Thermally Conductive and Insulating Epoxy Composites by Synchronously Incorporating Si-sol Functionalized Glass Fibers and Boron Nitride Fillers

Rui-Han Zhang; Xue-Tao Shi; Lin Tang; Zheng Liu; Jun-Liang Zhang; Yong-Qiang Guo; Jun-Wei Gu

doi:10.1007/s10118-020-2391-0

Your Location：

Home >

Browse articles >

Thermally Conductive and Insulating Epoxy Composites by Synchronously Incorporating Si-sol Functionalized Glass Fibers and Boron Nitride Fillers

ARTICLE | Updated：2020-03-17

- Thermally Conductive and Insulating Epoxy Composites by Synchronously Incorporating Si-sol Functionalized Glass Fibers and Boron Nitride Fillers
- Thermally Conductive and Insulating Epoxy Composites by Synchronously Incorporating Si-sol Functionalized Glass Fibers and Boron Nitride Fillers
- Chinese Journal of Polymer Science 2020年38卷第7期页码：730-739
- Affiliations：
  
  Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi’an 710072, China
- Author bio：
  
  gjw@nwpu.edu.cn or nwpugjw@163.com
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51973173 and 51773169), Natural Science Basic Research Plan for Distinguished Young Scholars in Shaanxi Province of China (No. 2019JC-11), Fundamental Research Funds for the Central Universities (No. 310201911py010), and Fund Project of Basic and Applied Basic Research in Guangdong Province of China (No. 2019B1515120093).
- DOI：10.1007/s10118-020-2391-0
  中图分类号：
- 收稿：2019-12-14，
  
  修回：2020-1-9，
  
  录用：2020-1-15，
  
  网络首发：2020-03-17，
  
  纸质出版：2020-07
- Accepted：
Scan QR Code
Zhang, R. H.; Shi, X. T.; Tang, L.; Liu, Z.; Zhang, J. L.; Guo, Y. Q.; Gu, J. W. Thermally conductive and insulating epoxy composites by synchronously incorporating Si-sol functionalized glass fibers and boron nitride fillers. Chinese J. Polym. Sci. 2020, 38, 730–739

Rui-Han Zhang, Xue-Tao Shi, Lin Tang, et al. Thermally Conductive and Insulating Epoxy Composites by Synchronously Incorporating Si-sol Functionalized Glass Fibers and Boron Nitride Fillers[J]. Chinese Journal of Polymer Science, 2020, 38(7): 730-739.
Zhang, R. H.; Shi, X. T.; Tang, L.; Liu, Z.; Zhang, J. L.; Guo, Y. Q.; Gu, J. W. Thermally conductive and insulating epoxy composites by synchronously incorporating Si-sol functionalized glass fibers and boron nitride fillers. Chinese J. Polym. Sci. 2020, 38, 730–739 DOI： 10.1007/s10118-020-2391-0.

Rui-Han Zhang, Xue-Tao Shi, Lin Tang, et al. Thermally Conductive and Insulating Epoxy Composites by Synchronously Incorporating Si-sol Functionalized Glass Fibers and Boron Nitride Fillers[J]. Chinese Journal of Polymer Science, 2020, 38(7): 730-739. DOI： 10.1007/s10118-020-2391-0.

摘要

Abstract

Glass fibers (GFs)/epoxy laminated composites always present weak interlaminar shear strength (ILSS) and low cross-plane thermal conductivity coefficient (

┴

). In this work

silica-sol

synthesized from tetraethyl orthosilicate (TEOS) and KH-560

via

sol-gel method

was employed to functionalize the surface of GFs (Si-GFs). Together with a spherical boron nitride (BNN-30)

the thermally conductive BNN-30/Si-GFs/epoxy laminated composites were then fabricated. Results demonstrate that Si-sol is beneficial to the improvement of mechanical properties for epoxy laminated composites (especially for ILSS). The BNN-30/Si-GFs/epoxy laminated composites with 15 wt% BNN-30 fillers display the optimal comprehensive properties. In-plane

(

) and

┴

reach the maximum of 2.37 and 1.07 W·m

−1

·K

−1

146.9% and 132.6% higher than those of Si-GFs/epoxy laminated composites (

= 0.96 W·m

−1

·K

−1

and

┴

= 0.46 W·m

−1

·K

−1

)

respectively

and also about 10.8 and 4.9 times those of pure epoxy resin (

┴

0.22 W·m

−1

·K

−1

). And the heat-resistance index (

HRI

)

dielectric constant (

)

dielectric loss (tan

)

breakdown strength (

)

surface resistivity (

) as well as volume resistivity (

) are 197.3 °C

4.95

0.0046

22.3 kV·mm

−1

1.8 × 10

and 2.1 × 10

Ω·cm

respectively.

关键词

Keywords

references

Yang X. L.; Li, K.; Xu, M. Z.; Liu, X. B. . Designing a phthalonitrile/benzoxazine blend for the advanced GFRP composite material . Chinese J. Polym. Sci. , 2018 . 36 106 - 112 . DOI: 10.1007/s10118-018-2033-y http://doi.org/10.1007/s10118-018-2033-y .

Xu, X.; Zhang, Y.; Jiang, J.; Wang, H.; Zhao, X.; Li, Q.; Lu, W. . In - situ curing of glass fiber reinforced polymer composites via resistive heating of carbon nanotube films . Compos. Sci. Technol. , 2017 . 149 20 - 27 . DOI: 10.1016/j.compscitech.2017.06.001 http://doi.org/10.1016/j.compscitech.2017.06.001 .

Agrawal, S.; Singh, K. K.; Sarkar, P. K. . A comparative study of wear and friction characteristics of glass fibre reinforced epoxy resin, sliding under dry, oil-lubricated and inert gas environments . Tribol. Int. , 2016 . 96 217 - 224 . DOI: 10.1016/j.triboint.2015.12.033 http://doi.org/10.1016/j.triboint.2015.12.033 .

Park, D. W.; Oh, G. H.; Kim, H. S. . Predicting the stacking sequence of E-glass fiber reinforced polymer (GFRP) epoxy composite using terahertz time-domain spectroscopy (THz-TDS) system . Compos. Part B Eng. , 2017 . 177 107385 .

Shahkhosravi, N. A.; Yousefi, J.; Najafabadi, M. A.; Burvill, C.; Minak, G. . Fatigue life reduction of GFRP composites due to delamination associated with the introduction of functional discontinuities . Compos. Part B Eng. , 2019 . 163 536 - 547 . DOI: 10.1016/j.compositesb.2019.01.005 http://doi.org/10.1016/j.compositesb.2019.01.005 .

Rahmat, M.; Ashrafi, B.; Naftel, A.; Djokic, D.; Martinez-Rubi, Y.; Jakubinek, M. B.; Simard, B. . Enhanced shear performance of hybrid glass fiber-epoxy laminates modified with boron nitride nanotubes . ACS Appl. Nano Mater. , 2018 . 1 2709 - 2717 . DOI: 10.1021/acsanm.8b00413 http://doi.org/10.1021/acsanm.8b00413 .

Gu, S. L.; Liu, H. H.; Cao, H.; Mercier, C.; Li, Y. J. . Investigations on the interactions between Li-TFSI and glass fibers in the ternary PP/GF/Li-TFSI composites . Chinese J. Polym. Sci. , 2018 . 36 113 - 118 . DOI: 10.1007/s10118-018-2018-x http://doi.org/10.1007/s10118-018-2018-x .

Halder, S.; Ahemad, S.; Das, S.; Wang, J. . Epoxy/glass fiber laminated composites integrated with amino functionalized ZrO 2 for advanced structural applications . ACS Appl. Mater. Interfaces , 2016 . 8 1695 - 1706 . DOI: 10.1021/acsami.5b09149 http://doi.org/10.1021/acsami.5b09149 .

Slobodian, P.; Lloret, Pertegás S.; Riha, P.; Matyas, J.; Olejnik, R.; Schledjewski, R.; Kovar, M. . Glass fiber/epoxy composites with integrated layer of carbon nanotubes for deformation detection . Compos. Sci. Technol. , 2018 . 156 61 - 69 . DOI: 10.1016/j.compscitech.2017.12.012 http://doi.org/10.1016/j.compscitech.2017.12.012 .

Tang, Y.; Gu, J.; Yu, Y.; Kong, J. . Preparation of POSS/quartz fibers/cyanate ester resins laminated composites . Polym. Compos. , 2015 . 36 2017 - 2021 . DOI: 10.1002/pc.23111 http://doi.org/10.1002/pc.23111 .

Zhang, L. X.; Chang, Q.; Sun, Z.; Zhang, J. J.; Qi, J. L.; Feng, J. C. . Wetting of AgCuTi alloys on quartz fiber reinforced composite modified by vertically aligned carbon nanotubes . Carbon , 2019 . 154 375 - 383 . DOI: 10.1016/j.carbon.2019.08.043 http://doi.org/10.1016/j.carbon.2019.08.043 .

Alsaadi, M.; Bulut, M.; Erkliğ, A.; Jabbar, A. . Nano-silica inclusion effects on mechanical and dynamic behavior of fiber reinforced carbon/Kevlar with epoxy resin hybrid composites . Compos. Part B Eng. , 2018 . 152 169 - 179 . DOI: 10.1016/j.compositesb.2018.07.015 http://doi.org/10.1016/j.compositesb.2018.07.015 .

Tang, L.; Dang, J.; He, M.; Li, J.; Kong, J.; Tang, Y.; Gu, J. . Preparation and properties of cyanate-based wave-transparent laminated composites reinforced by dopamine/POSS functionalized Kevlar cloth . Compos. Sci. Technol. , 2019 . 169 120 - 126 . DOI: 10.1016/j.compscitech.2018.11.018 http://doi.org/10.1016/j.compscitech.2018.11.018 .

Yu, L.; Lu, F.; Huang, X.; Liu, Y.; Li, M.; Pan, H.; Wu, L.; Huang, Y.; Hu, Z. . Facile interface design strategy for improving the uvioresistant and self-healing properties of poly( p -phenylene benzobisoxazole) fibers . ACS Appl. Mater. Interfaces , 2019 . 11 39292 - 39303 . DOI: 10.1021/acsami.9b11595 http://doi.org/10.1021/acsami.9b11595 .

Liu, Z.; Zhang, J.; Tang, L.; Zhou, Y.; Lin, Y.; Wang, R.; Kong, J.; Tang, Y.; Gu, J. . Improved wave-transparent performances and enhanced mechanical properties for fluoride-containing PBO precursor modified cyanate ester resins and their PBO fibers/cyanate ester composites . Compos. Part B Eng. , 2019 . 178 107466 DOI: 10.1016/j.compositesb.2019.107466 http://doi.org/10.1016/j.compositesb.2019.107466 .

Bhanuprakash, L.; Ali, A.; Mokkoth, R.; Varghese, S. . Mode I and Mode II interlaminar fracture behavior of E-glass fiber reinforced epoxy composites modified with reduced exfoliated graphite oxide . Polym. Compos. , 2018 . 39 E2506 - E2518 . DOI: 10.1002/pc.24809 http://doi.org/10.1002/pc.24809 .

Mahmood, H.; Vanzetti, L.; Bersani, M.; Pegoretti, A. . Mechanical properties and strain monitoring of glass-epoxy composites with graphene-coated fibers . Compos. Part A-Appl. S. , 2018 . 107 112 - 123 . DOI: 10.1016/j.compositesa.2017.12.023 http://doi.org/10.1016/j.compositesa.2017.12.023 .

Balkova, R.; Jancar, J.; Cech, V. . Effect of RF-plasma deposition parameters on the composition and properties of organic layers deposited on glass fibers . Compos. Sci. Technol. , 2009 . 69 2485 - 2490 . DOI: 10.1016/j.compscitech.2009.06.024 http://doi.org/10.1016/j.compscitech.2009.06.024 .

Cech, V.; Knob, A.; Hosein, H. A.; Babik, A.; Lepcio, P.; Ondreas, F.; Drzal, L. T. . Enhanced interfacial adhesion of glass fibers by tetravinylsilane plasma modification . Compos. Part A-Appl. S. , 2014 . 58 84 - 89 . DOI: 10.1016/j.compositesa.2013.12.003 http://doi.org/10.1016/j.compositesa.2013.12.003 .

Yang, W.; Zhang, Y. R.; Yuen, A. C. Y.; Chen, T. B. Y.; Chan, M. C.; Peng, L. Z.; Yang, W. J.; Zhu, S. E.; Yang, B. H.; Hu, K. H.; Yeoh, G. H.; Lu, H. D. . Synthesis of phosphorus-containing silane coupling agent for surface modification of glass fibers: effective reinforcement and flame retardancy in poly(1,4-butylene terephthalate) . Chem. Eng. J. , 2017 . 321 257 - 267 . DOI: 10.1016/j.cej.2017.03.123 http://doi.org/10.1016/j.cej.2017.03.123 .

Safi, S.; Zadhoush, A.; Masoomi, M. . Effects of chemical surface pretreatment on tensile properties of a single glass fiber and the glass fiber reinforced epoxy composite . Polym. Compos. , 2016 . 37 91 - 100 . DOI: 10.1002/pc.23158 http://doi.org/10.1002/pc.23158 .

Li, S.; Lin, Q.; Zhu, H.; Hou, H.; Li, Y.; Wu, Q.; Cui, C. . Improved mechanical properties of epoxy-based composites with hyperbranched polymer grafting glass-fiber . Polym. Adv. Technol. , 2016 . 27 898 - 904 . DOI: 10.1002/pat.3746 http://doi.org/10.1002/pat.3746 .

Luo, N.; Zhong, H.; Yang, M.; Yuan, X.; Fan, Y. . Modifying glass fiber surface with grafting acrylamide by UV-grafting copolymerization for preparation of glass fiber reinforced PVDF composite membrane . J. Environ. Sci. , 2016 . 39 208 - 217 . DOI: 10.1016/j.jes.2015.11.010 http://doi.org/10.1016/j.jes.2015.11.010 .

Asadi, A.; Miller, M.; Moon, R. J.; Kalaitzidou, K. . Improving the interfacial and mechanical properties of short glass fiber/epoxy composites by coating the glass fibers with cellulose nanocrystals . Express. Polym. Lett. , 2016 . 10 587 - 597 . DOI: 10.3144/expresspolymlett.2016.54 http://doi.org/10.3144/expresspolymlett.2016.54 .

Tang, L.; He, M.; Na, X.; Guan, X.; Zhang, R.; Zhang, J.; Gu, J. . Functionalized glass fibers cloth/spherical BN fillers/epoxy laminated composites with excellent thermal conductivities and electrical insulation properties . Compos. Commun. , 2019 . 16 5 - 10 . DOI: 10.1016/j.coco.2019.08.007 http://doi.org/10.1016/j.coco.2019.08.007 .

Yang, X.; Guo, Y.; Han, Y.; Li, Y.; Ma, T.; Chen, M.; Kong, J.; Gu, J. . Significant improvement of thermal conductivities for BNNS/PVA composite films via electrospinning followed by hot-pressing technology . Compos. Part B Eng. , 2019 . 175 107070 DOI: 10.1016/j.compositesb.2019.107070 http://doi.org/10.1016/j.compositesb.2019.107070 .

Yeo, H.; Islam, A. M., You, N. H.; Ahn, S.; Goh, M.; Hahn, J. R.; Jang, S. G. . Characteristic correlation between liquid crystalline epoxy and alumina filler on thermal conducting properties . Compos. Sci. Technol. , 2017 . 141 99 - 105 . DOI: 10.1016/j.compscitech.2017.01.016 http://doi.org/10.1016/j.compscitech.2017.01.016 .

Zhang, G. D.; Fan, L.; Bai, L.; He, M. H.; Zhai, L.; Mo, S. . Mesoscopic simulation assistant design of immiscible polyimide/BN blend films with enhanced thermal conductivity . Chinese J. Polym. Sci. , 2018 . 36 1394 - 1402 . DOI: 10.1007/s10118-018-2155-2 http://doi.org/10.1007/s10118-018-2155-2 .

Yang, X.; Liang, C.; Ma, T.; Guo, Y.; Kong, J.; Gu, J.; Zhu, J. . A review on thermally conductive polymeric composites: classification, measurement, model and equations, mechanism and fabrication methods . Adv. Compos. Hybrid. Mater. , 2018 . 1 207 - 230 . DOI: 10.1007/s42114-018-0031-8 http://doi.org/10.1007/s42114-018-0031-8 .

Ji, C.; Yan, C.; Wang, Y.; Xiong, S.; Zhou, F.; Li, Y.; Sun, R.; Wong, C. P. . Thermal conductivity enhancement of CNT/MoS 2 /graphene-epoxy nanocomposites based on structural synergistic effects and interpenetrating network . Compos. Part B Eng. , 2019 . 163 363 - 370 . DOI: 10.1016/j.compositesb.2018.11.005 http://doi.org/10.1016/j.compositesb.2018.11.005 .

Owais, M.; Zhao, J.; Imani, A.; Wang, G.; Zhang, H.; Zhang, Z. . Synergetic effect of hybrid fillers of boron nitride, graphene nanoplatelets, and short carbon fibers for enhanced thermal conductivity and electrical resistivity of epoxy nanocomposites . Compos. Part A-Appl. S. , 2019 . 117 11 - 22 . DOI: 10.1016/j.compositesa.2018.11.006 http://doi.org/10.1016/j.compositesa.2018.11.006 .

Ruan, K.; Guo, Y.; Tang, Y.; Zhang, Y.; Zhang, J.; He, M.; Kong, J.; Gu, J. . Improved thermal conductivities in polystyrene nanocomposites by incorporating thermal reduced graphene oxide via electrospinning-hot press technique . Compos. Commun. , 2018 . 10 68 - 72 . DOI: 10.1016/j.coco.2018.07.003 http://doi.org/10.1016/j.coco.2018.07.003 .

Huang, T.; Zhang, G.; Gao, Y. . A novel silver nanoparticle-deposited aluminum oxide hybrids for epoxy composites with enhanced thermal conductivity and energy density . Compos. Interfaces , 2019 . 26 1001 - 1011 . DOI: 10.1080/09276440.2019.1578569 http://doi.org/10.1080/09276440.2019.1578569 .

Feng, Y.; He, C.; Wen, Y.; Zhou, X.; Xie, X.; Ye, Y.; Mai, Y. W. . Multi-functional interface tailoring for enhancing thermal conductivity, flame retardancy and dynamic mechanical property of epoxy/Al 2 O 3 composites . Compos. Sci. Technol. , 2018 . 160 42 - 49 . DOI: 10.1016/j.compscitech.2018.03.009 http://doi.org/10.1016/j.compscitech.2018.03.009 .

Yu, C.; Zhang, J.; Li, Z.; Tian, W.; Wang, L.; Luo, J.; Li, Q.; Fan, X.; Yao, Y. . Enhanced through-plane thermal conductivity of boron nitride/epoxy composite . Compos. Part A-Appl. S. , 2017 . 98 25 - 31 . DOI: 10.1016/j.compositesa.2017.03.012 http://doi.org/10.1016/j.compositesa.2017.03.012 .

Han, J.; Du, G.; Gao, W.; Bai, H. . An anisotropically high thermal conductive boron nitride/epoxy composite based on nacre-mimetic 3D network . Adv. Funct. Mater. , 2019 . 29 1900412 DOI: 10.1002/adfm.201900412 http://doi.org/10.1002/adfm.201900412 .

Huang, X.; Iizuka, T.; Jiang, P.; Ohki, Y.; Tanaka, T. . Role of interface on the thermal conductivity of highly filled dielectric epoxy/AlN composites . J. Phys. Chem. C , 2012 . 116 13629 - 13639 . DOI: 10.1021/jp3026545 http://doi.org/10.1021/jp3026545 .

Chung, S. L.; Lin, J. S. . Thermal conductivity of epoxy resin composites filled with combustion-synthesized AlN powder . Polym. Compos. , 2018 . 39 E2125 - E2133 . DOI: 10.1002/pc.24481 http://doi.org/10.1002/pc.24481 .

Xiao, C.; Chen, L.; Tang, Y.; Zhang, X.; Zheng, K.; Tian, X. . Enhanced thermal conductivity of silicon carbide nanowires (SiC w )/epoxy resin composite with segregated structure . Compos. Part A-Appl. S. , 2019 . 116 98 - 105 . DOI: 10.1016/j.compositesa.2018.10.023 http://doi.org/10.1016/j.compositesa.2018.10.023 .

Ma, T.; Zhao, Y.; Ruan, K.; Liu, X.; Zhang, J.; Guo, Y.; Yang, X.; Kong, J.; Gu, J. . Highly thermal conductivities, excellent mechanical robustness and flexibility, and outstanding thermal stabilities of aramid nanofiber composite papers with nacre-mimetic layered structures . ACS Appl. Mater. Interfaces , 2020 . 12 1677 - 1686 . DOI: 10.1021/acsami.9b19844 http://doi.org/10.1021/acsami.9b19844 .

Han, Y.; Shi, X.; Yang, X.; Guo, Y.; Zhang, J.; Kong, J.; Gu, J. . Enhanced thermal conductivities of epoxy nanocomposites via incorporating in - situ fabricated hetero-structured SiC-BNNS fillers . Compos. Sci. Technol. , 2020 . 187 107944 DOI: 10.1016/j.compscitech.2019.107944 http://doi.org/10.1016/j.compscitech.2019.107944 .

Hu, J.; Huang, Y.; Yao, Y.; Pan, G.; Sun, J.; Zeng, X.; Sun, R.; Xu, J. B.; Song, B.; Wong, C. P. . Polymer composite with improved thermal conductivity by constructing a hierarchically ordered three-dimensional interconnected network of BN . ACS Appl. Mater. Interfaces , 2017 . 9 13544 - 13553 . DOI: 10.1021/acsami.7b02410 http://doi.org/10.1021/acsami.7b02410 .

Jiang, Y.; Shi, X.; Feng, Y.; Li, S.; Zhou, X.; Xie, X. . Enhanced thermal conductivity and ideal dielectric properties of epoxy composites containing polymer modified hexagonal boron nitride . Compos. Part A-Appl. S. , 2018 . 107 657 - 664 . DOI: 10.1016/j.compositesa.2018.02.016 http://doi.org/10.1016/j.compositesa.2018.02.016 .

Yang, X.; Guo, Y.; Luo, X.; Zheng, N.; Ma, T.; Tan, J.; Li, C.; Zhang, Q.; Gu, J. . Self-healing, recoverable epoxy elastomers and their composites with desirable thermal conductivities by incorporating BN fillers via in - situ polymerization . Compos. Sci. Technol. , 2018 . 164 59 - 64 . DOI: 10.1016/j.compscitech.2018.05.038 http://doi.org/10.1016/j.compscitech.2018.05.038 .

Choi, S.; Yang, J.; Kim, Y.; Nam, J.; Kim, K.; Shim, S. E. . Microwave-accelerated synthesis of silica nanoparticle-coated graphite nanoplatelets and properties of their epoxy composites . Compos. Sci. Technol. , 2014 . 103 8 - 15 . DOI: 10.1016/j.compscitech.2014.08.003 http://doi.org/10.1016/j.compscitech.2014.08.003 .

Burger, N.; Laachachi, A.; Mortazavi, B.; Ferriol, M.; Lutz, M.; Toniazzo, V.; Ruch, D. . Alignments and network of graphite fillers to improve thermal conductivity of epoxy-based composites . Int. J. Heat Mass Tran. , 2015 . 89 505 - 513 . DOI: 10.1016/j.ijheatmasstransfer.2015.05.065 http://doi.org/10.1016/j.ijheatmasstransfer.2015.05.065 .

Luo, B.; Wang, X.; Wang, Y.; Li, L. . Fabrication, characterization, properties and theoretical analysis of ceramic/PVDF composite flexible films with high dielectric constant and low dielectric loss . J. Mater. Chem. A , 2014 . 2 510 - 519 . DOI: 10.1039/C3TA14107A http://doi.org/10.1039/C3TA14107A .

Xu, N.; Hu, L.; Zhang, Q.; Xiao, X.; Yang, H.; Yu, E. . Significantly enhanced dielectric performance of poly(vinylidene fluoride- co -hexafluoropylene)-based composites filled with hierarchical flower-like TiO 2 particles . ACS Appl. Mater. Interfaces , 2015 . 7 27373 - 27381 . DOI: 10.1021/acsami.5b08987 http://doi.org/10.1021/acsami.5b08987 .

Wang, Z.; Liu, J.; Cheng, Y.; Chen, S.; Yang, M.; Huang, J.; Wang, H.; Wu, G.; Wu, H. . Alignment of boron nitride nanofibers in epoxy composite films for thermal conductivity and dielectric breakdown strength improvement . Nanomaterials , 2018 . 8 242 DOI: 10.3390/nano8040242 http://doi.org/10.3390/nano8040242 .

Chen, S.; Cheng, Y.; Xie, Q.; Xiao, B.; Wang, Z.; Liu, J.; Wu, G. . Enhanced breakdown strength of aligned-sodium-titanate-nanowire/epoxy nanocomposites and their anisotropic dielectric properties . Compos. Part A-Appl. S. , 2019 . 120 84 - 94 . DOI: 10.1016/j.compositesa.2019.02.024 http://doi.org/10.1016/j.compositesa.2019.02.024 .

Feng, C. P.; Wan, S. S.; Wu, W. C.; Bai, L.; Bao, R. Y.; Liu, Z. Y.; Yang, M. B.; Chen, J.; Yang, W. . Electrically insulating, layer structured SiR/GNPs/BN thermal management materials with enhanced thermal conductivity and breakdown voltage . Compos. Sci. Technol. , 2018 . 167 456 - 462 . DOI: 10.1016/j.compscitech.2018.08.039 http://doi.org/10.1016/j.compscitech.2018.08.039 .

Yang, X.; Fan, S; Li, Y.; Guo, Y; Li, Y.; Ruan, K.; Zhang, S.; Zhang, J.; Kong, J.; Gu, J. . Synchronously improved electromagnetic interference shielding and thermal conductivity for epoxy nanocomposites by constructing 3D copper nanowires/thermally annealed graphene aerogel framework . Compos. Part A-Appl. S. , 2020 . 128 105670 DOI: 10.1016/j.compositesa.2019.105670 http://doi.org/10.1016/j.compositesa.2019.105670 .

浏览量

134

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

In situ Loaded Nanoscale Red Phosphorus on Mesoporous Silica for Simultaneously Improved Flame Retardancy and Toughness of Epoxy Composites

Application of Polysulfone Cardo Copolymer in Epoxy Resin Binders for the Production of Carbon Fiber Reinforced Plastics

Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid