Molecular Weight Dependence of Associative Behavior in Polyimide/DMF Solutions

Hong-Xiang Chen; En-Song Zhang; Mei Hong; Wei Liu; Xue-Min Dai; Quan Chen; Xue-Peng Qiu; Xiang-Ling Ji

doi:10.1007/s10118-020-2358-1

Your Location：

Home >

Browse articles >

Molecular Weight Dependence of Associative Behavior in Polyimide/DMF Solutions

ARTICLE | Updated：2019-11-18

- Molecular Weight Dependence of Associative Behavior in Polyimide/DMF Solutions
- Molecular Weight Dependence of Associative Behavior in Polyimide/DMF Solutions
- Chinese Journal of Polymer Science 2020年38卷第6期页码：629-637
- Affiliations：
  
  a.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China
  c.Laboratory of Polymer Composites and Engineering, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  zhangensong@fudan.edu.cn (E.S.Z.)
  xlji@ciac.ac.cn (X.L.J.)
- Funds：
  
  This work was financially supported by the National Basic Research Program of China (No. 2014CB643604) and the National Natural Science Foundation of China (No. 51173178).
- DOI：10.1007/s10118-020-2358-1
  中图分类号： M
- 收稿：2019-08-23，
  
  修回：2019-9-12，
  
  录用：2019-9-16，
  
  网络首发：2019-11-18，
  
  纸质出版：2020-06
- Accepted：
Scan QR Code
Chen, H. X.; Zhang, E. S.; Hong, M.; Liu, W.; Dai, X. M.; Chen, Q.; Qiu, X. P.; Ji, X. L. Molecular weight dependence of associative behavior in polyimide/DMF solutions. Chinese J. Polym. Sci. 2020, 38, 629–637

Hong-Xiang Chen, En-Song Zhang, Mei Hong, et al. Molecular Weight Dependence of Associative Behavior in Polyimide/DMF Solutions[J]. Chinese Journal of Polymer Science, 2020, 38(6): 629-637.
Chen, H. X.; Zhang, E. S.; Hong, M.; Liu, W.; Dai, X. M.; Chen, Q.; Qiu, X. P.; Ji, X. L. Molecular weight dependence of associative behavior in polyimide/DMF solutions. Chinese J. Polym. Sci. 2020, 38, 629–637 DOI： 10.1007/s10118-020-2358-1.

Hong-Xiang Chen, En-Song Zhang, Mei Hong, et al. Molecular Weight Dependence of Associative Behavior in Polyimide/DMF Solutions[J]. Chinese Journal of Polymer Science, 2020, 38(6): 629-637. DOI： 10.1007/s10118-020-2358-1.

摘要

Abstract

Eight 6FDA-TFDB polyimide (PI) samples with absolute molecular weights ranging from 1.25 × 10

g·mol

–1

to 3.11 × 10

g·mol

–1

are obtained by precipitation fractionation. Rheological experiments are conducted to determine the influence of molecular weight on the associating behavior of PI in

′-dimethylformamide (DMF) solutions in a broad volume fraction

including abnormal steady shear flow

solution heterogeneity

and scaling behavior. Abnormal flow behaviors

i.e.

multi-region shear thinning and weak shear thickening

are studied

and these behaviors have not been reported in literature. The heterogeneity of PI/DMF solutions is examined by dynamic rheological test. By plotting

versus

four concentration regions of I–IV can be distinguished for all PI samples with various molecular weights. The scaling results in different concentration regions are in good agreement with the associative polymer theory proposed by Rubinstein and Semenov. The scaling exponents do not show molecular weight dependence in concentration regions I and II. In concentration regions III and IV

the scaling exponents change little when the molecular weight is below 242 k but increase when the molecular weight increases from 242 k to 311 k. This work can help us to understand polyimide solution properties from dilute to semidilute entangled solutions

and will guide the polyimide solution preparation for different processing.

关键词

Keywords

references

Ogura, M.; Tokuda, H.; Imabayashi, S.; Watanabe, M . Preparation and solution behavior of a thermoresponsive diblock copolymer of poly(ethyl glycidyl ether) and poly(ethylene oxide) . Langmuir , 2007 . 23 9429 - 34 . DOI: 10.1021/la701384q http://doi.org/10.1021/la701384q .

Renou, F.; Benyahia, L.; Nicolai, T . Influence of adding unfunctionalized PEO on the viscoelasticity and the structure of dense polymeric micelle solutions formed by hydrophobically end-capped PEO . Macromolecules , 2007 . 40 4626 - 4634 . DOI: 10.1021/ma070263e http://doi.org/10.1021/ma070263e .

Castelletto, V.; Hamley, I. W.; Yuan, X. F.; Kelarakis, A.; Booth, C . Structure and rheology of aqueous micellar solutions and gels formed from an associative poly(oxybutylene)-poly(oxyethylene)-poly(oxybutylene) triblock copolymer . Soft Matter , 2005 . 1 138 - 145 . DOI: 10.1039/b419103j http://doi.org/10.1039/b419103j .

Suzuki, S.; Uneyama, T.; Watanabe, H . Concentration dependence of nonlinear rheological properties of hydrophobically modified ethoxylated urethane aqueous solutions . Macromolecules , 2013 . 46 3497 - 3504 . DOI: 10.1021/ma400429y http://doi.org/10.1021/ma400429y .

Ding, K.; Wang, F.; Wu, F . Association behavior of porphyrin pendants in pH-sensitive water-soluble polymer . Chinese J. Polym. Sci. , 2012 . 30 63 - 71 . DOI: 10.1007/s10118-012-1104-8 http://doi.org/10.1007/s10118-012-1104-8 .

Golkaram, M.; Fodor, C.; Ruymbeke, E.; Loos, K . Linear viscoelasticity of weakly hydrogen-bonded polymers near and below the sol-gel transition . Macromolecules , 2018 . 51 4910 - 4916 . DOI: 10.1021/acs.macromol.8b00772 http://doi.org/10.1021/acs.macromol.8b00772 .

Candau, F.; Regalado, E. J.; Selb, J . Scaling behavior of the zero shear viscosity of hydrophobically modified poly(acrylamide)s . Macromolecules , 1998 . 31 5550 - 5552 . DOI: 10.1021/ma9802982 http://doi.org/10.1021/ma9802982 .

Yang, X.; Liu, J.; Li, P.; Liu, C . Self-assembly properties of hydrophobically associative perfluorinated polyacrylamide in dilute and semi-dilute solutions . J. Polym. Res. , 2015 . 22 103 DOI: 10.1007/s10965-015-0750-2 http://doi.org/10.1007/s10965-015-0750-2 .

Xu, D.; Craig, S. L . Scaling laws in supramolecular polymer networks . Macromolecules , 2011 . 44 5465 - 5472 . DOI: 10.1021/ma200096s http://doi.org/10.1021/ma200096s .

Li, J.; Wu, F.; Wang, E . Hydrophobically associating polyacrylamides modified by a novel self-associative cationic monomer . Chinese J. Polym. Sci. , 2010 . 28 137 - 145 . DOI: 10.1007/s10118-010-8223-x http://doi.org/10.1007/s10118-010-8223-x .

Witten, T. A . Associative polymers and shear thickening . Journal de Physique , 1988 . 49 1055 - 1063 . DOI: 10.1051/jphys:019880049060105500 http://doi.org/10.1051/jphys:019880049060105500 .

Kujawa, P.; Audibert-Hayet, A.; Selb, J.; Candau, F . Rheological properties of multisticker associative polyelectrolytes in semidilute aqueous solutions . J. Polym. Sci., Part B: Polym. Phys. , 2010 . 42 1640 - 1655 . .

Chassenieux, C.; Nicolai, T.; Benyahia, L . Rheology of associative polymer solutions . Curr. Opin. Colloid Interface Sci. , 2011 . 16 18 - 26 . DOI: 10.1016/j.cocis.2010.07.007 http://doi.org/10.1016/j.cocis.2010.07.007 .

Rubinstein, M.; Semenov, A. N . Dynamics of entangled solutions of associative polymers . Macromolecules , 2001 . 34 1058 - 1068 . DOI: 10.1021/ma0013049 http://doi.org/10.1021/ma0013049 .

Feldman, K. E.; Kade, M. J.; Meijer, E. W.; Hawker, C. J.; Kramer, E. J . Model transient networks from strongly hydrogen-bonded polymers . Macromolecules , 2009 . 42 9072 - 9081 . DOI: 10.1021/ma901668w http://doi.org/10.1021/ma901668w .

Regalado, E. J.; Selb, J.; Candau, F . Viscoelastic behavior of semidilute solutions of multisticker polymer chains . Macromolecules , 1999 . 32 8580 - 8588 . DOI: 10.1021/ma990999e http://doi.org/10.1021/ma990999e .

Cram, S. L.; Brown, H. R.; Spinks, G. M.; Hourdet, D.; Creton, C . Hydrophobically modified dimethylacrylamide synthesis and rheological behavior . Macromolecules , 2005 . 38 2981 - 2989 . DOI: 10.1021/ma048504v http://doi.org/10.1021/ma048504v .

Kujawa, P.; Audibert-Hayet, A.; Selb, J.; Candau, F . Effect of ionic strength on the rheological properties of multisticker associative polyelectrolytes . Macromolecules , 2006 . 39 384 - 392 . DOI: 10.1021/ma051312v http://doi.org/10.1021/ma051312v .

Ding, M . Isomeric polyimides . Prog. Polym. Sci. , 2007 . 32 623 - 668 . DOI: 10.1016/j.progpolymsci.2007.01.007 http://doi.org/10.1016/j.progpolymsci.2007.01.007 .

Chisca, S.; Musteata, V. E.; Sava, I.; Bruma, M . Dielectric behavior of some aromatic polyimide films . Eur. Polym. J. , 2011 . 47 1186 - 1197 . DOI: 10.1016/j.eurpolymj.2011.01.008 http://doi.org/10.1016/j.eurpolymj.2011.01.008 .

Liaw, D.; Wang, K.; Huang, Y.; Lee, K.; Lai, J.; Ha, C . Advanced polyimide materials: syntheses, physical properties and applications . Prog. Polym. Sci. , 2012 . 37 907 - 974 . DOI: 10.1016/j.progpolymsci.2012.02.005 http://doi.org/10.1016/j.progpolymsci.2012.02.005 .

Dong, Z.; Feng, T.; Zheng, C.; Li, G.; Liu, F.; Qiu, X . Mechanical properties of polyimide/multi-walled carbon nanotube composite fibers . Chinese J. Polym. Sci. , 2016 . 34 1386 - 1395 . DOI: 10.1007/s10118-016-1841-1 http://doi.org/10.1007/s10118-016-1841-1 .

Dhara, M. G.; Banerjee, S . Fluorinated high-performance polymers: Poly(arylene ether)s and aromatic polyimides containing trifluoromethyl groups . Prog. Polym. Sci. , 2010 . 35 1022 - 1077 . DOI: 10.1016/j.progpolymsci.2010.04.003 http://doi.org/10.1016/j.progpolymsci.2010.04.003 .

Yang, C.; Su, Y.; Wen, S.; Hsiao, S . Highly optically transparent/low color polyimide films prepared from hydroquinone- or resorcinol-based bis(ether anhydride) and trifluoromethyl-containing bis(ether amine)s . Polymer , 2006 . 47 7021 - 7033 . DOI: 10.1016/j.polymer.2006.07.066 http://doi.org/10.1016/j.polymer.2006.07.066 .

Liu, G.; Qiu, X.; Bo, S.; Ji, X . Chain conformation and local rigidity of soluble polyimide (II): isomerized polyimides in THF . Chem. Res. Chin. Univ. , 2012 . 28 329 - 333 . .

Liu, G.; Qiu, X.; Siddiq, M.; Bo, S.; Ji, X . Temperature dependence of chain conformation and local rigidity of isomerized polyimides in dimethyl formamide . Chem. Res. Chin. Univ. , 2013 . 29 1022 - 1028 . DOI: 10.1007/s40242-013-2323-4 http://doi.org/10.1007/s40242-013-2323-4 .

Savitski, E. P.; Li, F.; Lin, S. H.; Mccreight, K. W.; Wu, W.; Hsieh, E.; Rapold, R. F.; Leland, M. E.; Mclntyre, D. M.; Harris, F. W.; Cheng, S. Z. D.; Wu, C . Investigation of the solution behavior of organo soluble aromatic polyimides . Int. J. Polym. Anal. Charact. , 1997 . 4 153 - 172 . DOI: 10.1080/10236669708033943 http://doi.org/10.1080/10236669708033943 .

Zhang, E.; Dai, X.; Dong, Z.; Qiu, X.; Ji, X . Critical concentration and scaling exponents of one soluble polyimide from dilute to semidilute entangled solutions . Polymer , 2016 . 84 275 - 285 . DOI: 10.1016/j.polymer.2016.01.001 http://doi.org/10.1016/j.polymer.2016.01.001 .

Gupta, P.; Elkins, C.; Long, T. E.; Wilkes, G. L . Electrospinning of linear homopolymers of poly(methyl methacrylate): exploring relationships between fiber formation, viscosity, molecular weight and concentration in a good solvent . Polymer , 2005 . 46 4799 - 4810 . DOI: 10.1016/j.polymer.2005.04.021 http://doi.org/10.1016/j.polymer.2005.04.021 .

Zhang, E.; Chen, H.; Dai, X.; Liu, X.; Yang, W.; Liu, W.; Dong, Z.; Qiu, X.; Ji, X . Influence of molecular weight on scaling exponents and critical concentrations of one soluble 6FDA-TFDB polyimide in DMF solution . J. Polym. Res. , 2017 . 24 47 DOI: 10.1007/s10965-017-1204-9 http://doi.org/10.1007/s10965-017-1204-9 .

Zhang, E.; Dai, X.; Zhu, Y.; Chen, Q.; Sun, Z.; Qiu, X.; Ji, X . Associative behavior of one polyimide with high molecular weight in solution through a relatively weak interaction . Polymer , 2018 . 141 166 - 174 . DOI: 10.1016/j.polymer.2018.03.008 http://doi.org/10.1016/j.polymer.2018.03.008 .

Doi, M.; Edwards, S. F. The theory of polymer dynamics . Oxford university press Inc., New York, 1986 , p. 91

Han, C. D.; Jhon, M. S . Correlations of the first normal stress difference with shear stress and of the storage modulus with loss modulus for homopolymers . J. Appl. Polym. Sci. , 1986 . 32 3809 - 3840 . DOI: 10.1002/app.1986.070320302 http://doi.org/10.1002/app.1986.070320302 .

Bird, R. B.; Curtiss, C. F.; Armstrong, R. C.; Hassage., O. Dynamics of polymeric liquids, Vol 1: Fluid mechanics . Wiley, New York, 1987 , p. 576

Jin, L.; Tan, Y.; Shangguan, Y.; Lin, Y.; Xu, B.; Wu, Q.; Zheng, Q . Multi-region shear thinning for subsequent static self-thickening in chitosan-graft-polyacrylamide aqueous solution . J. Phys. Chem. B , 2013 . 117 15111 - 21 . DOI: 10.1021/jp408782e http://doi.org/10.1021/jp408782e .

van Egmond, J. W . Shear-thickening in suspensions, associating polymers, worm-like micelles, and poor polymer solutions . Curr. Opin. Colloid Interface Sci. , 1998 . 3 385 - 390 . DOI: 10.1016/S1359-0294(98)80054-X http://doi.org/10.1016/S1359-0294(98)80054-X .

Witten, T. A.; Cohen, M. H . Crosslinking in shear-thickening ionomers . Macromolecules , 1985 . 18 1915 - 1918 . DOI: 10.1021/ma00152a019 http://doi.org/10.1021/ma00152a019 .

Wang, S. Q . Transient network theory for shear-thickening fluids and physically crosslinked networks . Macromolecules , 1992 . 25 7003 - 7010 . DOI: 10.1021/ma00051a043 http://doi.org/10.1021/ma00051a043 .

Xu, D.; Liu, C. Y.; Craig, S. L . Divergent shear thinning and shear thickening behavior of supramolecular polymer networks in semidilute entangled polymer solutions . Macromolecules , 2011 . 44 2343 - 2353 . DOI: 10.1021/ma2000916 http://doi.org/10.1021/ma2000916 .

Vaccaro, A.; Marrucci, G . A model for the nonlinear rheology of associating polymers . J. Non-Newtonian Fluid Mech. , 2000 . 92 261 - 273 . DOI: 10.1016/S0377-0257(00)00095-1 http://doi.org/10.1016/S0377-0257(00)00095-1 .

Hackelbusch, S.; Rossow, T.; van Assenbergh, P.; Seiffert, S . Chain dynamics in supramolecular polymer networks . Macromolecules , 2013 . 46 6273 - 6286 . DOI: 10.1021/ma4003648 http://doi.org/10.1021/ma4003648 .

Watanabe, H . Viscoelasticity and dynamics of entangled polymers . Prog. Polym. Sci. , 1999 . 24 1253 - 1403 . DOI: 10.1016/S0079-6700(99)00029-5 http://doi.org/10.1016/S0079-6700(99)00029-5 .

Eom, Y.; Kim, B. C . Solubility parameter-based analysis of polyacrylonitrile solutions in N , N -dimethyl formamide and dimethyl sulfoxide . Polymer , 2014 . 55 2570 - 2577 . DOI: 10.1016/j.polymer.2014.03.047 http://doi.org/10.1016/j.polymer.2014.03.047 .

Rakesh, G.; Deshpande, A. P . Rheology of crosslinking poly vinyl alcohol systems during film formation and gelation . Rheol. Acta , 2010 . 49 1029 - 1039 . .

Cox, W. P.; Merz, E. H . Correlation of dynamic and steady flow viscosities . J. Polym. Sci. , 1958 . 28 619 - 622 . DOI: 10.1002/pol.1958.1202811812 http://doi.org/10.1002/pol.1958.1202811812 .

Suzuki, S.; Uneyama, T.; Inoue, T.; Watanabe, H . Nonlinear rheology of telechelic associative polymer networks: shear thickening and thinning behavior of hydrophobically modifiedethoxylated urethane (HEUR) in aqueous solution . Macromolecules , 2012 . 45 888 - 898 . DOI: 10.1021/ma202050x http://doi.org/10.1021/ma202050x .

Rubinstein, M.; Dobrynin, A. V . Associations leading to formation of reversible networks and gels . Curr. Opin. Colloid Interface Sci. , 1999 . 4 83 - 87 . DOI: 10.1016/S1359-0294(99)00013-8 http://doi.org/10.1016/S1359-0294(99)00013-8 .

Leibler, L.; Rubinstein, M.; Colby, R. H . Dynamics of reversible networks . Macromolecules , 1991 . 24 4701 - 4712 . DOI: 10.1021/ma00016a034 http://doi.org/10.1021/ma00016a034 .

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Swelling, Interfacial Behavior, and Rheology of Soft Core-Shell Microgels Introducing Acid Isomer for pH-Temperature Dual-responsiveness

Droplet Bridging Effect in Polymer/Polymer/Filler Ternary Composites

The Effect of NMR Setting Parameters on Molecular Weight Determination of Polyether Diols

The New Methods for Characterization of Molecular Weight of Supramolecular Polymers

Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms