yan-Bin Gong, Shan Ma, et al. Antistatic Structural Color and Photoluminescent Membranes from Co-assembling Cellulose Nanocrystals and Carbon Nanomaterials for Anti-counterfeiting[J]. Chinese Journal of Polymer Science, 2020, 38(10): 1061-1071.
Liu, S. Y.; Gong, Y. B.; Ma, S.; Wang, Y. H.; Gan, L.; Huang, J. Antistatic structural color and photoluminescent membranes from co-assembling cellulose nanocrystals and carbon nanomaterials for anti-counterfeiting. Chinese J. Polym. Sci. 2020, 38, 1061–1071 DOI： 10.1007/s10118-020-2414-x.

Si-Yuan Liu, Yan-Bin Gong, Shan Ma, et al. Antistatic Structural Color and Photoluminescent Membranes from Co-assembling Cellulose Nanocrystals and Carbon Nanomaterials for Anti-counterfeiting[J]. Chinese Journal of Polymer Science, 2020, 38(10): 1061-1071. DOI： 10.1007/s10118-020-2414-x.

摘要

Abstract

Static charges on optical anti-counterfeiting membranes may lead to materials structural changes

dust stain aggravation

and misreading of optical information. Incorporating conductive particles is a common way to transfer accumulative charges

but the key issue is how to achieve high dispersion and effective distribution of particles. According to the strategy of assembly-induced structural colors

cellulose nanocrystals (CNCs) were employed as a solid emulsifier to stabilize hydrophobic carbon nanoparticles (CNPs) in aqueous media; subsequently

by solvent-evaporation-modulated co-assembly under a condition of 30 °C and 20 RH%

the binary suspensions containing 2 wt% CNC and CNPs with the equivalent concentration relative to CNC ranged from 1:40 to 1:10 were used to prepare antistatic composite membranes. Surface chemistry regulation of CNCs was applied to optimize the dispersibility of CNPs and the orientation of assembled CNC arrays

and the hydrophilic CNCs were more favorable for dispersion and assembly of binary suspension systems. Meanwhile

one-dimension carbon nanotube (CNT) and zero-dimension carbon black (CB) were found to show better dispersibility than two-dimension graphene

which was verified by a semi-quantitative theoretical study. Moreover

the stable binary systems of CNT/CNC and CB/CNC were chosen for co-assembly as membranes

and the uniaxial orientation could be optimized as the full-width of 9.8° at half-maximum deviation angle while the surface resistivity could also drop down to 3.42 × 10

Ω·cm·cm

−1

. The structural color character of such paper-homology and antistatic-integrated membranes contributes to optical information hiding-and-reading

and shows great potential as optical mark recognition materials for electrostatic discharge protective packaging and anti-counterfeiting applications.

关键词

Keywords

references

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