An Electrochemically Stable 2D Covalent Organic Framework for High-performance Organic Supercapacitors

Rashid Iqbal; Amir Badshah; Ying-Jie Ma; Lin-Jie Zhi

doi:10.1007/s10118-020-2412-z

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An Electrochemically Stable 2D Covalent Organic Framework for High-performance Organic Supercapacitors

ARTICLE | Updated：2020-03-25

- An Electrochemically Stable 2D Covalent Organic Framework for High-performance Organic Supercapacitors
- An Electrochemically Stable 2D Covalent Organic Framework for High-performance Organic Supercapacitors
- Chinese Journal of Polymer Science 2020年38卷第5期页码：558-564
- Affiliations：
  
  a.CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology, Beijing 100190, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
  c.Department of chemistry, Kohat University of Science and Technology, Khyber Pakhtunkhwa, Pakistan
- Author bio：
  
  mayj@nanoctr.cn (Y.J.M.)
  zhilj@nanoctr.cn (L.J.Z.)
- Funds：
  
  This work was financially supported by the Ministry of Science and Technology of China (No. 2012CB933403), Beijing Natural Science Foundation (No. 2182086), the National Natural Science Foundation of China (Nos. 51425302 and 51302045), CAS-TWAS President's PhD Fellowship program, the Beijing Municipal Science and Technology Commission (No. Z121100006812003), and the Chinese Academy of Sciences.
- DOI：10.1007/s10118-020-2412-z
  中图分类号：
- 收稿：2019-12-23，
  
  修回：2020-2-14，
  
  录用：2020-2-24，
  
  网络首发：2020-03-25，
  
  纸质出版：2020-05
- Accepted：
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Iqbal, R.; Badshah, A.; Ma, Y. J.; Zhi, L. J. An electrochemically stable 2D covalent organic framework for high-performance organic supercapacitors. Chinese J. Polym. Sci. 2020, 38, 558–564

Rashid Iqbal, Amir Badshah, Ying-Jie Ma, et al. An Electrochemically Stable 2D Covalent Organic Framework for High-performance Organic Supercapacitors[J]. Chinese Journal of Polymer Science, 2020, 38(5): 558-564.
Iqbal, R.; Badshah, A.; Ma, Y. J.; Zhi, L. J. An electrochemically stable 2D covalent organic framework for high-performance organic supercapacitors. Chinese J. Polym. Sci. 2020, 38, 558–564 DOI： 10.1007/s10118-020-2412-z.

Rashid Iqbal, Amir Badshah, Ying-Jie Ma, et al. An Electrochemically Stable 2D Covalent Organic Framework for High-performance Organic Supercapacitors[J]. Chinese Journal of Polymer Science, 2020, 38(5): 558-564. DOI： 10.1007/s10118-020-2412-z.

摘要

Abstract

An electrochemically stable two-dimensional covalent organic framework

PI-COF

has been synthesized by a scalable solvothermal method. PI-COF possesses a highly crystalline structure

well-defined pores

high specific surface area

and cluster macrostructure. Thanks to these features

PI-COF can work as electrode materials in organic supercapacitors

exhibiting a specific capacitance of 163 F/g at 0.5 A/g over a wide potential window of 0−2.5 V. Moreover

PI-COF shows excellent rate performance

which can deliver 96 F/g even at a high current density of 40 A/g. Because of the high capacitance and wide potential window

PI-COF has achieved a superior energy density of 35.7 W·h/kg at a power density of 250 W/kg. Most importantly

due to the remarkable electrochemical stability

the PI-COF based device shows outstanding cycling stability with 84.1% capacitance maintained (137 F/g) after 3.0 × 10

charged/discharged cycles at 1 A/g. This work should shed light on designing new COF-based electrode materials for supercapacitors and other electrochemical devices.

关键词

Keywords

references

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