Three-dimensional Covalent Organic Frameworks as Host Materials for Lithium-Sulfur Batteries

Zhen Li; Hang-Yu Zhou; Fu-Lai Zhao; Tian-Xiong Wang; Xuesong Ding; Bao-Hang Han; Wei Feng

doi:10.1007/s10118-020-2384-z

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Three-dimensional Covalent Organic Frameworks as Host Materials for Lithium-Sulfur Batteries

ARTICLE | Updated：2020-02-27

- Three-dimensional Covalent Organic Frameworks as Host Materials for Lithium-Sulfur Batteries
- Three-dimensional Covalent Organic Frameworks as Host Materials for Lithium-Sulfur Batteries
- Chinese Journal of Polymer Science 2020年38卷第5期页码：550-557
- Affiliations：
  
  a.Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
  b.School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
  c.University of Chinese Academy of Science, Beijing 100049, China
  d.Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China
- Author bio：
  
  dingxs@nanoctr.cn (X.D.)
  hanbh@nanoctr.cn (B.H.H.)
  weifeng@tju.edu.cn (W.F.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21674026, 21574032, 51573125, 51573147, 51803149, 51973155, and 51633007 (the State Key Program)), the Sino-German Center for Research Promotion (No. GZ1286), and the Chinese Academy of Sciences (No. 121D11KYSB20170031).
- DOI：10.1007/s10118-020-2384-z
  中图分类号：
- 收稿：2019-09-30，
  
  修回：2019-12-31，
  
  录用：2020-1-2，
  
  网络首发：2020-02-27，
  
  纸质出版：2020-05
- Accepted：
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Li. Z.; Zhou, H. Y.; Zhao, F. L.; Wang, T. X.; Ding, X.; Han, B. H.; Feng, W. Three-dimensional covalent organic frameworks as host materials for lithium-sulfur batteries. Chinese J. Polym. Sci. 2020, 38, 550–557

Zhen Li, Hang-Yu Zhou, Fu-Lai Zhao, et al. Three-dimensional Covalent Organic Frameworks as Host Materials for Lithium-Sulfur Batteries[J]. Chinese Journal of Polymer Science, 2020, 38(5): 550-557.
Li. Z.; Zhou, H. Y.; Zhao, F. L.; Wang, T. X.; Ding, X.; Han, B. H.; Feng, W. Three-dimensional covalent organic frameworks as host materials for lithium-sulfur batteries. Chinese J. Polym. Sci. 2020, 38, 550–557 DOI： 10.1007/s10118-020-2384-z.

Zhen Li, Hang-Yu Zhou, Fu-Lai Zhao, et al. Three-dimensional Covalent Organic Frameworks as Host Materials for Lithium-Sulfur Batteries[J]. Chinese Journal of Polymer Science, 2020, 38(5): 550-557. DOI： 10.1007/s10118-020-2384-z.

摘要

Abstract

Two reported three-dimensional covalent organic frameworks (3D-COFs)

COF-300 and COF-301

which have hierarchical porous structures and large pore volumes

were synthesized and employed as host materials for lithium-sulfur batteries. Owing to possessing excellent porosities as well as abundant hydroxyl groups in the pore walls

COF-301 can not only trap lithium polysulfides (PSs)

via

physical adsorption inside the pores

but also capture PSs by chemical interactions to relieve the shuttle effect. Interestingly

it is the first time that 3D-COFs were utilized as host materials for lithium-sulfur batteries as well as hydroxyl groups were introduced into COFs for improving the battery performance. As a result

COF-301@S as cathode material could reserve the capacity of 411.6 mA·h·g

–1

after 500 cycles with only 0.081% fading per cycle at 0.5 C

exhibiting better battery performance compared with COF-300@S. This study not only expands the applications of 3D-COFs but also provides a new route for designing lithium-sulfur batteries.

关键词

Keywords

references

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