Polyphosphoester-modified Cellulose Nanocrystals for Stabilizing Pickering Emulsion Polymerization of Styrene

Kun-Ming Che; Ming-Zu Zhang; Jin-Lin He; Pei-Hong Ni

doi:10.1007/s10118-020-2404-z

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Polyphosphoester-modified Cellulose Nanocrystals for Stabilizing Pickering Emulsion Polymerization of Styrene

ARTICLE | Updated：2020-04-20

- Polyphosphoester-modified Cellulose Nanocrystals for Stabilizing Pickering Emulsion Polymerization of Styrene
- Polyphosphoester-modified Cellulose Nanocrystals for Stabilizing Pickering Emulsion Polymerization of Styrene
- Chinese Journal of Polymer Science 2020年38卷第9期页码：921-931
- Affiliations：
  
  College of Chemistry, Chemical Engineering and Materials Science, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Soochow University, Suzhou 215123, China
- Author bio：
  
  phni@suda.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21975169 and 21374066), the Major Program of the Natural Science Project of Jiangsu Higher Education Institutions (No. 15KJA150007), the Natural Science Foundation of Jiangsu Province (No. BK20171212), a Project Funded by the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions, and Soochow-Waterloo University Joint Project for Nanotechnology from Suzhou Industrial Park.
- DOI：10.1007/s10118-020-2404-z
  中图分类号：
- 收稿：2019-12-28，
  
  修回：2020-2-12，
  
  录用：2020-2-17，
  
  网络首发：2020-04-20，
  
  纸质出版：2020-09
- Accepted：
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Che, K. M.; Zhang, M. Z.; He, J. L.; Ni, P. H. Polyphosphoester-modified cellulose nanocrystals for stabilizing pickering emulsion polymerization of styrene. Chinese J. Polym. Sci. 2020, 38, 921–931

Kun-Ming Che, Ming-Zu Zhang, Jin-Lin He, et al. Polyphosphoester-modified Cellulose Nanocrystals for Stabilizing Pickering Emulsion Polymerization of Styrene[J]. Chinese Journal of Polymer Science, 2020, 38(9): 921-931.
Che, K. M.; Zhang, M. Z.; He, J. L.; Ni, P. H. Polyphosphoester-modified cellulose nanocrystals for stabilizing pickering emulsion polymerization of styrene. Chinese J. Polym. Sci. 2020, 38, 921–931 DOI： 10.1007/s10118-020-2404-z.

Kun-Ming Che, Ming-Zu Zhang, Jin-Lin He, et al. Polyphosphoester-modified Cellulose Nanocrystals for Stabilizing Pickering Emulsion Polymerization of Styrene[J]. Chinese Journal of Polymer Science, 2020, 38(9): 921-931. DOI： 10.1007/s10118-020-2404-z.

摘要

Abstract

The structure and properties of functional nanoparticles are important for stabilizing Pickering emulsion polymerization. Recently

cellulose nanocrystals (CNCs) are increasingly favored as a bio-based stabilizer for Pickering emulsions. In this study

we reported a novel functionalized polyphosphoester-grafted CNCs for the stabilization of oil-in-water Pickering emulsions and the emulsion polymerization of styrene. First

polyphosphoester containing an amino group at one end of the chain

abbreviated as PBYP-NH

was prepared by ring-opening polymerization (ROP) and hydrolysis reaction

wherein PBYP represents poly[2-(but-3-yn-1-yloxy)-2-oxo-1

2-dioxaphospholane]. Subsequently

CNC-COOH was obtained

via

6-tetramethylpiperidine-1-oxyl (TEMPO) oxidation of CNCs. The functionalized nanocrystals CNC-PBYP-COOH with carboxyl groups and polyphosphoester on the surface were obtained by the amidation reaction of PBYP-NH

with CNC-COOH. Finally

we used CNC-PBYP-COOH as sole particle emulsifiers to stabilize styrene-in-water Pickering emulsions and studied its effects on the emulsions in details by using dynamic light scattering (DLS). The results indicated that the properties of these emulsions depended on the concentration of hydrophobically modified CNCs

volume ratios of oil to water

and pH values. The modified CNCs had higher ability to stabilize the styrene-in-water emulsions relative to the unmodified CNCs

and a stable oil-in-water (o/w) Pickering emulsion with diameter of hundreds of nanometers could be obtained. The resulting emulsions could be polymerized to yield nanosized latexes. The polyphosphoester-modified CNCs as green particle emulsifiers can efficiently stabilize nanoemulsions and latexes

which would promote the development of novel environmentally friendly materials.

关键词

Keywords

references

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