Understanding Self-assembly, Colloidal Behavior and Rheological Properties of Graphene Derivatives for High-performance Supercapacitor Fabrication

Xia-Wei Yun; Bo Tang; Zhi-Yuan Xiong; Xiao-Gong Wang

doi:10.1007/s10118-020-2411-0

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Understanding Self-assembly, Colloidal Behavior and Rheological Properties of Graphene Derivatives for High-performance Supercapacitor Fabrication

FEATURE ARTICLE | Updated：2020-03-26

- Understanding Self-assembly, Colloidal Behavior and Rheological Properties of Graphene Derivatives for High-performance Supercapacitor Fabrication
- Understanding Self-assembly, Colloidal Behavior and Rheological Properties of Graphene Derivatives for High-performance Supercapacitor Fabrication
- Chinese Journal of Polymer Science 2020年38卷第5期页码：423-434
- Affiliations：
  
  a.Department of Chemical Engineering, Laboratory of Advanced Materials (Ministry of Education), Tsinghua University, Beijing 100084, China
  b.Department of Chemical and Bio-molecular Engineering, The University of Melbourne, Melbourne, Victoria 3010, Australia
- Author bio：
  
  zhiyuan.xiong@unimelb.edu.au (Z.Y.X.)
  wxg-dce@mail.tsinghua.edu.cn (X.G.W.)
- Funds：
  
  This work was financially supported by the National Basic Research Program of China (973 Program, No. 2012CB933402).
- DOI：10.1007/s10118-020-2411-0
  中图分类号：
- 收稿：2019-12-20，
  
  修回：2019-1-1，
  
  录用：2020-2-24，
  
  网络首发：2020-03-26，
  
  纸质出版：2020-05
- Accepted：
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Yun, X. W.; Tang, B.; Xiong, Z. Y.; Wang. X. G. Understanding self-assembly, colloidal behavior and rheological properties of graphene derivatives for high-performance supercapacitor fabrication. Chinese J. Polym. Sci. 2020, 38, 423–434

Xia-Wei Yun, Bo Tang, Zhi-Yuan Xiong, et al. Understanding Self-assembly, Colloidal Behavior and Rheological Properties of Graphene Derivatives for High-performance Supercapacitor Fabrication[J]. Chinese Journal of Polymer Science, 2020, 38(5): 423-434.
Yun, X. W.; Tang, B.; Xiong, Z. Y.; Wang. X. G. Understanding self-assembly, colloidal behavior and rheological properties of graphene derivatives for high-performance supercapacitor fabrication. Chinese J. Polym. Sci. 2020, 38, 423–434 DOI： 10.1007/s10118-020-2411-0.

Xia-Wei Yun, Bo Tang, Zhi-Yuan Xiong, et al. Understanding Self-assembly, Colloidal Behavior and Rheological Properties of Graphene Derivatives for High-performance Supercapacitor Fabrication[J]. Chinese Journal of Polymer Science, 2020, 38(5): 423-434. DOI： 10.1007/s10118-020-2411-0.

摘要

Abstract

Graphene derivatives

such as graphene oxide (GO) and reduced graphene oxide (RGO)

have been widely used as promising two-dimensional nanoscale building blocks due to their fascinating properties

cost-effective production

and good processability. Understanding the intrinsic self-assembling

colloidal

and rheological features of graphene derivatives is of critical importance to establish the formation-structure-property relationship of graphene-based materials. This article reviews recent progresses in our studies of these interesting properties of graphene derivatives for developing high performance supercapacitors. The content is organized to include characteristics of the dispersions of graphene derivatives

self-assembly of nanosheets from liquid medium

colloidal behavior

rheological properties of the dispersions

processing methods based on the properties

and performance of the fabricated supercapacitors. GO and RGO nanosheets are proved to form different types of assembled structures with unique morphologies

such as ultrathin layer-by-layer films

porous aggregates

and nanoscrolls. The unique rheological properties of GO dispersions and hydrogels

feasible for both the traditional wet-processing and newly-developed technology like three-dimensional printing

are highlighted for their potential in structural manipulation and scalable fabrication of graphene-based devices. The research devoted to up-grading the performance of supercapacitors is presented in some details

which could be applicable for fabricating other graphene-based energy storage devices. Some challenges and perspectives in our point of view are given in the last part of this feature article.

关键词

Keywords

references

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